Uses Description
ChemicalBook > CAS DataBase List > (Bromomethyl)cyclopropane

(Bromomethyl)cyclopropane

Uses Description
Product Name
(Bromomethyl)cyclopropane
CAS No.
7051-34-5
Chemical Name
(Bromomethyl)cyclopropane
Synonyms
CYCLOPROPYLMETHYL BROMIDE;Cyclopropane, (bromomethyl)-;CPMBr;(Bromomethyl)cyclopr;(Xiu Jiaji)cyclopropane;BroMoMethyl)cyclopropan;Cyclopropylmethylbromid;Roflumilast impurity 18;CYCLOPROPYLMETYL BROMIDE;Bromo(cyclopropyl)methane
CBNumber
CB8119915
Molecular Formula
C4H7Br
Formula Weight
135
MOL File
7051-34-5.mol
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(Bromomethyl)cyclopropane Property

Melting point:
87-90 °C
Boiling point:
105-107 °C(lit.)
Density 
1.392 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.457(lit.)
Flash point:
107 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
Specific Gravity
1.392
color 
Clear colorless to slightly colored
Water Solubility 
Not miscible in water.
BRN 
605296
Stability:
Stable. Flammable. Incompatible with strong bases, strong oxidizing agents.
InChIKey
AEILLAXRDHDKDY-UHFFFAOYSA-N
CAS DataBase Reference
7051-34-5(CAS DataBase Reference)
NIST Chemistry Reference
Cyclopropane, (bromomethyl)-(7051-34-5)
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Safety

Hazard Codes 
Xi,F,Xn
Risk Statements 
10-36/37/38-22
Safety Statements 
23-24/25-37/39-26-16-36/37/39
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
Hazard Note 
Irritant
HazardClass 
3
PackingGroup 
III
HS Code 
29035990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
242403
Product name
(Bromomethyl)cyclopropane
Purity
97%
Packaging
1g
Price
$54
Updated
2024/03/01
Sigma-Aldrich
Product number
242403
Product name
(Bromomethyl)cyclopropane
Purity
97%
Packaging
5g
Price
$162
Updated
2024/03/01
Alfa Aesar
Product number
L01122
Product name
(Bromomethyl)cyclopropane, 97%
Packaging
1g
Price
$46.4
Updated
2024/03/01
Alfa Aesar
Product number
L01122
Product name
(Bromomethyl)cyclopropane, 97%
Packaging
5g
Price
$132
Updated
2024/03/01
Alfa Aesar
Product number
L01122
Product name
(Bromomethyl)cyclopropane, 97%
Packaging
25g
Price
$522
Updated
2024/03/01
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(Bromomethyl)cyclopropane Chemical Properties,Usage,Production

Uses

(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Description

(Bromomethyl) cyclopropane is a cyclopropane derivative. It can be used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1, 4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Chemical Properties

Colorless to yellow liquid

Uses

(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0

General Description

The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

(Bromomethyl)cyclopropane Preparation Products And Raw materials

Raw materials

Tetrahydrofuran Diethyl ether Lithium Aluminum Hydride Cyclopropanecarboxylic acid Phosphorus tribromide

Preparation Products

Cimetropium bromide 2-cyclopropylethanamine Cyclopropylacetic acid
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View Lastest Price from (Bromomethyl)cyclopropane manufacturers

Speranza Chemical Co., Ltd.
Product
(Bromomethyl)cyclopropane 7051-34-5
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200 tons/ year
Release date
2020-03-11
HebeiShuoshengImportandExportco.,Ltd
Product
(Bromomethyl)cyclopropane 7051-34-5
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-06
Hebei Yanxi Chemical Co., Ltd.
Product
(Bromomethyl)cyclopropane 7051-34-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
100tons
Release date
2023-09-27

7051-34-5, (Bromomethyl)cyclopropaneRelated Search:

Cyclopropanecarbonitrile Bromotrimethylsilane Cyclopropylboronic acid BROMOPENTAMETHYLBENZENE 1,1-Bis(hydroxymethyl)cyclopropane Ciprofloxacin Ciprofloxacin lactate CHLORODIBROMOMETHANE Cyclohexylmethyl bromide Cyclopropyl methyl ketone Ciprofloxacin hydrochloride Cyromazine Dibromomethane Sodium bromate Propiconazole Cyclopropane Ethidium bromide Benzyl bromide Cyclopropylmethyl Bromide

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  • (BROMOMETHYL)CYCLOPROPANE 7051-34-5
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  • C4H7Br
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