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ChemicalBook > CAS DataBase List > 1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene

Reaction
Product Name
1,1'-Bis(diisopropylphosphino)ferrocene
CAS No.
97239-80-0
Chemical Name
1,1'-Bis(diisopropylphosphino)ferrocene
Synonyms
DIPPF;1,1'-Bis(diisopropyL;1,1'-Bis(di-i-propylphosphino)f;cyclopentyl(diisopropyl)phosphane;-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-Bis(di-i-propylphosphino)ferrocene;1,1'-bis-(di-Isopropylphosphino)ferrocene;1,1'-Bis(diisopropylphosphino)ferrocene>1,1'-Bis(diisopropylphosphino)ferrocene,98%
CBNumber
CB8105732
Molecular Formula
C22H36FeP210*
Formula Weight
418.31
MOL File
97239-80-0.mol
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1,1'-Bis(diisopropylphosphino)ferrocene Property

Melting point:
50-52 °C(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange-yellow
Water Solubility 
Insoluble in water.
InChI
InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
InChIKey
LPBBEMRSRONKMN-UHFFFAOYSA-N
SMILES
P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
CAS DataBase Reference
97239-80-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
578266
Product name
1,1′-Bis(diisopropylphosphino)ferrocene
Purity
97%
Packaging
500mg
Price
$196
Updated
2025/07/31
TCI Chemical
Product number
B2710
Product name
1,1'-Bis(diisopropylphosphino)ferrocene
Purity
>98.0%(T)
Packaging
1g
Price
$144
Updated
2025/07/31
TCI Chemical
Product number
B2710
Product name
1,1'-Bis(diisopropylphosphino)ferrocene
Purity
>98.0%(T)
Packaging
100mg
Price
$38
Updated
2025/07/31
Strem Chemicals
Product number
26-0275
Product name
1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF
Packaging
500mg
Price
$61
Updated
2024/03/01
Strem Chemicals
Product number
26-0275
Product name
1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF
Packaging
2g
Price
$179
Updated
2024/03/01
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1,1'-Bis(diisopropylphosphino)ferrocene Chemical Properties,Usage,Production

Reaction

  1. Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
  2. Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
  3. Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
  4. Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
  5. Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
  6. Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
  7. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.





Description

1,1′-Bis(diisopropylphosphino)ferrocene (DiPPF) is a ferrocene-based phosphine ligand frequently is used in electrochemical reaction studies. DiPPF can help support high oxidation states of metal atoms by forming iron interactions and donating electrons via low-energy charge transfer from iron to nickel atoms.

Chemical Properties

orange crystalline powder

Uses

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

1,1'-Bis(diisopropylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Ferrocene Hexane N,N,N',N'-Tetramethylethylenediamine Chlorodiisopropylphosphine n-Butyllithium

Preparation Products

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1,1'-Bis(diisopropylphosphino)ferrocene Suppliers

Americas 1 Belgium 1 China 148 Europe 2 Germany 3 India 3 Japan 3 Russia 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 2 United States 11 Global 178
Aladdin Scientific
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View Lastest Price from 1,1'-Bis(diisopropylphosphino)ferrocene manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
1,1'-bis-(di-Isopropylphosphino)ferrocene 97239-80-0
Price
US $2.00-6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-07-29
WUHAN FORTUNA CHEMICAL CO., LTD
Product
1,1'-Bis(diisopropylphosphino)ferrocene 97239-80-0
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-30
Henan Research New Materials Co., Ltd.
Product
1,1'-Bis(diisopropylphosphino)ferrocene 97239-80-0
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
98％
Supply Ability
100kg
Release date
2024-07-26

97239-80-0, 1,1'-Bis(diisopropylphosphino)ferroceneRelated Search:

1,1'-Bis(di-tert-butylphosphino)ferrocene 1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,2,3,4,5-PENTAPHENYL-1'-(DI-TERT-BUTYLPHOSPHINO)FERROCENE 1,1'-Bis(diphenylphosphino)ferrocene Ferrocene 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, 1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,1-Bis[(2S,3S,4S,5S)-2,5-dimethyl-3,4-O-isopropylidene-3,4-dihydroxyphospholanyl]ferrocene 1,1μ-Bis[(2S,5S)-2,5-diisopropylphospholano]ferrocene S,S-Me-FerrocelaneTM 1,1μ-Bis(diisopropylphosphino)ferrocene(cod)Rh-phosphotungstic acid on alumox (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE(COD)RH-PHOSPHOTUNGSTIC ACID 1,1μ-Bis[(2R,5R)-2,5-diisopropylphospholano]ferrocene 1,1'-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]FERROCENE

  • BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON
  • 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
  • -BIS(DIISOPROPYLPHOSPHINO)FERROCENE
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  • 1,1'-Bis(diisopropylphosphino)ferrocene,98%
  • 1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%
  • 1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene
  • Ferrocene,1,1'-bis[bis(1-Methylethyl)phosphino]-
  • 1,1'-Bis(di-i-propylphosphino)ferrocene,98%
  • cyclopentyl(diisopropyl)phosphane
  • 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF
  • 1,1'-Bis(di-i-propylphosphino)f
  • 1,1'-Bis(diisopropylphosphino)ferrocene&gt
  • 1,1'-Bis(diisopropyL
  • 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE ISO 9001：2015 REACH
  • bis(2-diisopropylphosphanylcyclopenta-1,3-dien-1-yl)iron
  • 1,1'-bis-(di-Isopropylphosphino)ferrocene
  • 1,1'-Bis(di-i-propylphosphino)ferrocene
  • DIPPF
  • 1,1′-Bis(diisopropylphosphino)ferrocene, CAS 97239-80-0
  • 97239-80-0
  • 97239-80-8
  • C22H36FeP210
  • C22H36FeP2
  • 2C11H18PFe
  • Phosphine Ligands
  • Ferrocenes
  • Metallocenes
  • Polydentate Phosphine Ligands
  • Phosphorus Compounds
  • Catalysis and Inorganic Chemistry
  • Achiral Phosphine
  • Aryl Phosphine
  • Ligand
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands