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Dimethyl 2,6-Pyridinedicarboxylate

Product Name
Dimethyl 2,6-Pyridinedicarboxylate
CAS No.
5453-67-8
Chemical Name
Dimethyl 2,6-Pyridinedicarboxylate
Synonyms
DIMETHYL PYRIDINE-2,6-DICARBOXYLATE;20g;dimethyl pyridine-2,6-carboxylate;Pyridine-2,6-dicarboxylic acid dimethyl ester;AKOS 90661;20G/100G/1KG;RARECHEM AL BF 0203;Dimethyl2,6-pyridin;pyridine-2,6-carboxyL;DIMETHYL DIPICOLINATE
CBNumber
CB9118465
Molecular Formula
C9H9NO4
Formula Weight
195.17
MOL File
5453-67-8.mol
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Dimethyl 2,6-Pyridinedicarboxylate Property

Melting point:
121-125 °C(lit.)
Boiling point:
100 °C(Press: 0.005 Torr)
Density 
1.231±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform
pka
-0.46±0.10(Predicted)
form 
Solid
color 
Off-White
Water Solubility 
Soluble in water(14 g/L) (25°C). Soluble in chloroform.
InChI
InChI=1S/C9H9NO4/c1-13-8(11)6-4-3-5-7(10-6)9(12)14-2/h3-5H,1-2H3
InChIKey
SNQQJEJPJMXYTR-UHFFFAOYSA-N
SMILES
C1(C(OC)=O)=NC(C(OC)=O)=CC=C1
CAS DataBase Reference
5453-67-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
37/38-41
Safety Statements 
26-39
WGK Germany 
3
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
379336
Product name
Dimethyl 2,6-pyridinedicarboxylate
Purity
99%
Packaging
10g
Price
$36.4
Updated
2024/03/01
Sigma-Aldrich
Product number
379336
Product name
Dimethyl 2,6-pyridinedicarboxylate
Purity
99%
Packaging
50g
Price
$69.2
Updated
2024/03/01
TCI Chemical
Product number
P1444
Product name
Dimethyl 2,6-Pyridinedicarboxylate
Purity
>98.0%(GC)
Packaging
5g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
P1444
Product name
Dimethyl 2,6-Pyridinedicarboxylate
Purity
>98.0%(GC)
Packaging
25g
Price
$88
Updated
2024/03/01
Alfa Aesar
Product number
H32251
Product name
Dimethyl pyridine-2,6-dicarboxylate, 98%
Packaging
10g
Price
$52.65
Updated
2024/03/01
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Dimethyl 2,6-Pyridinedicarboxylate Chemical Properties,Usage,Production

Chemical Properties

Off-White Solid

Uses

Dimethyl 2,6-pyridinedicarboxylate may be used in the synthesis of:

  • ditopic macrocycle having two xylyl rings linked by diethylene glycol and 2,6-pyridinediamide spacers, which acts as host molecule capable of forming complexes with diphenylurea derivatives
  • N,N′-bis(2-aminoethyl)dipicoloinic acid diamide Schiff base
  • 1,1′-(2,6-bispyridyl)bis-3-(9-ethylcarbazole-3-yl)-1,3-propanedione

Application

Dimethyl 2,6-pyridinedicarboxylate could be used as a starting material to synthesize four pyridine-bridged bis pyrazole ligands by Claisen condensation[1]. These ligands could be further treated with UCl4 to yield the corresponding novel mononuclear uranium(IV) complexes [UIV(R′′′2L)(Cl)4].    

General Description

The standard molar enthalpy of formation for dimethyl 2,6-pyridinedicarboxylate (dimethylpyridine-2,6-dicarboxylate) has been calculated from the standard molar enthalpy of combustion, which was measured by a static bomb calorimeter.

storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

References

[1] Korzekwa, Jana , et al. "Synthesis and characterization of uranium(IV) tetrachloro complexes in bis-pyrazolylpyridine ligand environments." Dalton Transactions (2017):10.1039.C7DT02947K.

Dimethyl 2,6-Pyridinedicarboxylate Preparation Products And Raw materials

Raw materials

Pyridine-2,6-dicarboxylic acid Chloroform Methanol Sulfuric acid

Preparation Products

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Dimethyl 2,6-Pyridinedicarboxylate Suppliers

Americas 1 Belgium 3 Canada 2 China 235 Europe 1 France 1 Germany 9 India 30 Japan 2 Russia 1 Slovakia 1 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 6 United States 36 Global 331
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Kanto Chemical Co. Inc.
Tel
--
Fax
--
Email
kanto-61@gms.kanto.co.jp
Country
Japan
ProdList
530
Advantage
58
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View Lastest Price from Dimethyl 2,6-Pyridinedicarboxylate manufacturers

Hebei Zhanyao Biotechnology Co. Ltd
Product
DIMETHYL 2,6-PYRIDINEDICARBOXYLATE 5453-67-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 TONS
Release date
2021-10-15
Hebei Zhanyao Biotechnology Co. Ltd
Product
DIMETHYL 2,6-PYRIDINEDICARBOXYLATE 5453-67-8
Price
US $10.00/Kg/Bag
Min. Order
1Kg/Bag
Purity
99%
Supply Ability
20 Tons
Release date
2021-11-10
Dideu Industries Group Limited
Product
DIMETHYL 2,6-PYRIDINEDICARBOXYLATE 5453-67-8
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-10-22

5453-67-8, Dimethyl 2,6-PyridinedicarboxylateRelated Search:

DIMETHYL 2,3-PYRIDINEDICARBOXYLATE PYRIDINE-3,4-DICARBOXYLIC ANHYDRIDE Diethyl 2,6-pyridinedicarboxylate dimethyl 4-chloropyridine-2,6-dicarboxylate Dimethyl 2,6-Pyridinedicarboxylate DIMETHYL 2,5-PYRIDINEDICARBOXYLATE DIETHYL 4-ETHYL-1,4-DIHYDRO-2,6-DIMETHYL-3,5-PYRIDINEDICARBOXYLATE,diethyl 4-ethyl-dihydro-dimethyl-3,5-pyridinedicarboxylate DIETHYL1,4-DIHYDRO-2,6-DIMETHYL-3,5-PYRIDINEDICARBOXYLATE(DILUDIN),DIETHYL 1,4-DIHYDRO-2,6-DIMETHYL-3,5-PYRIDINEDICARBOXYLATE DIETHYL 2,6-DIMETHYL-3,5-PYRIDINEDICARBOXYLATE Ethyl methyl 4-(2,3-dichlorophenyl)-1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Diethyl 4-ethoxy-2,6-pyridinedicarboxylate 2,2',6,6'-TETRAKIS(METHOXYCARBONYL)-4,4'-BIPYRIDINE DIETHYL 4-CHLORO-2,6-PYRIDINEDICARBOXYLATE Dimethyl 2-bromo-2,6-pyridinedicarboxylate Diethyl 4-iodo-2,6-pyridinedicarboxylate Dimethyl 4-methoxy-2,6-Pyridinedicarboxylate Diethyl 4-bromopyridine-2,6-dicarboxylate [4,4'-BIPYRIDINE]-2,2',6,6'-TETRACARBOXYLIC ACID TETRAETHYL ESTER

  • RARECHEM AL BF 0203
  • dimethyl pyridine-2,6-carboxylate
  • 2,6-PYRIDINEDICARBOXYLIC ACID DIMETHYL ESTER
  • DIPICOLINIC ACID DIMETHYL ESTER
  • DIMETHYL 2,6-PYRIDINEDICARBOXYLATE
  • DIMETHYL DIPICOLINATE
  • DIMETHYL PYRIDINE-2,6-DICARBOXYLATE
  • AKOS 90661
  • Pyridine-2,6-dicarboxylic acid dimethyl ester
  • 2,6-diMethyl pyridine-2,6-dicarboxylate
  • pyridine-2,6-carboxyL
  • 20G/100G/1KG
  • Dimethyl Dipicolinate Dipicolinic Acid Dimethyl Ester 2,6-Pyridinedicarboxylic Acid Dimethyl Ester
  • 20g
  • DiMethyl 2,6-pyridinedicarbox
  • Dimethylpyridine-2,6-dicarboxylate,98%
  • Dimethyl 2,6-pyridinedicarboxylate 99%
  • Dimethyl 2,6-pyridinecarboxylate
  • 2,6-pyridinedicarboxylate
  • Dimethyl2,6-pyridin
  • Dimethyl2,6-Pyridinedicarboxylate&gt
  • 2,6-Pyridinedicarboxylic acid, 2,6-dimethyl ester
  • DIMETHYL 2,6-PYRIDINEDICARBOXYLATE ISO 9001：2015 REACH
  • 2,6-Pyridine Dicarboxylic Acid Methyl Ester
  • 5453-67-8
  • 5458-67-8
  • Heterocyclic Building Blocks
  • Pyridines
  • Building Blocks
  • C9 to C46
  • Heterocycle-Pyridine series
  • Building Blocks
  • C8 to C9
  • Chemical Synthesis
  • Heterocyclic Building Blocks
  • C9 to C46
  • Heterocyclic Building Blocks
  • Aromatics
  • Heterocycles
  • blocks
  • Carboxes
  • Pyridines
  • Heterocyclic Compounds