ChemicalBook > CAS DataBase List > 4-Bromobenzenesulfonyl chloride

4-Bromobenzenesulfonyl chloride

Product Name
4-Bromobenzenesulfonyl chloride
CAS No.
98-58-8
Chemical Name
4-Bromobenzenesulfonyl chloride
Synonyms
4-bromobenzene-1-sulfonyl chloride;4-BromobenzenesuL;p-Brosyl chloride;AKOS BBS-00004603;4-Bromobenzenesulfon;4-Bromo-Benzenesulfonyl;(4-Bromophenyl)chlorosulfone;Bromobenzenesulfonylchloride;4-Bromobenzenesulfonylbromide;4-Bromobenzenesulfonyl chlori
CBNumber
CB8443863
Molecular Formula
C6H4BrClO2S
Formula Weight
255.52
MOL File
98-58-8.mol
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4-Bromobenzenesulfonyl chloride Property

Melting point:
73-75 °C (lit.)
Boiling point:
153 °C/15 mmHg (lit.)
Density 
1.7910 (estimate)
Flash point:
152-154°C/26mm
storage temp. 
Refrigerator, Under Inert Atmosphere
solubility 
soluble in Chloroform, DMSO
form 
Crystals or Crystalline Powder
color 
White to beige
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
Merck 
14,1407
BRN 
743518
CAS DataBase Reference
98-58-8(CAS DataBase Reference)
EPA Substance Registry System
Benzenesulfonyl chloride, 4-bromo- (98-58-8)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29049020
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
108669
Product name
4-Bromobenzenesulfonyl chloride
Purity
98%
Packaging
25g
Price
$61.6
Updated
2024/03/01
Sigma-Aldrich
Product number
108669
Product name
4-Bromobenzenesulfonyl chloride
Purity
98%
Packaging
100g
Price
$116
Updated
2024/03/01
TCI Chemical
Product number
B0550
Product name
4-Bromobenzenesulfonyl Chloride
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$56
Updated
2024/03/01
TCI Chemical
Product number
B0550
Product name
4-Bromobenzenesulfonyl Chloride
Purity
>98.0%(GC)(T)
Packaging
500g
Price
$936
Updated
2024/03/01
Alfa Aesar
Product number
A15909
Product name
4-Bromobenzenesulfonyl chloride, 98+%
Packaging
25g
Price
$50.65
Updated
2024/03/01
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4-Bromobenzenesulfonyl chloride Chemical Properties,Usage,Production

Chemical Properties

white to beige crystals or crystalline powder

Uses

4-Bromobenzenesulfonyl chloride is used as activating agent in the synthesis of oligodeoxyribo- and oligoribo- nucleotides in solution. It also used in the synthesis of 4-(N-allylsulfamoyl)phenylboronic acid and in protection of amines as 4-bromobenzenesulfonamides.

Uses

4-Bromobenzenesulfonyl chloride is used for identification of amines, and also in the synthesis and inhibition studies of substituted N-L-histidinylphenylsulfonyl hydrazide.

Uses

Identification of amines.

Synthesis Reference(s)

Synthesis, p. 1203, 1992 DOI: 10.1055/s-1992-26333

Purification Methods

Wash the sulfonyl chloride with cold water, dry and recrystallise it from pet ether, or from ethyl ether cooled in powdered Dry-Ice after the ether solution had been washed with 10% NaOH until colourless, then dry it with anhydrous Na2SO4. Alternatively dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and recrystallise it. [Huntress & Carten J Am Chem Soc 62 511 1940.] Test for the SO2Cl group by dissolving it in EtOH and boiling with NH4CNS whereby a yellow amorphous precipitate forms on cooling. [Beilstein 11 IV 162.]

4-Bromobenzenesulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

4-(Aminosulfonyl)phenylboronic acid 4-SULFAMOYLPHENYLBORONIC ACID, PINACOL ESTER
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4-Bromobenzenesulfonyl chloride Suppliers

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View Lastest Price from 4-Bromobenzenesulfonyl chloride manufacturers

R&D Scientific Inc.
Product
4-Bromobenzenesulfonyl chloride 98-58-8
Price
US $786.00/Kg
Min. Order
1Kg
Purity
99 %
Supply Ability
500 Kg
Release date
2024-11-15
Henan Fengda Chemical Co., Ltd
Product
4-Bromobenzenesulfonyl chloride 98-58-8
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Honest Joy Holdings Limited
Product
4-Bromobenzenesulfonyl chloride 98-58-8
Price
US $0.00/KG
Min. Order
1KG
Purity
97.2%
Supply Ability
100 tons
Release date
2022-02-18

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