Uses Description
ChemicalBook > CAS DataBase List > (Bromomethyl)cyclopropane

(Bromomethyl)cyclopropane

Uses Description
Product Name
(Bromomethyl)cyclopropane
CAS No.
7051-34-5
Chemical Name
(Bromomethyl)cyclopropane
Synonyms
CYCLOPROPYLMETHYL BROMIDE;Cyclopropane, (bromomethyl)-;CPMBr;(Bromomethyl)cyclopr;(Xiu Jiaji)cyclopropane;BroMoMethyl)cyclopropan;Cyclopropylmethylbromid;Roflumilast impurity 18;CYCLOPROPYLMETYL BROMIDE;Bromo(cyclopropyl)methane
CBNumber
CB8119915
Molecular Formula
C4H7Br
Formula Weight
135
MOL File
7051-34-5.mol
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(Bromomethyl)cyclopropane Property

Melting point:
87-90 °C
Boiling point:
105-107 °C(lit.)
Density 
1.392 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.457(lit.)
Flash point:
107 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
Specific Gravity
1.392
color 
Clear colorless to slightly colored
Water Solubility 
Not miscible in water.
BRN 
605296
Stability:
Stable. Flammable. Incompatible with strong bases, strong oxidizing agents.
InChIKey
AEILLAXRDHDKDY-UHFFFAOYSA-N
CAS DataBase Reference
7051-34-5(CAS DataBase Reference)
NIST Chemistry Reference
Cyclopropane, (bromomethyl)-(7051-34-5)
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Safety

Hazard Codes 
Xi,F,Xn
Risk Statements 
10-36/37/38-22
Safety Statements 
23-24/25-37/39-26-16-36/37/39
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
Hazard Note 
Irritant
HazardClass 
3
PackingGroup 
III
HS Code 
29035990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
242403
Product name
(Bromomethyl)cyclopropane
Purity
97%
Packaging
1g
Price
$54
Updated
2024/03/01
Sigma-Aldrich
Product number
242403
Product name
(Bromomethyl)cyclopropane
Purity
97%
Packaging
5g
Price
$162
Updated
2024/03/01
Alfa Aesar
Product number
L01122
Product name
(Bromomethyl)cyclopropane, 97%
Packaging
1g
Price
$46.4
Updated
2024/03/01
Alfa Aesar
Product number
L01122
Product name
(Bromomethyl)cyclopropane, 97%
Packaging
5g
Price
$132
Updated
2024/03/01
Alfa Aesar
Product number
L01122
Product name
(Bromomethyl)cyclopropane, 97%
Packaging
25g
Price
$522
Updated
2024/03/01
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(Bromomethyl)cyclopropane Chemical Properties,Usage,Production

Uses

(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Description

(Bromomethyl) cyclopropane is a cyclopropane derivative. It can be used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1, 4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Chemical Properties

Colorless to yellow liquid

Uses

(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0

General Description

The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

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(Bromomethyl)cyclopropane Suppliers

Syntor Fine Chemicals Ltd.
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View Lastest Price from (Bromomethyl)cyclopropane manufacturers

Speranza Chemical Co., Ltd.
Product
(Bromomethyl)cyclopropane 7051-34-5
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200 tons/ year
Release date
2020-03-11
HebeiShuoshengImportandExportco.,Ltd
Product
(Bromomethyl)cyclopropane 7051-34-5
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-06
Hebei Yanxi Chemical Co., Ltd.
Product
(Bromomethyl)cyclopropane 7051-34-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
100tons
Release date
2023-09-27

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