2-Fluoroaniline

Product Name: 2-Fluoroaniline
CAS No.: 348-54-9
Chemical Name: 2-Fluoroaniline
Synonyms: 2-fluroaniline;O-FLUOROANILINE;2-Fluorobenzenamine;AKOS 91139;2-Fluoranilin;2-FLUOROANILINE;FLUOROANILINE-2;AKOS BBS-00003628;1BO-Fluoroaniline;Aniline, 2-fluoro-
CBNumber: CB6853530
Molecular Formula: C6H6FN
Formula Weight: 111.12
MOL File: 348-54-9.mol

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2-Fluoroaniline Property

Melting point:: -29 °C
Boiling point:: 182-183 °C(lit.)
Density: 1.151 g/mL at 25 °C(lit.)
vapor pressure: 1 hPa (20 °C)
refractive index: n20/D 1.544(lit.)
Flash point:: 140 °F
storage temp.: Store below +30°C.
solubility: 17g/l
form: Liquid
pka: 3.2(at 25℃)
color: Clear colorless
Specific Gravity: 1.151
Water Solubility: 17 g/L (20°C)
BRN: 1524219
CAS DataBase Reference: 348-54-9(CAS DataBase Reference)
NIST Chemistry Reference: Benzenamine, 2-fluoro-(348-54-9)
EPA Substance Registry System: o-Fluoroaniline (348-54-9)

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Safety

Hazard Codes: Xn,T,Xi
Risk Statements: 22-37/38-41-36/38-33-23/24/25
Safety Statements: 26-39-37/39-45-36/37-28
RIDADR: UN 2941 6.1/PG 3
WGK Germany: 2
RTECS: BY1390000
Autoignition Temperature: 600 °C
Hazard Note: Toxic/Irritant
TSCA: T
HazardClass: 6.1
PackingGroup: III
HS Code: 29214210

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: F3401
Product name: 2-Fluoroaniline
Purity: ≥99%
Packaging: 25G
Price: $33.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: F3401
Product name: 2-Fluoroaniline
Purity: ≥99%
Packaging: 500G
Price: $344
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20565
Product name: 2-Fluoroaniline
Purity: for synthesis
Packaging: 100mL
Price: $178
Updated: 2024/03/01

Sigma-Aldrich

Product number: F3401
Product name: 2-Fluoroaniline
Purity: ≥99%
Packaging: 100G
Price: $83.4
Updated: 2022/05/15

TCI Chemical

Product number: F0032
Product name: 2-Fluoroaniline
Purity: >99.0%(GC)
Packaging: 25g
Price: $16
Updated: 2024/03/01

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2-Fluoroaniline Chemical Properties,Usage,Production

Chemical Properties

2-Fluoroaniline is a clear colorless to brown liquid, toxic, insoluble in water, soluble in ethanol and ether, its vapor and air can form an explosive mixture, which can cause combustion and explosion in case of fire and high heat. Reacts with oxidants. Decomposed by high heat to release toxic gases.

Uses

2-Fluoroaniline (cas# 348-54-9) is a useful reagent for the synthesis of insecticides.

Application

2-Fluoroaniline can be used to synthesize thermosensitive dye FH-102, which is a black thermosensitive dye with wide application and excellent performance. The dye can be used in the production of terminal output printing paper of electronic computer, EEG recording paper, telephone fax paper and transparent thermal film for oil field.

Definition

ChEBI: 2-fluoroaniline is a derivative of aniline in which the hydrogen at position 2 has been substituted by fluorine. It is used as a pharmaceutical intermediate It is a primary arylamine and a fluoroaniline.

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 3415, 1984 DOI: 10.1016/S0040-4039(01)91034-2

General Description

Clear liquid with a mild sweet odor. Sinks in and mixes slowly with water.

Air & Water Reactions

Water soluble.

Reactivity Profile

2-Fluoroaniline is a base. Neutralizes acids to form salts plus water in an exothermic reaction. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Health Hazard

Inhalation or ingestion causes bluish tint to fingernails, lips and ears indicative of cyanosis; headache, drowsiness, and nausea, followed by unconsciousness. Liquid can be absorbed through skin and cause similar symptoms. Contact with eyes causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Irritating and toxic hydrogen fluoride and oxides of nitrogen may form in fires.

Metabolic pathway

2-Fluoro and 3-fluoroanilines are preferentially hydroxylated at the para-position, and 4-fluoroaniline is both p- and o-hydroxylated to a significant extent by rat liver microsomes and is not accompanied with an NIH shift to give 4-hydroxyl-3-fluoroaniline.

2-Fluoroaniline Preparation Products And Raw materials

Raw materials

Ethyl 2-fluoropropionate 2-Nitrochlorobenzene Potassium fluoride Hydrogen

Preparation Products

Flufenoxuron carfentrazone-ethyl 4-Bromo-2-fluorobenzonitrile 2-FLUOROPHENYL ISOCYANATE 1-(2-FLUOROPHENYL)PIPERAZINE HYDROCHLORIDE

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View Lastest Price from 2-Fluoroaniline manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: 2-Fluoroaniline 348-54-9
Price: US $30.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-11-23

Henan Fengda Chemical Co., Ltd

Product: 2-Fluoroaniline 348-54-9
Price: US $50.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-22

XINGTAI XINGJIU NEW MATERIAL TECHNOLOGY CO., LTD

Product: 2-Fluoroaniline 348-54-9
Price: US $25.00/KG
Min. Order: 1KG
Purity: 0.99
Supply Ability: 50000kg/month
Release date: 2022-01-24

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FC6H4NH2

C2 to C6

Building Blocks

Amines

Organic Building Blocks

Nitrogen Compounds

Fluoro-Aromatics

Anilines, Aromatic Amines and Nitro Compounds

Fluorobenzene

Heterocyclic Compounds

Benzene derivatives

Fluorobenzene Series

Fluorine series

amine | alkyl Fluorine