ChemicalBook > CAS DataBase List > (S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl

(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl

Product Name
(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl
CAS No.
898543-06-1
Chemical Name
(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl
Synonyms
(S)-4-(4-(5-(aMinoMethyl)-2-oxooxazolidin-3-yl)phenyl)Morpholin-3-one hydrochloride;4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochloride;Rivaroxaban-19;Rivaroxaban Aminomethyl HCl Impurity;4-[4-[(5S)-5-(Aminomethyl)-2-oxo-1,3-oxazolidin-3-yl]phenyl]morpholin-3-one hydrochloride;idin-3-yL;Rivaroxaban C;)-2-oxooxazoL;in-3-one hydrochL;RIVAROXABAN AMINE
CBNumber
CB72537572
Molecular Formula
C14H17N3O4.ClH
Formula Weight
327.76
MOL File
898543-06-1.mol
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(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl Property

Melting point:
>276°C (dec.)
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Water (Slightly)
form 
Solid
pka
8.96[at 20 ℃]
color 
White to Off-White
Water Solubility 
184.9g/L at 20℃
InChI
InChI=1/C14H17N3O4.ClH/c15-7-12-8-17(14(19)21-12)11-3-1-10(2-4-11)16-5-6-20-9-13(16)18;/h1-4,12H,5-9,15H2;1H/t12-;/s3
InChIKey
ITMQDYQHNKXERQ-ZLBVLXFENA-N
SMILES
O=C1O[C@@H](CN)CN1C1C=CC(N2CCOCC2=O)=CC=1.Cl |&1:3,r|
LogP
-0.1 at 25℃
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
A616975
Product name
4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinoneHydrochloride
Packaging
10mg
Price
$80
Updated
2021/12/16
TRC
Product number
A616975
Product name
4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinoneHydrochloride
Packaging
5g
Price
$1185
Updated
2021/12/16
Matrix Scientific
Product number
093039
Product name
(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one hydrochloride
Purity
95+%
Packaging
250mg
Price
$38
Updated
2021/12/16
AK Scientific
Product number
J11350
Product name
RivaroxabanImpurity11HCl
Packaging
25mg
Price
$39
Updated
2021/12/16
Matrix Scientific
Product number
093039
Product name
(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one hydrochloride
Purity
95+%
Packaging
500mg
Price
$59
Updated
2021/12/16
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(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl Chemical Properties,Usage,Production

Uses

Rivaroxaban intermediate.

Flammability and Explosibility

Non flammable

Synthesis

446292-08-6

898543-06-1

The general procedure for the synthesis of (S)-4-(4-(5-(aminomethyl)-2-oxo-3-[4-(3-oxo-4-morpholinyl)phenyl]-5-oxazolidinyl]methyl]-1H-isoindole-1,3(2H)-dione from 2-[[(5S)-2-oxo-3-[4-(3-oxo-4-morpholinyl)phenyl]-5-oxazolidinyl]methyl]-1H-isoindole-1,3(2H)-dione was carried out in the following steps: in a four-necked round-bottomed flask. Methanol (2900 mL), 2-[[(5S)-2-oxo-3-[4-(3-oxo-4-morpholinyl)phenyl]-5-oxazolidinyl]methyl]-1H-isoindole-1,3(2H)-dione (290 g), and 40% aqueous methylamine solution (265 g) were added. The reaction mixture was stirred at 25 to 30 °C for 1 hour, then heated to 60 to 65 °C and maintained at that temperature for 4 hours. Upon completion of the reaction, the mixture was cooled to 25 to 30 °C, concentrated hydrochloric acid (290 mL, adjusted pH to 1-2) was added and stirring was continued for 30 minutes. The resulting solid was collected by filtration and washed with cold methanol (290 mL). The yield was 92.0%.

References

[1] Patent: WO2014/102820, 2014, A2. Location in patent: Paragraph 059
[2] Patent: CN105085371, 2017, B. Location in patent: Paragraph 0102-0104
[3] Patent: CN105085431, 2017, B. Location in patent: Paragraph 0093; 0094; 0095; 0096; 0097; 0098; 0099
[4] Patent: WO2012/35057, 2012, A2. Location in patent: Page/Page column 29
[5] Patent: WO2013/121436, 2013, A2. Location in patent: Page/Page column 27

(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl Suppliers

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View Lastest Price from (S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl 898543-06-1
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-04-12
Henan Aochuang Chemical Co.,Ltd.
Product
(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl 898543-06-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-19
Baoji Guokang Healthchem Co., Ltd.
Product
(S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl 898543-06-1
Price
US $715.00/Kg/Bag
Min. Order
1KG
Purity
99
Supply Ability
100kg
Release date
2021-06-05

898543-06-1, (S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HClRelated Search:

Rivaroxaban iMpurity 8 Acetic acid, 2-chloro-2-[2-(4-methoxyphenyl)hydrazinylidene], ethyl ester (R)-3-Piperidinamine dihydrochloride (R)-3-(Boc-Amino)piperidine 1H-ISOINDOLE-1,3(2H)-DIONE, 2-[[(5S)-2-OXO-3-[4-(3-OXO-4-MORPHOLINYL)PHENYL]-5-OXAZOLIDINYL]METHYL]- Rivaroxaban POLYSTYRENE IODOSOACETATE 1,2-Cyclohexanedione 4-(4-NITROPHENYL)MORPHOLIN-3-ONE (S)-(+)-Glycidyl Phthalimide 4-[4-(N-(3-chloro-(2R)-2-hydroxy-1-propyl)aMino)phenyl]Morpholin-3-one 5-CHLOROTHIOPHENE-2-CARBONYL CHLORIDE Ethyl (R)-(-)-4-cyano-3-hydroxybutyate 3-MORPHOLINONE, 4-[4-[(5S)-5-(AMINOMETHYL)-2-OXO-3-OXAZOLIDINYL]PHENYL]- 4-(4-AMINOPHENYL)MORPHOLIN-3-ONE 5-Chloro-2-thiophenecarboxylic Acid m-(Trifluoromethyl)phenylacetic acid (S)-(+)-Epichlorohydrin

  • (S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-1,3-oxazolidin-3-yl]phenyl]morpholin-3-one hydrochloride
  • Rivaroxaban Aminomethyl HCl Impurity
  • Rivaroxaban-19
  • 4-(4-((S)-5-(Aminomethyl)-2-Oxooxazolidin-3-Yl) Phenyl)Morpholin-3-One Hydrochloride
  • Rivaroxaban C
  • Rivaroxaban Impurity 11 HCl
  • (S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one hydrochloride (Rivaroxaban)
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochloride
  • 4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one hydrochloride
  • 3-Morpholinone, 4-[4-[(5S)-5-(aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-, hydrochloride (1:1)
  • (S)-4-(4-(5-(Aminomethyl)-2-oxoxazolidin-3-yl)phenyl)morpholin-3-one.HCl
  • (S)-4-(4-(5-(aMinoMethyl)-2-oxooxazolidin-3-yl)phenyl)Morpholin-3-one hydrochloride
  • 4-{4-[(5S)-5-aMinoMethyl)-2-oxo-1,3-oxazolidin-3-yl} Mor-pholin -3-one hydrochloride
  • 3-Morpholinone, 4-[4-[(5S)-5-(aMinoMethyl)-2-oxo-3-oxazolidinyl]phenyl]-, hydrochloride
  • 4-{4-[(5S)-5-aMinoMethyl)-2-oxo-1,3-oxazolidin-3-yl}Morpholin-3-one
  • Rivaroxaban interMediate A
  • Rivaroxaban Impurity 7-2
  • 2-[(2R)-2-Hydroxy-3-[[4-(3-oxo-4-morpholinyl)phenyl]amino]propyl]-1H-isoindole-1,3(2H)-
  • Rivaroxaban Impurity 10 HCl
  • (S)-4-(4-(5-(AminomethyL
  • )-2-oxooxazoL
  • idin-3-yL
  • in-3-one hydrochL
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochloride salt
  • 4-[4-[(5S)-5-(AMINOMETHYL)-2-OXO-3-OXAZOLIDINYL]PHENYL]-3-MORPHOLINONE HYDROCHLORIDE 898543-06-1
  • (S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one.HCl USP/EP/BP
  • (S)-4-(4-(5-(Aminomethyl)-2-oxooxazolidin-3-yl)phenyl)morpholin-3-one hydrochloride (Rivaroxaban Impurity)
  • (S)-4-(4-(5-(amino methyl)-2-Oxo Oxazolidin-3yl)Phenyl) morpholine-3-one HCl
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-mo...
  • Rivaroxaban Impurities352
  • Rivaroxaban Impurities1
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochlorideQ: What is 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochloride Q: What is the CAS Number of 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochloride Q: What is the storage condition of 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochloride Q: What are the applications of 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochloride
  • 4-{4-[(5S)-5-(aminomethyl)-2-oxo-1,3- oxazolidin-3-yl]phenyl} morpholin
  • Rivaroxaban Aminomethyl Hydrochloride Impurity
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochloride (Rivaroxaban Intermediate)
  • (S)-4-[4-[5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]morpholin-3-one Hydrochloride
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxooxazolidin-3-yl]phenyl]morpholin-3-one Hydrochloride
  • 4-(4-((S)-5-(Aminomethyl)-2-oxooxazolidin-3-Yl) phenyl)morpholin-3-one HCl
  • 4-[4-[(5S)-5-(aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-Morpholinone hydrochloride (1:1)
  • Intermediate of rivaroxaban
  • Rivaroxaban Impurity 7 HCl
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-1,3-oxazolidin-3-yl]phenyl]-3-morpholinone hydrochloride (1:1)
  • 4-[4-[(5S)-5-(aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]- 4-morpholinone，HCl
  • (4- [4- [(5S) -5- (aminomethyl) -2-oxo-3-oxazolyl] phenyl] -3-morpholinone hydrochloride
  • (S) -4- (4- (5- (aminomethyl) -2-oxoxazolidine-3-yl) phenyl) morpholin-3-one hydrochloride
  • 4-[4-[(5S)-5-(Aminomethyl)-2-oxo-3-oxazolidinyl]phenyl]-3-morpholinone hydrochlorid
  • Intermediate of RivaroxabanⅡ
  • (R)-2-(2-hydroxy-3-((3-(3-oxomorpholino)phenyl)amino)propyl)isoindoline-1,3-dione
  • (S)-4-(4-(5-(Aminomethy1)-2-oxooxazolidin-3- yl)pheny1)morpholin-3-one.HCl
  • Intermediate of Rivaroxaban 2
  • 4- [4- [(5S) -5- (aminomethyl) -2-oxo-3-oxazolyl] phenyl] -3-methylpyrrolidone hydrochloride
  • (S)-4-(4-(5-(Aminomethyl)-2-Oxooxazolidin-3-Yl)Phenyl)Mo
  • Rivaroxaban Intermediates III
  • (S) 4- (4- (5- (aminomethyl) -2-oxoxazolidine 3-yl) phenyl) morpholine-3-one hydrochloride
  • Rivaroxaban Degradation Impurity
  • Rivaroxaban Impurity 13 HCl
  • RIVAROXABAN AMINE