METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE

Preparation

Product Name: METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE
CAS No.: 70264-94-7
Chemical Name: METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE
Synonyms: METHYL 3-METHOXY-4-BROMOMETHYLBENZOATE;)-3-methoxybenzoate;Methyl 4-(Bromomethyl)-m-anisate;4-(bromomethyl)-3-methoxybenzoate;METHYL4-BROMOETHYL-3-METHOXYBENZOATE;METHYL3-METHOXY-4-(BROMOMETHYL)BENZONATE;METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE;Methyl 4-(bromomethyl)-3-methoxybenzonate;Methyl4-(Bromomethyl)-3-methoxybenzoate>4-(Bromomethyl)-m-anisic Acid Methyl Ester
CBNumber: CB4342137
Molecular Formula: C10H11BrO3
Formula Weight: 259.1
MOL File: 70264-94-7.mol

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METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE Property

Melting point:: 92-94°C
Boiling point:: 324.2±32.0 °C(Predicted)
Density: 1.432
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Chloroform (Sparingly), Methanol (Slightly)
form: powder to crystal
color: White to Light yellow
CAS DataBase Reference: 70264-94-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,N
Risk Statements: 36/37/38-50/53-43-41-38
Safety Statements: 26-36/37/39-61-60
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
HazardClass: IRRITANT
PackingGroup: Ⅲ
HS Code: 2918999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 681180
Product name: Methyl 4-(bromomethyl)-3-methoxybenzoate
Purity: 97%
Packaging: 5g
Price: $82.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 681180
Product name: Methyl 4-(bromomethyl)-3-methoxybenzoate
Purity: 97%
Packaging: 1g
Price: $69.8
Updated: 2023/06/20

TCI Chemical

Product number: M2356
Product name: Methyl 4-(Bromomethyl)-3-methoxybenzoate
Purity: >97.0%(GC)
Packaging: 5g
Price: $106
Updated: 2024/03/01

TCI Chemical

Product number: M2356
Product name: Methyl 4-(Bromomethyl)-3-methoxybenzoate
Purity: >97.0%(GC)
Packaging: 25g
Price: $425
Updated: 2024/03/01

TRC

Product number: M258700
Product name: Methyl 4-(bromomethyl)-3-methoxybenzoate
Packaging: 5g
Price: $70
Updated: 2021/12/16

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METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE Chemical Properties,Usage,Production

Preparation

Methyl 4-(bromomethyl)-3-methoxybenzoate is prepared by the following steps:A mixture of methyl 3-methoxy-4-methylbenzoate 37 (5 g, 27.8 mmol), NBS (4.94 g, 27.8 mmol), and benoyl peroxide (0.0008 g, 0.003 mmol) was refluxed in CCl4 (25 ml) for 10 hours. The reaction mixture was allowed to cool and filtered. The residue was washed with CCl4 and the combined filtrate concentrated in vacuo. Purification by column chromatography over silica gel (5-10% EtOAc-pet ether) furnished a colourless solid (7.19 g).Yield : 100%

Uses

Methyl 4-(Bromomethyl)-3-methoxybenzoate is an intermediate used to prepare heteroarylphenyloxoacetyl and heteroarylphenylsulfonyl benzoylpiperazine analogs of BMS 378806 as HIV entry inhibitors. It is also used to synthesize steroid 5α-reductase inhibiting acylpiperidines.

METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE Preparation Products And Raw materials

Raw materials

N-Bromosuccinimide 2,2'-Azobis(2-methylpropionitrile) 3-Hydroxy-4-methylbenzoic acid Carbon tetrachloride Dimethyl sulfate

Preparation Products

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METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE Suppliers

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View Lastest Price from METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE manufacturers

Career Henan Chemical Co

Product: METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE 70264-94-7
Price: US $1.00/KG
Min. Order: 1G
Purity: 98%
Supply Ability: 100KG
Release date: 2018-08-15

70264-94-7, METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATERelated Search:

methyl 4-(bromomethyl)-2-methoxybenzoate METHYL-3-BROMOMETHYL-5-METHOXYBENZOATE 4-Methylbenzyl bromide 4-Bromomethylbenzoic acid Methyl 4-(bromomethyl)benzoate 3-METHOXY-4-METHYLBENZALDEHYDE METHYL 3-METHOXY-4-METHYLBENZOATE METHYL 3-HYDROXY-4-METHYLBENZOATE 2-(BROMOMETHYL)PHENOL 1-(bromomethyl)-2-methoxybenzene 3-Hydroxy-4-methylbenzoic acid 4-(BROMOMETHYL)BENZALDEHYDE 3-Methoxy-4-methylbenzoic acid METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE

Methyl 4-(bromomethyl)-3-methoxybenzonate

4-BROMOMETHYL-3-METHOXY-BENZOIC ACID METHYL ESTER

METHYL3-METHOXY-4-(BROMOMETHYL)BENZONATE

METHYL4-BROMOETHYL-3-METHOXYBENZOATE

4-Brommethyl-3-methoxybenzoesuremethylester

Methyl 4-brome methyl-3-methoxy benzoate

Methyl 4-(bromomethyl)-3-(methyloxy)benzoate

Methyl 4-(bromomethyl)-3-methoxybenzoate 98%

Benzoic acid, 4-(bromomethyl)-3-methoxy-, methyl ester

METHYL 3-METHOXY-4-BROMOMETHYLBENZOATE

METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE

3-METHOXY-4-(BROMOMETHYL)BENZOIC ACID METHYL ESTER

Methyl4-(Bromomethyl)-3-methoxybenzoate&gt

)-3-methoxybenzoate

4-(Bromomethyl)-m-anisic Acid Methyl Ester

Methyl 4-(Bromomethyl)-m-anisate

CAS No.70264-94-7 METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE

4-(bromomethyl)-3-methoxybenzoate

3-Methoxy-4-bromomethylbenzoate methyl ester

70264-94-7

C10H11O3Br

BENZYL HALIDE

C10 to C11

Carbonyl Compounds

Building Blocks

Esters

Organic Building Blocks

Building Blocks

C10 to C11

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

Aromatic Esters

Benzoic acid

C10 to C11

Carbonyl Compounds

Esters