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Ethyl thiophene-3-carboxylate

Product Name
Ethyl thiophene-3-carboxylate
CAS No.
5751-80-4
Chemical Name
Ethyl thiophene-3-carboxylate
Synonyms
THOO2;3-thenoate;ethyl 3-thenoate;RARECHEM AL BI 0549;ETHYL 3-THIENYLACETATE;ETHYL 3-THIOPHENEACETATE;ETHYL THIOPHENE-3-ACETATE;Thiophene -3-ethyl forMate;Ethyl thiophen-3-carboxylate;ETHYL THIOPHENE-3-CARBOXYLATE
CBNumber
CB8737087
Molecular Formula
C7H8O2S
Formula Weight
156.2
MOL File
5751-80-4.mol
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Ethyl thiophene-3-carboxylate Property

Boiling point:
97-98 °C (8 mmHg)
Density 
1.12
refractive index 
1.509-1.511
Flash point:
103 °C
storage temp. 
Keep in dark place,Sealed in dry,2-8°C
form 
clear liquid
color 
Colorless to Light yellow to Light orange
Water Solubility 
Soluble in water.
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Safety

Safety Statements 
24/25-23
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
E1082
Product name
Ethyl 3-Thiophenecarboxylate
Purity
>95.0%(GC)
Packaging
1g
Price
$31
Updated
2025/07/31
TCI Chemical
Product number
E1082
Product name
Ethyl 3-Thiophenecarboxylate
Purity
>95.0%(GC)
Packaging
5g
Price
$121
Updated
2025/07/31
TRC
Product number
E818128
Product name
EthylThiophene-3-carboxylate
Packaging
10mg
Price
$45
Updated
2021/12/16
TRC
Product number
E818128
Product name
EthylThiophene-3-carboxylate
Packaging
50mg
Price
$60
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK172772
Product name
Ethylthiophene-3-carboxylate
Purity
98%
Packaging
25g
Price
$490
Updated
2021/12/16
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Ethyl thiophene-3-carboxylate Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

Ethyl thiophene-3-carboxylate is used as an intermediate in organic syntheses

Synthesis

64-17-5

88-13-1

5751-80-4

Thirteen mL (200 mmol) of thionyl chloride was added slowly and dropwise at 0 °C to a 100 mL ethanol solution containing 9 g (70 mmol) of 3-thiophenecarboxylic acid and 86 mg (0.7 mmol) of 4-dimethylaminopyridine. The reaction mixture was gradually warmed from 0 °C to room temperature over 48 h with continuous stirring. Subsequently, the reaction solution was evaporated to dryness. The resulting residue was purified by silica column chromatography with the eluent being a 1:1 heptane/dichloromethane solvent mixture. Finally 10 g (91% yield) of ethyl thiophene-3-carboxylate was obtained.

References

[1] Patent: WO2004/113331, 2004, A1. Location in patent: Page 38-39
[2] Organic Process Research and Development, 2017, vol. 21, # 7, p. 947 - 955
[3] Organic Letters, 2008, vol. 10, # 9, p. 1851 - 1854
[4] Angewandte Chemie - International Edition, 2017, vol. 56, # 33, p. 9924 - 9929
[5] Angew. Chem., 2017, vol. 129, p. 10056 - 10061,6

Ethyl thiophene-3-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyl thiophene-3-carboxylate Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
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61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
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JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
15883
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
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View Lastest Price from Ethyl thiophene-3-carboxylate manufacturers

Career Henan Chemical Co
Product
Ethyl thiophene-3-carboxylate 5751-80-4
Price
US $1.00/KG
Min. Order
1KG
Purity
97-99%
Supply Ability
1000KGS
Release date
2019-12-18

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