2-(Dimethylamino)ethyl acrylate Property

Melting point:

-60°C

Boiling point:

64 °C12 mm Hg(lit.)

Density 

0.943 g/mL at 25 °C(lit.)

vapor pressure 

0.35 psi ( 20 °C)

refractive index 

n20/D 1.438(lit.)

Flash point:

138 °F

storage temp. 

2-8°C

pka

8.21±0.28(Predicted)

form 

clear liquid

color 

Colorless to Light yellow to Light orange

Water Solubility 

Soluble in water (1.000 g/L at 20°C).

Sensitive 

Light Sensitive

BRN 

1099119

CAS DataBase Reference

2439-35-2(CAS DataBase Reference)

NIST Chemistry Reference

2-Propenoic acid, 2-(dimethylamino)ethyl ester(2439-35-2)

EPA Substance Registry System

2-(Dimethylamino)ethyl acrylate (2439-35-2)

Safety

Hazard Codes 

T+,N

Risk Statements 

24/25-26-34-50-43-21/22

Safety Statements 

26-28-36/37/39-45-61

RIDADR 

UN 3302 6.1/PG 2

WGK Germany 

2

RTECS 

AS8578000

TSCA 

Yes

HazardClass 

6.1

PackingGroup 

II

HS Code 

29221990

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H330Fatal if inhaled

H400Very toxic to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

2-(Dimethylamino)ethyl acrylate Chemical Properties,Usage,Production

Uses

This compound was used as a reagent for investigating the hydrolytic stability of poly((2-​dimethylamino)​ethyl methacrylate) and comparing with the stability of its monomer. The result has been ascribed to a coordination of the protonated dimethylamino group and the ester carbonyl, rendering the ester more susceptible to nucleophilic attack of a hydroxyl ion.

Uses

2-(Dimethylamino)ethyl acrylate (AmAc) are aminoacrylates. AmAc was used to fabricate gold/acrylic polymer nanocomposites.1 2-(dimethylamino)ethyl acrylate (DAEA) can undergo copolymerization with 2-acrylamido-2-methylpropanesulphonic acid (AMPS).

Application

2-(Dimethylamino)ethyl acrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals, as a catalytic agent, as a petrochemical additive and agrochemicals.

General Description

A colorless to light yellow liquid with an acrid odor. Insoluble in water and floats on water. Irritates the eyes and produces tears.

Air & Water Reactions

Highly flammable. Insoluble in water. Dimethylaminoethyl acrylate hydrolyzes slowly in water to produce acrylic acid and dimethylaminoethanol.

Reactivity Profile

Lachrymater. The reactive groups, in this substance, are the amine and ester and their possible reactivity concerns are listed below: Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Health Hazard

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Dimethylaminoethyl acrylate is flammable.

Flammability and Explosibility

Non flammable