ChemicalBook > CAS DataBase List > 4-Nitro-2-picoline N-oxide

4-Nitro-2-picoline N-oxide

Product Name
4-Nitro-2-picoline N-oxide
CAS No.
5470-66-6
Chemical Name
4-Nitro-2-picoline N-oxide
Synonyms
4-Nitro-2-picoL;2-methyl-4-nitro-p;4-Nitro-2-picoline N;Methyl-4-nitropyridine N-;4-Nitro-a-picoline N-oxide;4-NITRO-2-PICOLINE N-OXIDE;2-Methyl-4-nitropyridine1-one;2-Picoline, 4-nitro-, 1-oxide;2-methyl-4-nitro-pyridin1-oxide;4-Nitro-2-picoline-N-oxide ,98%
CBNumber
CB7453384
Molecular Formula
C6H6N2O3
Formula Weight
154.12
MOL File
5470-66-6.mol
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4-Nitro-2-picoline N-oxide Property

Melting point:
155-159 °C(lit.)
Boiling point:
277.46°C (rough estimate)
Density 
1.4564 (rough estimate)
refractive index 
1.5100 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO, Methanol
pka
-1.18±0.10(Predicted)
form 
powder
color 
yellow to light orange
λmax
333nm(EtOH)(lit.)
BRN 
135501
InChI
InChI=1S/C6H6N2O3/c1-5-4-6(8(10)11)2-3-7(5)9/h2-4H,1H3
InChIKey
FTTIAVRPJGCXAC-UHFFFAOYSA-N
SMILES
C1(C)[N+]([O-])=CC=C([N+]([O-])=O)C=1
CAS DataBase Reference
5470-66-6(CAS DataBase Reference)
NIST Chemistry Reference
4-Nitro-2-picoline-n-oxide(5470-66-6)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38-40
Safety Statements 
22-26-36
RIDADR 
2811
WGK Germany 
3
RTECS 
UT5710000
HazardClass 
6.1
PackingGroup 
III
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
454850
Product name
2-Methyl-4-nitropyridine N-oxide
Purity
97%
Packaging
25g
Price
$386
Updated
2024/03/01
Sigma-Aldrich
Product number
454850
Product name
2-Methyl-4-nitropyridine N-oxide
Purity
97%
Packaging
5g
Price
$79.9
Updated
2023/06/20
TCI Chemical
Product number
M2114
Product name
2-Methyl-4-nitropyridine N-Oxide
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$66
Updated
2024/03/01
TCI Chemical
Product number
M2114
Product name
2-Methyl-4-nitropyridine N-Oxide
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$228
Updated
2024/03/01
Alfa Aesar
Product number
L06614
Product name
4-Nitro-2-picoline N-oxide, 98%
Packaging
5g
Price
$72
Updated
2021/12/16
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4-Nitro-2-picoline N-oxide Chemical Properties,Usage,Production

Chemical Properties

Yellow Solid

Uses

A nitroheterocyclic compound and its potential suitability as radiosensitizer for cancer radiotherapy.

Reactivity Profile

4-Nitro-2-picoline N-oxide could be used to synthesize 2-Methyl-4-nitro-6-(pyridin-2-yl)pyridine 1-oxide which is a key intermediate of Caerulomycin E and A[1].
 

References

[1] Zhang, Fang , and X. F. Duan . "Facile one-pot direct arylation and alkylation of nitropyridine N-oxides with Grignard reagents. " Organic Letters 43.13(2012).

4-Nitro-2-picoline N-oxide Preparation Products And Raw materials

Raw materials

Preparation Products

4-ACETAMIDOPYRIDINE-2-CARBOXYLIC ACID 4-Bromopyridine-2-carboxylic acid 2-Methyl-4-nitropyridine 4-Aminopyridine-2-carboxylic acid 4-Hydroxy-2-methylpyridine 2-METHYL-4-ACETAMIDOPYRIDINE 4-Hydroxypyridine-2-carboxylic acid 4-Amino-2-picoline 4-Bromo-2-methylpyridine
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4-Nitro-2-picoline N-oxide Suppliers

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View Lastest Price from 4-Nitro-2-picoline N-oxide manufacturers

Dideu Industries Group Limited
Product
4-Nitro-2-picoline N-oxide 5470-66-6
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons min
Release date
2021-09-08
Career Henan Chemical Co
Product
4-Nitro-2-picoline N-oxide 5470-66-6
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2018-08-02

5470-66-6, 4-Nitro-2-picoline N-oxideRelated Search:

Methylparaben 2-Picoline 4-Nitropyridine N-oxide Pyridine-N-oxide 2,6-Lutidine 2-Chloro-5-chloromethylpyridine 4-Nitropyridine 4-Methylpyridine 2-Picoline-N-oxide 2-Methyl-4-nitropyridine 2,4,6-Collidine METHYL THIOPHENE-2-CARBOXYLATE Methyl acrylate Kresoxim-methyl Bensulfuron methyl Methyl acetate Thiophanate-methyl Methyl

  • 2-Methyl-4-nitropyridine1-one
  • 4-Nitro-2-picoline N-oxide 2-Methyl-4-nitropyridine 1-oxide
  • 2-Methyl-4-nitropyridine <i>N</i>-Oxide
  • Methyl-4-nitropyridine N-
  • 2- Methyl-4- nitropyridine oxide
  • 2-methyl-4-nitro-pyridin1-oxide
  • 2-Picoline, 4-nitro-, 1-oxide
  • 4-Nitro-2-methylpyridine 1-oxide
  • 4-Nitro-a-picoline N-oxide
  • Pyridine, 2-methyl-4-nitro-, 1-oxide
  • 4-NITRO-2-METHYLPYRIDINE-N-OXIDE
  • 4-NITRO-2-PICOLINE N-OXIDE
  • 4-NITROPYRIDINE-2-PICOLINE-N-OXIDE
  • 4-Nitropyridine-2-methyl-N-oxide
  • 2-Methyl-4-nitro-1-oxidopyridin-1-ium
  • 4-Nitro-2-picoline-N-oxide ,98%
  • 4-Nitro-2-picoline N
  • 2-Methyl-4-nitropyridine 1-oxide (4-Nitro-2-picoline N-oxide)
  • 2-Methyl-4-nitropyridinium-1-olate, 4-Nitro-2-picoline N-oxide
  • 2-Methyl-4-nitro-1$l^{5}-pyridin-1-one
  • 4-Nitro-2-picoline-N-oxide (2-Methyl-4-nitropyridin-N-oxide)
  • 4-NITRO-2-PICOLINE N-OXIDE (2-METHYL-4-NITROPYRIDINE-N-OXIDE)
  • 2-methyl-4-nitro-p
  • 2-METHYL-4-NITROPYRIDINE 1-OXIDE
  • 2-METHYL-4-NITROPYRIDINE N-OXIDE
  • 2-METHYL-4-NITROPYRIDINIUM-1-OLATE
  • 2-Methyl-4-nitropyridineN-Oxide&gt
  • 4-Nitro-2-picoL
  • 4-Nitro-2-picoline N-oxide ISO 9001：2015 REACH
  • 2-Picoline-4-Nitro pyridine-N-oxide
  • Pyridine, 2-methyl-4-nitro-, 1-oxide (9CI, ACI)
  • 2-methyl-4-nitro-Pyridine 1-oxide (9CI ACI)
  • 5470-66-6
  • Building Blocks
  • C6
  • Heterocyclic Building Blocks
  • Pyridines
  • Pyridines, Pyrimidines, Purines and Pteredines
  • Aromatics
  • Bases & Related Reagents
  • Nucleotides
  • C6
  • Heterocyclic Building Blocks
  • blocks
  • NitroCompounds
  • Pyridines
  • Pyridine
  • Aromatics Compounds
  • Heterocycles
  • Nitric Oxide Reagents