ChemicalBook > CAS DataBase List > 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER

3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER

Product Name
3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER
CAS No.
82702-31-6
Chemical Name
3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER
Synonyms
RARECHEM AL BF 0277;Methyl 3-bromo-4-fluorobenzene;METHYL 3-BROMO-4-FLUOROBENZOATE;3-bromo-4-fluoro-2-methylbenzoate;Methyl3-bromo-4-fluorobenzoate98%;Methyl 3-bromo-4-fluorobenzoate 98%;3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER;Benzoic acid, 3-bromo-4-fluoro-, methyl ester
CBNumber
CB8164036
Molecular Formula
C8H6BrFO2
Formula Weight
233.03
MOL File
82702-31-6.mol
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3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER Property

Melting point:
26-28
Boiling point:
245.3±20.0 °C(Predicted)
Density 
1.577±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
powder to lump
color 
White to Orange to Green
InChI
InChI=1S/C8H6BrFO2/c1-12-8(11)5-2-3-7(10)6(9)4-5/h2-4H,1H3
InChIKey
JVORYGNKYAXATM-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C(F)C(Br)=C1
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
22
Hazard Note 
Irritant/Keep cold
HS Code 
2916310090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M3018
Product name
Methyl 3-Bromo-4-fluorobenzoate
Purity
>98.0%(GC)
Packaging
1g
Price
$29
Updated
2025/07/31
TCI Chemical
Product number
M3018
Product name
Methyl 3-Bromo-4-fluorobenzoate
Purity
>98.0%(GC)
Packaging
5g
Price
$96
Updated
2025/07/31
TRC
Product number
M295918
Product name
Methyl 3-Bromo-4-fluorobenzoate
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
M295918
Product name
Methyl 3-Bromo-4-fluorobenzoate
Packaging
500mg
Price
$65
Updated
2021/12/16
AK Scientific
Product number
V7890
Product name
Methyl 3-Bromo-4-fluorobenzoate
Packaging
10g
Price
$144
Updated
2021/12/16
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3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Synthesis

67-56-1

1007-16-5

82702-31-6

a) Synthesis of methyl 3-bromo-4-fluorobenzoate 3-Bromo-4-fluorobenzoic acid (3.33 g, 15.2 mmol) was dissolved in methanol (30 mL) and acetyl chloride (4.3 mL, 60.8 mmol) was added slowly and dropwise under cooling in an ice bath. The reaction mixture was stirred at room temperature for 20 hours. After completion of the reaction, the reaction solution was concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: hexane/ethyl acetate) to afford methyl 3-bromo-4-fluorobenzoate (3.2 g, 90% yield) as a colorless oil.1H-NMR (CDCl3) δ: 3.92 (3H, s), 7.18 (1H, dd, J = 8.0, 8.2 Hz), 7.99 (1H, ddd, J = 1.9, 4.9, 8.0 Hz), 7.99 (1H, ddd, J = 1.9, 4.9, 8.0 Hz). 4.9, 8.0 Hz), 8.27 (1H, dd, J = 1.9, 6.5 Hz).

References

[1] European Journal of Medicinal Chemistry, 2007, vol. 42, # 11-12, p. 1334 - 1357
[2] Patent: US2010/280013, 2010, A1. Location in patent: Page/Page column 16
[3] Journal of Enzyme Inhibition and Medicinal Chemistry, 2012, vol. 27, # 5, p. 658 - 665,8
[4] Patent: WO2007/99171, 2007, A2. Location in patent: Page/Page column 55
[5] ACS Medicinal Chemistry Letters, 2013, vol. 4, # 3, p. 358 - 362

3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER Suppliers

Americas 1 China 117 Europe 1 Germany 4 India 6 Italy 1 Japan 1 United Kingdom 5 United States 12 Global 148
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View Lastest Price from 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Methyl 3-bromo-4-fluorobenzoate 82702-31-6
Price
US $0.00-0.00/KG
Min. Order
5mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-07

82702-31-6, 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTERRelated Search:

METHYL 2-BROMO-5-FLUOROBENZOATE Methyl 3-BroMo-5-forMylbenzoate 3-Bromo-2-fluorobenzoic acid methyl ester Methyl 3-bromo-5-iodobenzoate Methyl 4-fluoro-3-nitrobenzoate methyl 3-bromo-4-chlorobenzoate 5-BROMO-2-NITRO-BENZOIC ACID METHYL ESTER Methyl 2-broMo-4-chlorobenzoate Methyl 5-bromo-2-chlorobenzoate 3-AMINO-5-BROMOBENZOATE methyl 3-bromo-5-fluoro-2-methylbenzoate Methyl 3-bromo-4-(trifluoromethyl)benzoate METHYL 3-BROMO-5-CHLOROBENZOATE METHYL 3-BROMO-6-FLUORO-2-METHYLBENZOATE 3-BroMo-5-cyanobenzoic acid Methyl ester Methyl 3-bromo-4-hydroxybenzoate methyl 3-bromo-5-chloro-2-methylbenzoate 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER

  • 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER
  • METHYL 3-BROMO-4-FLUOROBENZOATE
  • RARECHEM AL BF 0277
  • Methyl 3-bromo-4-fluorobenzoate 98%
  • Methyl3-bromo-4-fluorobenzoate98%
  • Methyl 3-bromo-4-fluorobenzene
  • 3-bromo-4-fluoro-2-methylbenzoate
  • Benzoic acid, 3-bromo-4-fluoro-, methyl ester
  • 82702-31-6
  • Acids & Esters
  • Bromine Compounds
  • Fluorine Compounds
  • blocks
  • Bromides
  • Carboxes
  • FluoroCompounds
  • Aromatic Esters