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Fluoroacetic acid

Product Name
Fluoroacetic acid
CAS No.
144-49-0
Chemical Name
Fluoroacetic acid
Synonyms
MFA;HFA;2-Fluoroacetic acid;Cymonic acid;fluoroacetic;2-fluoroaceticacid;Acetic acid, 2-fluoro-;C06108;Un 2642;CH2FCOOH
CBNumber
CB6212623
Molecular Formula
C2H3FO2
Formula Weight
78.04
MOL File
144-49-0.mol
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Fluoroacetic acid Property

Melting point:
33°C
Boiling point:
165°C
Density 
1.3693
pka
2.6(at 25℃)
Water Solubility 
50mg/L(20 ºC)
CAS DataBase Reference
144-49-0(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, fluoro-(144-49-0)
EPA Substance Registry System
Fluoroacetic acid (144-49-0)
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Safety

Hazard Codes 
T+,N
Risk Statements 
20/21/22-35-50-28
Safety Statements 
26-36/37/39-45-61-22-20
RIDADR 
2642
HazardClass 
6.1(a)
PackingGroup 
I
Hazardous Substances Data
144-49-0(Hazardous Substances Data)
Toxicity
LD50 oral in rat: 4680ug/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H300Fatal if swallowed

H400Very toxic to aquatic life

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P391Collect spillage. Hazardous to the aquatic environment

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
F489600
Product name
FluoroaceticAcid
Packaging
500mg
Price
$135
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
70259
Product name
FluoroaceticAcid
Packaging
10g
Price
$950
Updated
2021/12/16
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Fluoroacetic acid Chemical Properties,Usage,Production

Description

Fluoroacetic acid is a colorless crystallinesolid. Molecular weight=78.05; Boiling point=165C;Freezing/Melting point=35C. Hazard Identification(based on NFPA-704 M Rating System): Health 3,Flammability 0, Reactivity 0. Soluble in water.

Chemical Properties

Fluoroacetic acid is a colorless crystalline solid.

Chemical Properties

Colorless crystal. Soluble in water and alcohol.

Uses

Rodenticide.

Uses

Fluoroacetic acid (CH2FCOOH) is very poisonous. It is used to kill rats and mice.

Definition

ChEBI: A haloacetic acid that is acetic acid in which one of the methyl hydrogens is substituted by fluorine.

General Description

A colorless crystalline solid. May be toxic by ingestion. Used to make other chemicals.

Air & Water Reactions

Water soluble.

Reactivity Profile

Fluoroacetic acid is a halogenated carboxylic acid derivative. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in Fluoroacetic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Hazard

Toxic by ingestion.

Health Hazard

Fluoroacetic acid is very toxic; ingestion of small quantities may cause death.

Fire Hazard

When heated to decomposition, Fluoroacetic acid emits highly toxic fumes of fluorine containing compounds. Some of these materials may burn but none ignite readily. These materials may ignite combustibles (wood, paper, oil, etc.).

Safety Profile

Poison by ingestion, subcutaneous, intraperitoneal, and intravenous routes. Affects the human central nervous system, causing convulsions and ventricular fibrdlation. When heated to decomposition it emits toxic fumes of F and Na2O. See also SODIUM FLUOROACETATE.

Potential Exposure

This material is used as a rodenticide and a drug.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin,remove contaminated clothing and wash immediately withsoap and water. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart actionhas stopped. Transfer promptly to a medical facility. Whenthis chemical has been swallowed, get medical attention.Give large quantities of water and induce vomiting. Do notmake an unconscious person vomit. The symptoms of centralnervous system, cardiac, and renal failure do not becomemanifest until a few hours have passed. Specific treatment isnecessary in case of poisoning with this substance; the appropriate means with instructions must be available.

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area away from oxidizers.

Shipping

UN2642 Fluoroacetic acid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Reacts with reducing agents releasing flammable gas.

Waste Disposal

Use a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regula tions must be observed.

Fluoroacetic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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Fluoroacetic acid Suppliers

144-49-0, Fluoroacetic acidRelated Search:


  • RARECHEM AL BO 1262
  • Fluoroacetic acid: (Fluoroethanoic acid)
  • C06108
  • Un 2642
  • QEWYKACRFQMRMB-UHFFFAOYSA-N
  • Acetic acid, fluoro-
  • 2-Fluoroacetic acid
  • 2-fluoroaceticacid
  • Acide-monofluoracetique
  • acide-monofluoracetique(french)
  • Acido monofluoroacetio
  • acidomonofluoracetio
  • acidomonofluoroacetio
  • alpha-fluoroaceticacid
  • CH2FCOOH
  • Cymonic acid
  • cymonicacid
  • FLUOROACETIC ACID
  • MONOFLUORACETICACID
  • Fluoressigsure
  • fluoroacetate
  • fluoroacetic
  • fluoro-aceticaci
  • HFA
  • MFA
  • Monofluorazijnzuur
  • Monofluoressigsaure
  • monofluoroacetate
  • Monofluoroacetic Acid
  • monofluoroaceticacid
  • Acetic acid, 2-fluoro-
  • Fluoroacetic acid USP/EP/BP
  • 144-49-0
  • 144-49-2
  • C2H3FO3
  • FCH2COOH
  • HFA