3-Amino-4-methoxybenzanilide
- Product Name
- 3-Amino-4-methoxybenzanilide
- CAS No.
- 120-35-4
- Chemical Name
- 3-Amino-4-methoxybenzanilide
- Synonyms
- AMBA;AMAN;Red KD Base;Red based KD;FAST RED KD BASE;3-AMINO-P-ANISANILIDE;LABOTEST-BB LT01138545;4-Methoxy-3-aminobenzanilide;3-AMINO-4-METHOXYBENZANILIDE;3-amino-4-methoxy-benzanilid
- CBNumber
- CB7251074
- Molecular Formula
- C14H14N2O2
- Formula Weight
- 242.27
- MOL File
- 120-35-4.mol
3-Amino-4-methoxybenzanilide Property
- Melting point:
- 154-156°C
- Boiling point:
- 385.1°C (rough estimate)
- Density
- 1.1338 (rough estimate)
- vapor pressure
- 0-0Pa at 25℃
- refractive index
- 1.6419 (estimate)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- pka
- 13.44±0.70(Predicted)
- form
- Solid
- color
- White to Off-White
- LogP
- 2.08 at 23℃ and pH7
- CAS DataBase Reference
- 120-35-4(CAS DataBase Reference)
- EPA Substance Registry System
- Benzamide, 3-amino-4-methoxy-N-phenyl- (120-35-4)
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- RTECS
- CV7400000
- TSCA
- Yes
- HazardClass
- IRRITANT
- HS Code
- 2924297099
- Toxicity
- mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01183,
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- S373079
- Product name
- 3-AMINO-4-METHOXYBENZANILIDE
- Purity
- Aldrich
- Packaging
- 50mg
- Price
- $179
- Updated
- 2024/03/01
- Product number
- A1954
- Product name
- 3-Amino-4-methoxybenzanilide
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $38
- Updated
- 2024/03/01
- Product number
- A1954
- Product name
- 3-Amino-4-methoxybenzanilide
- Purity
- >98.0%(T)
- Packaging
- 250g
- Price
- $75
- Updated
- 2024/03/01
- Product number
- A19168
- Product name
- 3-Amino-4-methoxybenzanilide, 98%
- Packaging
- 50g
- Price
- $173
- Updated
- 2021/12/16
- Product number
- A19168
- Product name
- 3-Amino-4-methoxybenzanilide, 98%
- Packaging
- 10g
- Price
- $44.2
- Updated
- 2021/12/16
3-Amino-4-methoxybenzanilide Chemical Properties,Usage,Production
Chemical Properties
Gray powder.
Uses
3-Amino-4-methoxybenzanilide is used in preparation method of Cyanate resin-based near-zero expansion composite material truss rod.
Uses
Dyes, pharmaceuticals, and other organic chemicals.
Synthesis
3-Amino-4-methoxybenzanilide is prepared by the reaction of 3-amino-4-methoxybenzoic acid and aniline. The steps are as follows:
A total of 0.17 mL (0.18 mmol) of DIC and 0.24 g (0.18 mmol) of HOBt were added to a dichloromethane solution of 0.20 g (0.12 mmol) of 1 at room temperature, and the reaction mixture was stirred for 0.5 h.
Then, 0.13 mL (0.14 mmol) of aniline was added to the mixture.
After approximately 3 h, 0.5 N NaOH was added to the solution.
The lower layer was isolated, and 0.5 N HCl was added until the aqueous solution was neutral.
The dichloromethane layer was washed three times with 10 mL of water, and then MgSO4 was added.
After 2 h, the solution was filtered, and the solvent was removed.
The residue was purified by column chromatography on silica gel (eluent: petroleum ether:ethyl acetate = 3:1) to yield the desired 3-Amino-4-methoxybenzanilide as a white solid (yield: 76%). Mp: 197-198 °C. 1H NMR (400 MHz, DMSO-d6) δ (ppm): 9.92 (1H, s, NH), 7.74 (2H, d, J = 9.0 Hz, PhH), 7.32 (2H, m, PhH), 7.21 (2H, d, J = 8.0 Hz, PhH), 7.06 (1H, m, PhH), 6.88 (1H, d, J = 8.0 Hz, PhH), 4.90 (2H, br s, NH2), 3.83 (3H, s, OCH3). ESI-MS (m/z): 243 (M + H)+.
3-Amino-4-methoxybenzanilide Preparation Products And Raw materials
Raw materials
Preparation Products
3-Amino-4-methoxybenzanilide Suppliers
- Tel
- 13771648447
- Fax
- +86-512-69233657
- sales@henryda-chem.com
- Country
- China
- ProdList
- 61
- Advantage
- 58
- Tel
- 17720472265
- Fax
- QQ：2195228001
- 2195228001@qq.com
- Country
- China
- ProdList
- 283
- Advantage
- 58
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 4006608290; 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40241
- Advantage
- 62
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30132
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24539
- Advantage
- 81
- Tel
- 400-6009262 16621234537
- Fax
- 021-64823266
- zhangsn@titansci.com
- Country
- China
- ProdList
- 14113
- Advantage
- 59
- Tel
- 021-54306202 13764082696;
- info@hanhongsci.com
- Country
- China
- ProdList
- 42982
- Advantage
- 64
- Tel
- 0712-0712-2580635 15527768850
- 1791901229@qq.com
- Country
- China
- ProdList
- 8849
- Advantage
- 52
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12990
- Advantage
- 57
View Lastest Price from 3-Amino-4-methoxybenzanilide manufacturers
- Product
- 3-Amino-4-methoxybenzanilide 120-35-4
- Price
- US $0.00/Kg/Bag
- Min. Order
- 1KG
- Purity
- 99%min
- Supply Ability
- 1000kg
- Release date
- 2021-11-29
- Product
- 3-Amino-4-methoxybenzanilide 120-35-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-08-15
- Product
- 3-Amino-4-methoxybenzanilide 120-35-4
- Price
- US $12.60/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 5000kg
- Release date
- 2021-07-13