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Methyl 3-bromo-5-iodobenzoate

Product Name
Methyl 3-bromo-5-iodobenzoate
CAS No.
188813-07-2
Chemical Name
Methyl 3-bromo-5-iodobenzoate
Synonyms
Methyl 5-bromo-3-iodobenzoate;Methyl3-bromo-5-iodobenzoate97%;Methyl 3-bromo-5-iodobenzoate 97%;Benzoic acid, 3-bromo-5-iodo-, meth;3-BroMo-5-iodobenzoic acid Methyl ester;Benzoic acid,3-broMo-5-iodo-, Methyl ester
CBNumber
CB61106462
Molecular Formula
C8H6BrIO2
Formula Weight
340.94
MOL File
188813-07-2.mol
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Methyl 3-bromo-5-iodobenzoate Property

Melting point:
62.0-63.0 °C
Boiling point:
334.5±32.0 °C(Predicted)
Density 
2.059±0.06 g/cm3(Predicted)
storage temp. 
RT, protect from light
form 
Powder
Appearance
White to off-white Solid
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
M296580
Product name
Methyl3-Bromo-5-iodobenzoate
Packaging
10mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB67313
Product name
3-Bromo-5-iodobenzoic acid methyl ester
Packaging
500mg
Price
$60
Updated
2021/12/16
ChemScene
Product number
CS-0044963
Product name
Methyl3-bromo-5-iodobenzoate
Packaging
1g
Price
$60
Updated
2021/12/16
Apolloscientific
Product number
OR17113
Product name
Methyl3-bromo-5-iodobenzoate
Purity
97%
Packaging
1g
Price
$145
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB67313
Product name
3-Bromo-5-iodobenzoic acid methyl ester
Packaging
2g
Price
$155
Updated
2021/12/16
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Methyl 3-bromo-5-iodobenzoate Chemical Properties,Usage,Production

Synthesis

188815-32-9

74-88-4

188813-07-2

(a) Synthesis of methyl 3-bromo-5-iodobenzoate: In a dry reaction flask, 3-bromo-5-iodobenzoic acid (15 g, 45.9 mmol) was dissolved in a solvent mixture of tetrahydrofuran (20 mL) and N,N-dimethylformamide (75 mL). Sodium carbonate (9.7 g, 92 mmol) and iodomethane (5.7 mL, 92 mmol) were then added. The reaction mixture was stirred at room temperature for 20 hours. After completion of the reaction, most of the solvent was removed by concentration under reduced pressure. The residue was extracted with ethyl acetate and washed sequentially with water, saturated aqueous sodium bicarbonate solution and brine. The organic phase was dried over anhydrous sodium sulfate and concentrated under reduced pressure to give the title compound methyl 3-bromo-5-iodobenzoate. Yield: 15 g (99% yield).

References

[1] Patent: WO2010/103279, 2010, A1. Location in patent: Page/Page column 126
[2] Patent: WO2010/103297, 2010, A2. Location in patent: Page/Page column 71

Methyl 3-bromo-5-iodobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 3-bromo-5-iodobenzoate Suppliers

Energy Chemical
Tel
021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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China
ProdList
44801
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Accela ChemBio Co.,Ltd.
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021-50795510 4000665055
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021-50795055
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sales@accelachem.com
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China
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Beijing Eternalchem Co,. Ltd.
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010-59484199 18611897322
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sales@eternalchem.com
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China
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Shanghai Topbiochem Technology Co., Ltd
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021-58170097
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info@topbiochem.com
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China
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Shanghai Jian Chao Chemical Technology Co., Ltd.
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150-2103-5486 18017383231
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qq:2817624287
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983544897@qq.com
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China
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SynAsst Chemical.
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021-60343070
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021-35122006
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Mashilabs (Shanghai) Co.,Ltd.
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19916721580
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QQ:3154870176
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mafarm@126.com
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China
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Tianjin Anhao Biological Technology Co., Ltd.
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sales@ahpharmatech.com
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China
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Shanghai Na Qian Chemical Technology Co. Ltd.
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13598610367
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QQ:2468833170
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2841375912@qq.com
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China
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Cool Pharm, Ltd
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021-60455363 18019463053
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50966098
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China
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12346
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58
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View Lastest Price from Methyl 3-bromo-5-iodobenzoate manufacturers

Qingdao RENAS Polymer Material Co., Ltd.
Product
methyl 3-bromo-5-iodobenzoate 188813-07-2
Price
US $0.00/kg
Min. Order
20kg
Purity
99%
Supply Ability
20 tons
Release date
2025-04-07
Hangzhou ICH Biofarm Co., Ltd
Product
Methyl 3-bromo-5-iodobenzoate 188813-07-2
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
2000kg
Release date
2023-06-09
Career Henan Chemical Co
Product
Methyl 3-bromo-5-iodobenzoate 188813-07-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-12-31