ChemicalBook > CAS DataBase List > 2-FLUORO-6-IODOBENZOIC ACID

2-FLUORO-6-IODOBENZOIC ACID

Product Name: 2-FLUORO-6-IODOBENZOIC ACID
CAS No.: 111771-08-5
Chemical Name: 2-FLUORO-6-IODOBENZOIC ACID
Synonyms: CAS:111771-08-5;TIMTEC-BB SBB006699;RARECHEM AL BO 0280;2-Fluoro-6-iodobenzoic;2-FLUORO-6-IODOBENZOATE;2-FLUORO-6-IODOBENZOIC ACID;2-Fluoro-6-iodobenzoicAcid>2-Fluoro-6-iodobenzoicacid98%;Benzoic acid, 2-fluoro-6-iodo-;2-Fluoro-6-iodobenzoic acid 98%
CBNumber: CB9716814
Molecular Formula: C7H4FIO2
Formula Weight: 266.01
MOL File: 111771-08-5.mol

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2-FLUORO-6-IODOBENZOIC ACID Property

Melting point:: 123-126 °C (lit.)
Boiling point:: 301.6±27.0 °C(Predicted)
Density: 1.9575 (estimate)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Methanol
pka: 1.93±0.10(Predicted)
form: Powder
color: Yellow to light brown
Sensitive: Light Sensitive
BRN: 4982371
CAS DataBase Reference: 111771-08-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 429910
Product name: 2-Fluoro-6-iodobenzoic acid
Purity: 97%
Packaging: 5g
Price: $214
Updated: 2025/07/31

TCI Chemical

Product number: F0796
Product name: 2-Fluoro-6-iodobenzoic Acid
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $26
Updated: 2025/07/31

TCI Chemical

Product number: F0796
Product name: 2-Fluoro-6-iodobenzoic Acid
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $73
Updated: 2025/07/31

TRC

Product number: F591983
Product name: 2-Fluoro-6-iodobenzoic Acid
Packaging: 500mg
Price: $65
Updated: 2021/12/16

TRC

Product number: F591983
Product name: 2-Fluoro-6-iodobenzoic Acid
Packaging: 100mg
Price: $45
Updated: 2021/12/16

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2-FLUORO-6-IODOBENZOIC ACID Chemical Properties,Usage,Production

Chemical Properties

yellow to light brown powder

Uses

2-Fluoro-6-iodobenzoic acid may be used for the synthesis of fluoro-substituted benzoyl chlorides. It may be used for the one-pot regioselective synthesis of isocoumarins.

General Description

2-Fluoro-6-iodobenzoic acid is loose white crystal. It can be synthesized by using 2-amino-6-fluorobenzoic acid as the starting material.

Synthesis

124-38-9

1121-86-4

111771-08-5

At -70°C, n-butyllithium (n-BuLi, 120 mL) was slowly added dropwise to an ether (300 mL) solution of diisopropylamine (33.33 g, 330.00 mmol). The resulting solution was stirred continuously at -70 °C for 1 h. Subsequently, a solution of 1-fluoro-3-iodobenzene (22.2 g, 100.00 mmol) in ether (100 mL) was added. After continued stirring at -70 °C for 1 h, carbon dioxide (CO2, gas) was passed into the reaction mixture. The reaction mixture was stirred at -50°C for 1 hour. After the reaction was completed, the reaction mixture was extracted with deionized water (1 x 300 mL). The pH of the aqueous layer was adjusted to 1 by dropwise addition of 4 M hydrochloric acid (HCl), followed by extraction of the aqueous layer with ethyl acetate (EtOAc, 3 × 300 mL). The organic layers were combined, washed with saturated saline (2 × 100 mL), dried over anhydrous sodium sulfate (Na2SO4), and concentrated to dryness under reduced pressure to afford 8 g (33% yield) of 2-fluoro-6-iodobenzoic acid as a yellow solid.

References

[1] European Journal of Organic Chemistry, 2002, # 19, p. 3351 - 3358
[2] Synthesis, 2005, # 4, p. 617 - 621
[3] Patent: WO2008/103615, 2008, A1. Location in patent: Page/Page column 41

2-FLUORO-6-IODOBENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-FLUORO-6-IODOBENZOIC ACID manufacturers

Career Henan Chemical Co

Product: 2-FLUORO-6-IODOBENZOIC ACID 111771-08-5
Price: US $8.80/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 100kg
Release date: 2019-07-12

111771-08-5, 2-FLUORO-6-IODOBENZOIC ACIDRelated Search:

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RARECHEM AL BO 0280

TIMTEC-BB SBB006699

2-FLUORO-6-IODOBENZOIC ACID

2-Fluoro-6-iodobenzoic

2-Fluoro-6-iodobenzoic acid 98%

2-Fluoro-6-iodobenzoicacid98%

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2-Fluoro-6-iodobenzoicAcid&gt

Benzoic acid, 2-fluoro-6-iodo-

2-FLUORO-6-IODOBENZOATE

CAS:111771-08-5

111771-08-5

C7H4FIO2

FC6H3ICO2H

C7H3FIO2

CARBOXYLIC ACID

Building Blocks

Organic Building Blocks

Carboxylic Acids

Carbonyl Compounds

Fluorine series

Carbonyl Compounds

Carboxylic Acids