1-Hydroxy-2-naphthoic acid

Product Name: 1-Hydroxy-2-naphthoic acid
CAS No.: 86-48-6
Chemical Name: 1-Hydroxy-2-naphthoic acid
Synonyms: NSC 3717;Xinafoic acid.;RARECHEM AL BE 0359;2-Carboxy-1-naphthol;1-Hydroxy-2-naphthoi;LABOTEST-BB LT00452757;1-Hydroxy-2-phthoic acid;hydroxy-2-naphthoic acid;1-Hydroxy-2-naphthoicaci;1-hydroxy-β-naphthoic acid
CBNumber: CB6317591
Molecular Formula: C11H8O3
Formula Weight: 188.18
MOL File: 86-48-6.mol

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1-Hydroxy-2-naphthoic acid Property

Melting point:: 195-200 °C (dec.) (lit.)
Boiling point:: 283.17°C (rough estimate)
Density: 1.2100 (rough estimate)
refractive index: 1.6310 (estimate)
Flash point:: 150 °C
storage temp.: Sealed in dry,Room Temperature
solubility: alcohol: freely soluble
form: Powder or Crystals
pka: 3.02±0.30(Predicted)
color: White to slightly pink to tan
Water Solubility: SOLUBLE IN HOT WATER
Merck: 14,4834
BRN: 974438
InChIKey: SJJCQDRGABAVBB-UHFFFAOYSA-N
LogP: 3.196 (est)
CAS DataBase Reference: 86-48-6(CAS DataBase Reference)
EPA Substance Registry System: 1-Hydroxy-2-naphthoic acid (86-48-6)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39-37
WGK Germany: 3
TSCA: Yes
HS Code: 29182910

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 109630
Product name: 1-Hydroxy-2-naphthoic acid
Purity: ≥97.0%
Packaging: 5g
Price: $34.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 109630
Product name: 1-Hydroxy-2-naphthoic acid
Purity: ≥97.0%
Packaging: 100g
Price: $59.5
Updated: 2024/03/01

TCI Chemical

Product number: H0279
Product name: 1-Hydroxy-2-naphthoic Acid
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $32
Updated: 2024/03/01

TCI Chemical

Product number: H0279
Product name: 1-Hydroxy-2-naphthoic Acid
Purity: >98.0%(HPLC)(T)
Packaging: 500g
Price: $322
Updated: 2024/03/01

TCI Chemical

Product number: H0279
Product name: 1-Hydroxy-2-naphthoic Acid
Purity: >98.0%(HPLC)(T)
Packaging: 100g
Price: $97
Updated: 2024/03/01

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1-Hydroxy-2-naphthoic acid Chemical Properties,Usage,Production

Chemical Properties

beige to brown-grey powder. 1-Hydroxy-2-naphthoic acid [86-48-6], C11H8O3, Mr 188.17, mp 200℃, is only sparingly soluble in hot water but readily soluble in alkali and ethanol. It couples with diazo compounds in the 4-position and, with excess, in the 4,7-positions. It is sulfonated by oleum to give the 4-sulfonic and then the 4,7-disulfonic acids. Halogenation occurs in the 4-position, and nitrosation gives 2-nitroso-1-naphthol.

Uses

Metabolite from phenanthrene degradation. 1-Hydroxy-2-naphthoic acid is used as an intermediate for azo and triphenylmethane dyes and, more recently, for color-film dyes.

Uses

It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.

Definition

ChEBI: 1-hydroxy-2-naphthoic acid is a naphthoic acid with the carboxy group at position 2 and carrying a hydroxy substituent at the 1-position. It is a xenobiotic metabolite produced by the biodegradation of phenanthrene by microorganisms. It has a role as a bacterial xenobiotic metabolite and a fungal xenobiotic metabolite. It is a naphthoic acid, a member of naphthols and a hydroxy monocarboxylic acid. It is functionally related to a 2-naphthoic acid. It is a conjugate acid of a 1-hydroxy-2-naphthoate.

Preparation

Treatment of the dried sodium salt of 1-naphthol with carbon dioxide at 135℃ under pressure gives an 80 % yield of product.

General Description

1-Hydroxy-2-naphthoic acid is produced by the transformation of phenanthrene by NCIB 9816 clones.

Purification Methods

Successively crystallise the acid from EtOH/water, diethyl ether and acetonitrile, with filtration through a column of charcoal and Celite. [Tong & Glesmann J Am Chem Soc 79 583 1957, Beilstein 10 H 331, 10 IV 1194.]

1-Hydroxy-2-naphthoic acid Preparation Products And Raw materials

Raw materials

1-Naphthol Carbon dioxide Water Sodium formate

Preparation Products

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1-Hydroxy-2-naphthoic acid Suppliers

Americas 1 Australia 1 Belgium 3 Canada 2 China 270 Europe 4 France 1 Germany 12 India 19 Japan 7 Russia 1 Slovakia 1 Switzerland 2 The Netherlands 2 United Kingdom 15 United States 55 USA 1 Global 397

Shanghai Kangtuo Chemical Co., Ltd.

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J & K SCIENTIFIC LTD.

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View Lastest Price from 1-Hydroxy-2-naphthoic acid manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: 1-Hydroxy-2-naphthoic acid 86-48-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-13

Hebei Guanlang Biotechnology Co., Ltd.

Product: 1-Hydroxy-2-naphthoic acid 86-48-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2023-03-06

Henan Bao Enluo International TradeCo.，LTD

Product: 1-Hydroxy-2-naphthoic acid 86-48-6
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 50000tons
Release date: 2023-05-16

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86-48-6

84-48-6

HOC10H6COOH

C11H7O3

Organic Building Blocks

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Carboxylic Acids

Carbonyl Compounds

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CARBOXYLIC ACID

Aromatics

Intermediates of Dyes and Pigments

bc0001