ChemicalBook > CAS DataBase List > Ethyl 6-amino-5-methoxyindole-2-carboxylate

Ethyl 6-amino-5-methoxyindole-2-carboxylate

Product Name
Ethyl 6-amino-5-methoxyindole-2-carboxylate
CAS No.
107575-60-0
Chemical Name
Ethyl 6-amino-5-methoxyindole-2-carboxylate
Synonyms
6-AMino-5-Methoxy indole-2-carboxylate;ETHYL 6-AMINO-5-METHOXYINDOLE-2-CARBOXYLATE;methyl 6-amino-5-methoxy-1H-indole-2-carboxylate;6-amino-5-methoxyindole-2-carboxylic acid ethyl ester;6-AMino-5-Methoxy-1H-indole-2-carboxylic Acid Ethyl Ester;1H-Indole-2-carboxylic acid, 6-amino-5-methoxy-, ethyl ester;Nicotine Intermediates Ethyl 6-amino-5-methoxyindole-2-carboxylate
CBNumber
CB5448948
Molecular Formula
C12H14N2O3
Formula Weight
234.25
MOL File
107575-60-0.mol
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Ethyl 6-amino-5-methoxyindole-2-carboxylate Property

Melting point:
164-166°C
Boiling point:
439.3±40.0 °C(Predicted)
Density 
1.283±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
solubility 
Soluble in dichloromethane, ethyl acetate and methanol.
form 
Solid
pka
15.95±0.30(Predicted)
color 
Slightly Yellowish-Brown
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Safety

Risk Statements 
33-36/37/38
Safety Statements 
26-37
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
E898810
Product name
Ethyl6-Amino-5-methoxyindole-2-carboxylate
Packaging
100mg
Price
$1175
Updated
2021/12/16
Matrix Scientific
Product number
075676
Product name
Ethyl 6-amino-5-methoxyindole-2-carboxylate
Purity
95+%
Packaging
5g
Price
$1750
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0151902
Product name
ETHYL-6-AMINO-5-METHOXYINDOLE-2-CARBOXYLATE
Purity
95.00%
Packaging
250MG
Price
$1871.1
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
9988
Product name
Ethyl6-Amino-5-methoxyindole-2-carboxylate
Packaging
125mg
Price
$2120
Updated
2021/12/16
Matrix Scientific
Product number
075676
Product name
Ethyl 6-amino-5-methoxyindole-2-carboxylate
Purity
95+%
Packaging
1g
Price
$639
Updated
2021/12/16
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Ethyl 6-amino-5-methoxyindole-2-carboxylate Chemical Properties,Usage,Production

Chemical Properties

Slightly Yellowish-Brown Solid

Uses

Ethyl 6-amino-5-methoxyindole-2-carboxylate is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field.

Synthesis

119825-27-3

107575-60-0

The experimental procedure for the synthesis of ethyl 6-amino-5-methoxyindole-2-carboxylate using pyrroloquinoline impurity 1 as starting material was as follows: the experiment was divided into six groups, each using a different sample solution of heteropolyacid as catalyst. The procedure was as follows: compound 6 (0.524 g, 2 mmol) and benzylamine (0.321 g, 0.328 ml, 3 mmol) were placed in a 10 ml flask, and heteropolyacid ionic liquids (0.04 mmol) were added as catalysts, respectively. The reaction mixture was heated by microwave heating at 140 °C for 90 min. After completion of the reaction, 20 ml of ethyl acetate was added to the mixture and stirred thoroughly for 30 minutes. Subsequently, the mixture was filtered and the filtrate was concentrated to dryness by evaporation and finally purified by recrystallization to obtain the target product compound 7.

References

[1] Patent: CN104557921, 2018, B. Location in patent: Paragraph 0101-011
[2] Helvetica Chimica Acta, 1993, vol. 76, # 4, p. 1667 - 1673
[3] Patent: WO2006/102642, 2006, A1. Location in patent: Page/Page column 9; 15; 1/6
[4] Tetrahedron Letters, 1988, vol. 29, # 30, p. 3709 - 3712

Ethyl 6-amino-5-methoxyindole-2-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Ethyl 6-amino-5-methoxyindole-2-carboxylate manufacturers

Career Henan Chemical Co
Product
Ethyl 6-amino-5-methoxyindole-2-carboxylate 107575-60-0
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-13

107575-60-0, Ethyl 6-amino-5-methoxyindole-2-carboxylateRelated Search:

Ethanol 6-Aminocaproic acid Ethylparaben Ethyl formate 2-Ethoxyethanol Trinexapac-ethyl Benzocaine Tris(trimethylsilyl)phosphate ISOXADIFEN-ETHYL Ethyl acetate RESMETHRIN Urethane Glycine 5-Methoxyindole Ethyl chloroformate ETHYL 5-METHOXYINDOLE-2-CARBOXYLATE Diethyl ether 5-METHOXYINDOLE-2-CARBOXYLIC ACID

  • ETHYL 6-AMINO-5-METHOXYINDOLE-2-CARBOXYLATE
  • 6-amino-5-methoxyindole-2-carboxylic acid ethyl ester
  • 6-AMino-5-Methoxy indole-2-carboxylate
  • 6-AMino-5-Methoxy-1H-indole-2-carboxylic Acid Ethyl Ester
  • 1H-Indole-2-carboxylic acid, 6-amino-5-methoxy-, ethyl ester
  • Nicotine Intermediates Ethyl 6-amino-5-methoxyindole-2-carboxylate
  • methyl 6-amino-5-methoxy-1H-indole-2-carboxylate
  • 107575-60-0
  • 12H14N2O3
  • Aromatics Compounds
  • Aromatics
  • Indole Derivatives
  • 107575-60-0