ChemicalBook > CAS DataBase List > XPhos Pd G3

XPhos Pd G3

Reaction

Product Name: XPhos Pd G3
CAS No.: 1445085-55-1
Chemical Name: XPhos Pd G3
Synonyms: XPhos G3;XPhos Pd G3;CID 71540322;XPhos Pd G3 95%;XPhos-G3-Palladacycle;XPhos Pd G3 ChemBeads;Xphos Palladacycle Gen.3;Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-p;Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-prop...;Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
CBNumber: CB72686115
Molecular Formula: C46H62NO3PPdS
Formula Weight: 846.46
MOL File: 1445085-55-1.mol

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XPhos Pd G3 Property

Melting point:: 146-151°C (decomposition)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: white to off-white
InChI: InChI=1S/C33H49P.C12H9N.CH4O3S.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-6,8-9,13H;1H3,(H,2,3,4);/q;-2;;+2
InChIKey: VXKANHUGMZCOIM-UHFFFAOYSA-N
SMILES: P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

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Safety

Risk Statements: 52/53
Safety Statements: 61
WGK Germany: 3
HS Code: 2843909000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 763381
Product name: XPhos Pd G3
Purity: 95%
Packaging: 1g
Price: $200.56
Updated: 2025/07/31

Sigma-Aldrich

Product number: 763381
Product name: XPhos Pd G3
Purity: 95%
Packaging: 5g
Price: $962
Updated: 2025/07/31

Sigma-Aldrich

Product number: 763381
Product name: XPhos Pd G3
Purity: 98%, 1:1 MTBE adduct
Packaging: 1 unit
Price: $4040
Updated: 2025/07/31

Sigma-Aldrich

Product number: 763381
Product name: XPhos Pd G3
Purity: 98%, 1:1 MTBE adduct
Packaging: 1 unit
Price: $4040
Updated: 2025/07/31

Strem Chemicals

Product number: 46-0320
Product name: Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct, min. 98% [Xphos Palladacycle Gen. 3]
Packaging: 250mg
Price: $59
Updated: 2024/03/01

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XPhos Pd G3 Chemical Properties,Usage,Production

Reaction

Palladium precatalyst for facile C-N cross-coupling reactions.

Uses

XPhos Pd G3 may be used in the following reactions:

Cyanation reaction of heterocyclic halides.
Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.

Uses

Convenient dosable form of XPhos-Pd-G3.
0.025 mmoles per capsule (1EA = 0.025 mmoles)

General Description

XPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

XPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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XPhos Pd G3 Suppliers

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View Lastest Price from XPhos Pd G3 manufacturers

Henan Fengda Chemical Co., Ltd

Product: XPhos Pd G3 1445085-55-1
Price: US $10.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-28

Shaanxi Dideu Medichem Co. Ltd

Product: Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 1445085-55-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2020-04-17

Wuhan LPBchem Technology Co.,Ltd

Product: Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl）palladium(II) / XPhos Pd G3 1445085-55-1
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50kg
Release date: 2020-12-01

1445085-55-1, XPhos Pd G3Related Search:

tBuXPhos-Pd-G3 XantPhos Pd G4 Josiphos SL-J009-1 Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 Xantphos Pd G3 BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2

XPhos Pd G3

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

(2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [XPhos Palladacycle]

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%

XPhos G3

METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II), MIN. 98

METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)DICHLOROMETHANEADDUCT(XPHOS Pd G3)

XPhos-G3-Palladacycle

XPhos Pd G3 95%

(SP-4-3)-[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium

(SP-4-3)-[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato-κO)palladium

METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[XPHOSPALLADACYCLEGEN.3]

Xphos Palladacycle Gen.3

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-p

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), [XPhos Palladacycle]

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl）palladium(II) / XPhos Pd G3

Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato-κO)-, (SP-4-3)-

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-prop...

XPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct

Methanesulfonato(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (XPhos Pd G3)

CID 71540322

XPhos Pd G3 ChemBeads

Methanesulfonicacid(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),XPhosPalladacycleGen.3

Methanesulfonic acid (2-dicyclohexylphosphino-2',4',6'-tri-isopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

1445085-55-1

C46H62NO3PPdS

C33H49PC13H13NO3PdS

Buchwald Ligands&Precatalysts

Buchwald Precatalysts Series