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Isonicotinamide

Product Name
Isonicotinamide
CAS No.
1453-82-3
Chemical Name
Isonicotinamide
Synonyms
PYRIDINE-4-CARBOXAMIDE;IsoniacinaMide;NSC 82353;Isonicotimide;AURORA KA-3066;Isonicotinamid;ISONICOTINAMIDE;4-AMidopyridine;Isonicoitnamide;Isonicotinamide99%
CBNumber
CB8259608
Molecular Formula
C6H6N2O
Formula Weight
122.12
MOL File
1453-82-3.mol
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Isonicotinamide Property

Melting point:
155-157 °C(lit.)
Boiling point:
227.52°C (rough estimate)
Density 
1.2236 (rough estimate)
refractive index 
1.5350 (estimate)
storage temp. 
Store below +30°C.
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Solid
pka
pK1: 3.61(+1) (20°C)
color 
White to Off-White
Water Solubility 
191.7 g/L (37 ºC)
BRN 
2173
LogP
-0.28
CAS DataBase Reference
1453-82-3(CAS DataBase Reference)
NIST Chemistry Reference
4-Pyridinecarboxamide(1453-82-3)
EPA Substance Registry System
Isonicotinamide (1453-82-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
NR9500000
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29333999
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
I17451
Product name
Isonicotinamide
Purity
ReagentPlus , 99%
Packaging
25g
Price
$45.8
Updated
2024/03/01
Sigma-Aldrich
Product number
I17451
Product name
Isonicotinamide
Purity
ReagentPlus , 99%
Packaging
100g
Price
$78.6
Updated
2024/03/01
Sigma-Aldrich
Product number
8.14032
Product name
4-Pyridinecarboxylic acid amide
Purity
for synthesis
Packaging
50g
Price
$71.3
Updated
2022/05/15
TCI Chemical
Product number
I0135
Product name
Isonicotinamide
Purity
>99.0%(HPLC)(T)
Packaging
25g
Price
$29
Updated
2024/03/01
TCI Chemical
Product number
I0135
Product name
Isonicotinamide
Purity
>99.0%(HPLC)(T)
Packaging
500g
Price
$178
Updated
2024/03/01
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Isonicotinamide Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder

Uses

Isonicotinamide is an isomeric analogue of nicotinamide and a metabolite of isonicotinic thioamide. Isonicotinamide strongly inducde apoptosis in human acute myelomonocytic leukemia cells, HL-60.

Application

Isonicotinamide (pyridine-4-carboxamide) can be used as a heterocyclic building block to synthesize:
4-oxo-1,3-thiazinan-3-yl isonicotinamide derivatives as potential anti-tubercular agents.
Organotin(IV) complexes of isonicotinamide via synthesis of phosphoramidate ligands for various biological activity studies.
Bis-pyridinium isonicotinamide derivatives of 2-(hydroxyimino)-N-(pyridin-3-yl)acetamide as potent reactivators sarin.
Isonicotinamide can also be used as a co-former with active pharmaceutical ingredients (APIs) to prepare co-crystals.

Preparation

synthesis of isonicotinamide: In 6g tert-amyl alcohol, add 100mg ferric oxide, 100mg cobalt tetroxide and 100mg manganese dioxide (mass percentage in the mixture: 4.6%), 60mg 4-cyanopyridine (mass percentage in the mixture: 0.91%), 200uL Water (mass percentage in the mixture: 3.0%), mix well; react at 80°C for 24 hours, the conversion rate of 4-cyanopyridine is 99.0%, and the selectivity of the corresponding Isonicotinamide is 99.0%.

Definition

ChEBI: Isonicotinamide is a pyridinecarboxamide that is the monocarboxylic acid amide derivative of isonicotinic acid. It derives from an isonicotinic acid.

Purification Methods

Recrystallise isonicotinamide from hot water or isopropanol (158.5-159o), and dry it in a vacuum at 100o. The picrate crystallises from aqueous EtOH or H2O and has m 217-218o (214-215o). [Beilstein 22 III/IV 527, 22/2 V 195.]

Isonicotinamide Preparation Products And Raw materials

Raw materials

Preparation Products

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Isonicotinamide Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
K. Sakai & Co., Ltd.
Tel
--
Fax
--
Email
em@ksakai.co.jp
Country
Japan
ProdList
957
Advantage
58
Koa And Company,Ltd
Tel
--
Fax
--
Email
koa@koa-company.jp
Country
Japan
ProdList
24
Advantage
58
FUJIFILM Wako Pure Chemical Corporation
Tel
--
Fax
--
Email
ffwk-cservice@fujifilm.com
Country
Japan
ProdList
6222
Advantage
58
Fine Corporation
Tel
--
Fax
--
Email
info@fine-c.jp
Country
Japan
ProdList
1427
Advantage
58
ChemICHIBA (Namiki Shoji Co., Ltd.)
Tel
--
Fax
--
Country
Japan
ProdList
634
Advantage
0
Junsei Chemical Co., Ltd.
Tel
--
Fax
--
Email
shiyaku@junsei.co.jp
Country
Japan
ProdList
3096
Advantage
46
Nacalai Tesque, Inc.
Tel
--
Fax
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Email
info-tech@nacalai.co.jp
Country
Japan
ProdList
6046
Advantage
75
Koei Chemical Company, Ltd.
Tel
--
Fax
--
Country
Japan
ProdList
497
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Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from Isonicotinamide manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Isonicotinamide 1453-82-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-17
HebeiShuoshengImportandExportco.,Ltd
Product
Isonicotinamide 1453-82-3
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-08
Hebei Longbang Technology Co., Ltd
Product
Isonicotinamide 1453-82-3
Price
US $6.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-04-29

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