BrettPhos Pd G3

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Reaction

Product Name: BrettPhos Pd G3
CAS No.: 1470372-59-8
Chemical Name: BrettPhos Pd G3
Synonyms: BuBrettPhos Pd G3;BrettPhos-G3-Pd;BrettPhos Pd G3;BrettPhos Pd G3 95%;BrettPhos Palladacycle Gen.3;BrettPhosPdG3 BrettPhos Pd G3;BrettPhos Pd G3 ISO 9001：2015 REACH;BrettPhosPalladacycle3rdGeneration,98%;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'...;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu
CBNumber: CB62686118
Molecular Formula: C48H66NO5PPdS
Formula Weight: 906.51
MOL File: 1470372-59-8.mol

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BrettPhos Pd G3 Property

Melting point:: 150-193°C (decomposition)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: Powder
color: yellow to beige
InChI: InChI=1S/C35H53O2P.C12H9N.CH4O3S.Pd/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h19-25,27-28H,9-18H2,1-8H3;1-6,8-9,13H;1H3,(H,2,3,4);/q;-2;;+2
InChIKey: ASZHREKEHVNFFW-UHFFFAOYSA-N
SMILES: P(C1CCCCC1)(C1CCCCC1)(C1C(=CC=C(OC)C=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

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Safety

WGK Germany: 3
HS Code: 2843909000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 761605
Product name: BrettPhos Pd G3
Purity: 95%
Packaging: 1g
Price: $308
Updated: 2024/03/01

Sigma-Aldrich

Product number: 761605
Product name: BrettPhos Pd G3
Purity: 95%
Packaging: 5g
Price: $1310
Updated: 2024/03/01

Alfa Aesar

Product number: 047250
Product name: BrettPhos Palladacycle 3rd Generation, 98%
Packaging: 1g
Price: $460
Updated: 2024/03/01

Alfa Aesar

Product number: 047250
Product name: BrettPhos Palladacycle 3rd Generation, 98%
Packaging: 5g
Price: $1470.65
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0322
Product name: Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 3]
Packaging: 100mg
Price: $44
Updated: 2024/03/01

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BrettPhos Pd G3 Chemical Properties,Usage,Production

Reaction

Catalyst used in the regioselective synthesis of benzimidazolones via cascade C-N coupling of monosubstituted ureas.
Catalyst used in a mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow .applications to the synthesis of functionalized heterocycles.

Uses

BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.
It may be used in the synthesis of following compounds:

[Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]₂and AgOTf.
[Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]₂ and AgOTf.
[Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.
Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]₂.

General Description

BrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. BrettPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

BrettPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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BrettPhos Pd G3 Suppliers

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View Lastest Price from BrettPhos Pd G3 manufacturers

Wuhan LPBchem Technology Co.,Ltd

Product: Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3 1470372-59-8
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50kg
Release date: 2020-11-27

Longyan Tianhua Biological Technology Co., Ltd

Product: BrettPhos Pd G3 1470372-59-8
Price: US $65.00/KG
Min. Order: 1KG
Purity: 99
Supply Ability: 10000KG
Release date: 2020-11-11

Career Henan Chemical Co

Product: BrettPhos Pd G3 1470372-59-8
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-10

1470372-59-8, BrettPhos Pd G3Related Search:

XantPhos Pd G4 Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) tBuXPhos-Pd-G3 XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 Xantphos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2

Methanesulfonato2-Dicyclohexylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

BrettPhos Pd G3 95%

[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium

Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu

[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium

Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle]

Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%

BrettPhos Pd G3

Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1’- biphenyl)-2-(2’-amino-1,1’-biphenyl)]palladium(II) methanesulfonate methanesulfonate

BuBrettPhos Pd G3

[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate

Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 3]

BrettPhos Palladacycle Gen.3

BrettPhos-G3-Pd

Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3

Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)-

BrettPhosPalladacycle3rdGeneration,98%

BrettPhos Pd G3 ISO 9001：2015 REACH

2-(2-aminophenyl)phenyl]palladio methanesulfonate, dicyclohexyl({3,6-dimethoxy-2-[2,4,6-tris(propan-2-yl)phenyl]phenyl})phosphane

Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'...

BrettPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

BrettPhosPdG3 BrettPhos Pd G3

(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate[BrettPhos Pd G3]

Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

1470372-59-8

C48H66NO5PPdS

Buchwald Ligands&Precatalysts

Buchwald Precatalysts Series