Description Referrence
ChemicalBook > CAS DataBase List > 5-Bromo-2-methylpyridine

5-Bromo-2-methylpyridine

Description Referrence
Product Name
5-Bromo-2-methylpyridine
CAS No.
3430-13-5
Chemical Name
5-Bromo-2-methylpyridine
Synonyms
5-BROMO-2-PICOLINE;5-BROMOPICOLINE;3-BROMO-6-PICOLINE;2-Methyl-5-bromopyrid;5-Bromo-2-picoline,99%;5-BROMO-2-METHYLPYRIDINE;3-BROMO-6-METHYLPYRIDINE;2-METHYL-5-BROMOPYRIDINE;5-broMo-1-Methylpyridine;5-bormo-2-methylpyridine
CBNumber
CB7327298
Molecular Formula
C6H6BrN
Formula Weight
172.02
MOL File
3430-13-5.mol
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5-Bromo-2-methylpyridine Property

Melting point:
32-36 °C
Boiling point:
74 °C / 17mmHg
Density 
1.494±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Solid
pka
3.59±0.10(Predicted)
color 
Off-White to Light Yellow
BRN 
107324
InChI
InChI=1S/C6H6BrN/c1-5-2-3-6(7)4-8-5/h2-4H,1H3
InChIKey
OFKWIQJLYCKDNY-UHFFFAOYSA-N
SMILES
C1(C)=NC=C(Br)C=C1
CAS DataBase Reference
3430-13-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-36/37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H301Toxic if swalloed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B2572
Product name
5-Bromo-2-methylpyridine
Purity
>98.0%(GC)
Packaging
1g
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
B2572
Product name
5-Bromo-2-methylpyridine
Purity
>98.0%(GC)
Packaging
5g
Price
$58
Updated
2024/03/01
Alfa Aesar
Product number
H27085
Product name
5-Bromo-2-methylpyridine, 98%
Packaging
250mg
Price
$44.3
Updated
2023/06/20
Alfa Aesar
Product number
H27085
Product name
5-Bromo-2-methylpyridine, 98%
Packaging
1g
Price
$84.4
Updated
2023/06/20
TRC
Product number
B685590
Product name
5-Bromo-2-picoline
Packaging
50g
Price
$1390
Updated
2021/12/16
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5-Bromo-2-methylpyridine Chemical Properties,Usage,Production

Description

It is an important intermediate in the organic synthesis, which has many applications, such as pharmaceutical intermediate, organic synthesis, organic solvent, production of dyes, pesticide, and spice. Specifically, this chemical can act as the raw material to prepare 2:2’-dipyridyl and its derivatives.1 Moreover, this compound may be involved in the synthesis of biaryls through a one-pot tandem borylation/Suzuki-Miyaura cross-coupling reaction catalyzed by a palladacycle.2 In addition, 5-bromo-2-methylpyridine has been demonstrated to function as the substrate in a general palladium-catalyzed coupling of aryl bromides/triflates and thiols.3 Besides, this substance can facilitate the synthesis of 5-arylamino-2-picolines via displacement of bromide by anthranilic acid and decarboxylation.4

Referrence

  1. Willink, H. D. T.; Wibaut, J. P., The preparation of 2 : 2'-dipyridyl and some of its derivatives. Recueil Des Travaux Chimiques Des Pays-Bas 1935, 54, 275-283.
  2. Wang, L. H.; Cui, X. L.; Li, J. Y.; Wu, Y. S.; Zhu, Z. W.; Wu, Y. J., Synthesis of Biaryls through a One-Pot Tandem Borylation/Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by a Palladacycle. Eur. J. Org. Chem. 2012, 595-603.
  3. Itoh, T.; Mase, T., A general palladium-catalyzed coupling of aryl bromides/triflates and thiols. Org. Lett. 2004, 6, 4587-4590.
  4. Louis H. Peterson; Tolman, R. L., Reinvestigation of the synthesis of 5-arylamino-2-picolines J. Heterocycl. Chem. 1977.

Chemical Properties

Light yellow Cryst

Uses

5-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds.

5-Bromo-2-methylpyridine Preparation Products And Raw materials

Raw materials

Preparation Products

5-Bromo-2-hydroxymethylpyridine 5-BROMO-2-METHYLPYRIDINE N-OXIDE 4-AMINO-5-BROMO-2-METHYLPYRIDINE 5-Bromopyridine-2-carbaldehyde 6-Methylpyridine-3-boronic Acid
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View Lastest Price from 5-Bromo-2-methylpyridine manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
5-Bromo-2-methylpyridine 3430-13-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-03
Hebei Weibang Biotechnology Co., Ltd
Product
5-Bromo-2-methylpyridine 3430-13-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-12
Hebei Chuanghai Biotechnology Co,.LTD
Product
5-Bromo-2-methylpyridine 3430-13-5
Price
US $9.00/KG
Min. Order
1KG
Purity
99.9
Supply Ability
1 ton
Release date
2024-08-21

3430-13-5, 5-Bromo-2-methylpyridineRelated Search:

5-Bromo-2-hydroxymethylpyridine 5-Bromo-2-methoxypyridine 5-BROMO-2-(METHYLTHIO)PYRIMIDINE 2-AMINO-3,5-DIBROMO-6-METHYLPYRIDINE 2,6-Dimethyl-3,5-dibromopyridine 5-Bromo-2-methylpyridine 3-Bromo-2,6-dimethylpyridine Methyl 6-bromonicotinate 5-bromo-2-pyridinecarboxylic acid ethyl ester 5-Bromo-2-pyridinecarbonitrile 6-AMINO-5-BROMO-2-PICOLINE 5-BROMO-2-METHYLPYRIDINE N-OXIDE 3,5-DIBROMO-2,4,6-TRIMETHYLPYRIDINE 2-CHLORO-3-BROMO-6-PICOLINE 2,5,6-Tribromo-3-methylpyridine 2-FLUORO-3-BROMO-6-PICOLINE 2,3-DIBROMO-6-PICOLINE 3-AMINO-2-BROMO-5-PICOLINE

  • 5-broMo-1-Methylpyridine
  • 5--2- MethylpyridinebroMide
  • 2 - Methyl - 5 - broMide pyridine
  • 2-METHYL-5-BROMOPYRIDINE
  • 5-BROMOPICOLINE
  • 3-BROMO-6-METHYLPYRIDINE
  • 5-BROMO-2-METHYLPYRIDINE
  • 5-BROMO-2-PICOLINE
  • 3-BROMO-6-PICOLINE
  • 5-Bromo-2-methylpyridine 98%
  • Pyridine, 5-bromo-2-methyl-
  • 2-METHYL-5-BROMOPYRIDINE 98.5%(MIN)
  • 2-Methyl-5-bromopyrid
  • 5-bormo-2-methylpyridine
  • 5-Bromo-2-picoline,99%
  • 2-Picoline, 5-bromo- (6CI,7CI,8CI)
  • 5-Bromo-2-methylpyridine ,99%
  • 5-BROMO-2-METHYLPYRIDINE (5-BROMO-2-PICOLINE)
  • 5-BROMO-2-PICOLINE5-BROMO-2-METHYLPYRIDINE
  • 5-BroMo-2-picoline, 99% 1GR
  • 5-Bromo-2-methylpyridine &gt
  • 5-Bromo-2-methylpyridine ISO 9001：2015 REACH
  • 3430-13-5
  • 3430-18-5
  • 340-13-5
  • 1074-98-7
  • Building Blocks
  • Heterocyclic Building Blocks
  • Bromopyridines
  • Halopyridines
  • Pyridines
  • Halogenated Heterocycles
  • Building Blocks
  • C6
  • Chemical Synthesis
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Pyridines derivates
  • Bromopyridines
  • Halopyridines
  • Pyridine series
  • blocks
  • Bromides
  • Pyridines
  • Pyridine
  • Pyridines, Pyrimidines, Purines and Pteredines
  • alkyl bromide
  • 3430-13-5