Bis(benzonitrile)palladium chloride

Reaction

Product Name: Bis(benzonitrile)palladium chloride
CAS No.: 14220-64-5
Chemical Name: Bis(benzonitrile)palladium chloride
Synonyms: Pd(PhCN)2Cl2;BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE;Dichlorobis(benzonitrile)palladium;Bis(benzonitrile)palladium dichloride;BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE;Bis(benzonitrile)palladiuM(II);DICHLOROBIS(BENZONITRILE)PALLADIUM(II);Bis(benzonitriL;Bis(benzonitrile;Bis (benzonitrile) palladiuM
CBNumber: CB4339461
Molecular Formula: C14H10Cl2N2Pd
Formula Weight: 383.57
MOL File: 14220-64-5.mol

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Bis(benzonitrile)palladium chloride Property

Melting point:: 131 °C(lit.)
storage temp.: Inert atmosphere,2-8°C
solubility: Soluble in acetone, chloroform
form: Crystalline Powder
color: Orange to brown
Water Solubility: insoluble
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
BRN: 3981730
Exposure limits: NIOSH: IDLH 25 mg/m3
InChI: InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChIKey: WXNOJTUTEXAZLD-UHFFFAOYSA-L
SMILES: C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference: 14220-64-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21-23/24/25
Safety Statements: 22-24/25-23-45-36/37-27-20-9-4
RIDADR: UN3439
WGK Germany: 3
F: 9
TSCA: No
HazardClass: 6.1
PackingGroup: III
HS Code: 28439090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P321Specific treatment (see … on this label).

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 223689
Product name: Bis(benzonitrile)palladium(II) chloride
Purity: 95%
Packaging: 1g
Price: $87.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 223689
Product name: Bis(benzonitrile)palladium(II) chloride
Purity: 95%
Packaging: 10g
Price: $806
Updated: 2024/03/01

TCI Chemical

Product number: B1668
Product name: Bis(benzonitrile)palladium(II) Dichloride
Purity: >98.0%(T)
Packaging: 1g
Price: $199
Updated: 2024/03/01

TCI Chemical

Product number: B1668
Product name: Bis(benzonitrile)palladium(II) Dichloride
Purity: >98.0%(T)
Packaging: 5g
Price: $747
Updated: 2024/03/01

Alfa Aesar

Product number: 010006
Product name: trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.1%
Packaging: 1g
Price: $128.65
Updated: 2024/03/01

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Bis(benzonitrile)palladium chloride Chemical Properties,Usage,Production

Reaction

Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
Catalyst for the aza-Michael reaction of carbamates with enones.
Catalyst for the rearrangement of allylic imidates to allylic amides.
Catalyst for the Nazarov cyclization of α-alkoxy dienones.
Catalyst for the diamination of conjugated dienes.
Three component Michael addition, cyclization, cross-coupling reaction.
C-H activation of indoles.

Chemical Properties

yellow powder

Uses

suzuki reaction

Uses

Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.

Uses

Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:

For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins

General Description

This product has been enhanced for catalytic efficiency.

Bis(benzonitrile)palladium chloride Preparation Products And Raw materials

Raw materials

Toluene Palladium chloride Benzonitrile

Preparation Products

Chlorodimethylphenylsilane

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Bis(benzonitrile)palladium chloride Suppliers

Americas 1 Australia 1 Belgium 1 China 266 Europe 3 France 1 Germany 6 India 19 Japan 6 Norway 1 Russia 1 Singapore 1 South Korea 1 Switzerland 3 United Kingdom 9 United States 39 Global 359

TCI Chemicals (India) Pvt. Ltd.

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Triveni chemicals

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Alfa Aesar

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Mehta Enterprise

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Reax Chemicals

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Johnson Matthey Chemicals India Pvt., Ltd.

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LOBA CHEMIE PVT.LTD.

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A.J Chemicals

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View Lastest Price from Bis(benzonitrile)palladium chloride manufacturers

Shanghai Daken Advanced Materials Co.,Ltd

Product: Bis(benzonitrile)palladium(II)chloride 14220-64-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.00%
Supply Ability: 100KG /month
Release date: 2021-11-05

henan kanbei chemical co.,ltd

Product: Bis(benzonitrile)palladium chloride 14220-64-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-23

Zhuozhou Wenxi import and Export Co., Ltd

Product: Bis(benzonitrile)palladium chloride 14220-64-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-11

14220-64-5, Bis(benzonitrile)palladium chlorideRelated Search:

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TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE

Dichlorobis(benzonitrile)palladiuM(II),98% (C6H5CN)2PdCl2

Pd(PhCN)2Cl2

trans-Bis(benzonitrile)palladiuM chloride

Dichlorobis(benzonitrile)palladium(Ⅱ)

Benzonitrile, palladium complex

Bis(phenylnitrile)dichloropalladium

Dibenzonitrilepalladium dichloride

Dichlorobis(benzonitrile)palladium

Dichlorobis(phenyl cyanide)palladium

Palladium dichloride bis(benzonitrile)

Bis(benzonitrile)palladiuM(II)chloridel

Bis(benzonitrile)palladiuM(II) chloride 95%

Bis (benzonitrile) palladiuM

bis(benzonitrile)dichloro-Palladium

Bis(benzonitrile)-palladium(II) chloride (27.7% Pd) for synthesis

PALLADIUM(II) CHLORIDE BIS(BENZONITRILE) COMPLEX

Dichlorodiamminepalladium(II) PdCl2(C6H5CN)2

is(benzonitrile)palladium chloride

Bis(benzonitrile)palladium(II) chloride 95+%

TRANS-DICHLOROBIS-(BENZONITRILO)-PALLADIUM

TRANS-BIS(BENZONITRILE)DICHLOROPALLADATE (II)

TRANS-BIS(BENZONITRILE)DICHLOROPALLADIUM(II)

BIS(BENZONITRILE)DICHLOROPALLADIUM(II)

Bis(benzonitrile)palladium chloride

BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE

BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE

DICHLOROBIS(BENZONITRILE)PALLADIUM(II)

Dichlorobis(benzonitrile)palladium(II) ,(C6H5CN)2PdCl2

Benzonitrile - dichloropalladium (2:1)

Bis(benzonitrile)palladium(II) chloride, 99+%

trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.7%

Trans-Bis(benzonitrile)dichloropalladium(II) Can be used to form catalysts in situ by separate addition of ligand

Dichlorobis(benzonitrile)palladium(II),99%

Palladium, bis(benzonitrile)dichloro-

Palladium(II)chloro-bis(benzonitrile)

trans-Bis(benzonitrile)dichloropalladium(II), Pd

Dichlorobis(benzonitrile)palladium (II) ,98%

Bis(benzonitrile)palladiuM(II)

trans-Bis(benzonitrile)dichloropalladiuM(II), Pd 27.1%

Bis(benzonitrile)palladiuM(II) chloride, 99+% 1GR

Bis(benzonitrile)palladium(II) Dichloride &gt

Bis(benzonitrile)dichloropalladium(Ⅱ)

Bis(benzonitriL

Bis(benzonitrile)palladium dichloride

Bis(benzonitrile)palladium chloride ISO 9001：2015 REACH

Bis(benzonitrile)palladium(II)chloride 14220-64-5

Bis(benzonitrile)palladium(II) Dichloride extrapure, 27.4% Pd

BIS (BENZONITRILE) DICHLORO PALLADIUM (II) For synthesis

Bis(benzonitrile

14220-64-5

PdCl2C6H5CN2

C6H5CN2PdCl2

C14H10N2PdCl2

C14H10Cl2N2Pd

2C7H5NCl2Pd

Classes of Metal Compounds

Transition Metal Compounds