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2-Methoxy-5-sulfamoylbenzoic acid

Product Name
2-Methoxy-5-sulfamoylbenzoic acid
CAS No.
22117-85-7
Chemical Name
2-Methoxy-5-sulfamoylbenzoic acid
Synonyms
Sulpride Impurity D;Sulpiride IMpurity D;Sulpiride EP Impurity D;Sulpiride Impurity D(EP);5-SulfaMoyl-o-anisic Acid;5-sulphamoyl-o-anisic acid;Levosulpiride - EP Impurity D;2-Methoxy-5-sulfamoylbenzoicaci;2-METHOXY-5-SULFONYLBENZOIC ACID;2-METHOXY-5-SULFAMOYLBENZOIC ACID
CBNumber
CB7354418
Molecular Formula
C8H9NO5S
Formula Weight
231.23
MOL File
22117-85-7.mol
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2-Methoxy-5-sulfamoylbenzoic acid Property

Melting point:
220 °C
Boiling point:
482.5±55.0 °C(Predicted)
Density 
1.492±0.06 g/cm3(Predicted)
storage temp. 
Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Solid
pka
3.56±0.10(Predicted)
color 
White to Off-White
CAS DataBase Reference
22117-85-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Irritant
HS Code 
2922500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
B23698
Product name
2-Methoxy-5-sulfamoylbenzoic acid, 97%
Packaging
10g
Price
$45.65
Updated
2024/03/01
Alfa Aesar
Product number
B23698
Product name
2-Methoxy-5-sulfamoylbenzoic acid, 97%
Packaging
50g
Price
$129.65
Updated
2024/03/01
Alfa Aesar
Product number
B23698
Product name
2-Methoxy-5-sulfamoylbenzoic acid, 97%
Packaging
250g
Price
$459
Updated
2021/12/16
TRC
Product number
M326640
Product name
2-Methoxy-5-sulfamoylbenzoicAcid
Packaging
10g
Price
$180
Updated
2021/12/16
Apolloscientific
Product number
OR3567
Product name
2-Methoxy-5-sulphamoylbenzoicacid
Packaging
250g
Price
$215
Updated
2021/12/16
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2-Methoxy-5-sulfamoylbenzoic acid Chemical Properties,Usage,Production

Uses

2-Methoxy-5-sulfamoylbenzoic Acid is a metabolite of the antipsychotic drug, Sulpiride (S689145).

Preparation

Synthesis of 2-methoxy-5-sulfamoyl benzoic Acid: In the amination reaction of 2-methoxyl-5-amino-sulfonyl benzoic acid, the main influence factors were mainly ammonia concentration, reaction temperature and reaction time. Firstly, we investigated two approaches of animation reaction: ventilation with ammonia in solvent and ammonium hydroxide as amino-reactant and solvent. In this section, the way of ventilation with ammonia in methyl alcohol and tetrahydrofuran would cause the rapid reaction, resulting to the incomplete reaction of 2-methoxy-5-sulfamoylbenzoic acid owing to the formation of 2-methoxy-5-sulfamoyl benzoic acid coated on the surface of the reaction. On the contrary, the lab test indicated that the way of ammonium hydroxide as amino-reactant and solvent can provide better experimental results. Secondly, the reactive temperature was the more important factor. The optimized amination temperature was to 30 °C. The low temperature would result to the long amination time, whereas high temperature can result to the generation of by-product owing to the hydrolysis of sulfonyl chloride. Finally, we evaluated the effect of reaction time. The optimized reaction time was to 5 hours. The extended reaction time can’t cause the significant improvement of yield. As a consequence, the best reactive temperature was to 30 °C and the best mole ratio between 2-methoxy-5-sulfonylchlorobenzoic acid and ammonium hydroxide was to 1:20 and the best reactive time was to 5 hours. Under the best conditions, the yield can reach to 75.8%.

2-Methoxy-5-sulfamoylbenzoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methoxy-5-sulfamoylbenzoic acid Suppliers

Hubei Smer Pharmaceutical Technology Co., Ltd.
Tel
15527913960
Email
1784042512@qq.com
Country
China
ProdList
491
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58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
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96815
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
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China
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Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
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sales@chemreagents.com
Country
United States
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10186
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Adamas Reagent, Ltd.
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400-6009262 16621234537
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021-64823266
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chenyj@titansci.com
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China
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Accela ChemBio Co.,Ltd.
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021-50795510 4000665055
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021-50795055
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sales@accelachem.com
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China
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Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
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50
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
021-51613915-820 13611835272
Fax
021 51613951
Email
mmwang@sunwaypharm.cn
Country
China
ProdList
9734
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57
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View Lastest Price from 2-Methoxy-5-sulfamoylbenzoic acid manufacturers

Career Henan Chemical Co
Product
2-Methoxy-5-sulfamoylbenzoic acid 22117-85-7
Price
US $7.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2018-12-21

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