GUM GUAIAC Chemical Properties

Melting point:

85 °C (dec.)(lit.)

Merck 

13,4566

Safety Information

Hazard Codes 

Xn

Risk Statements 

22

Safety Statements 

36

WGK Germany 

3

RTECS 

ME6260000

Hazardous Substances Data

9000-29-7(Hazardous Substances Data)

Toxicity

LD50 orally in rats: >5000 mg/kg (Jenner)

MSDS

• Language:English Provider:SigmaAldrich

GUM GUAIAC Usage And Synthesis

Description

Bulnesia sarmienti Lor. is a wild tree 3 to 4 m (10 to 13 ft.) high, widespread in the woods of Argentina and in the Gran Chaco area of Paraguay. This variety yields the true guaiac, Guaiacum officinale L., also a tree native to tropical America (Caribbean Islands), grows wild or cultivated in Venezuela, Jamaica, Cuba, and Colombia. This variety yields a resinous substance from which a tincture is prepared. The wood and sawdust from the tree are the parts used. Guaiac has a soft, pleasant, rose-like odor reminiscent of tea roses.
The essential oil is obtained by steam distillation of chipped wood of B. sormienti in approximately 3% yields. It is a thick, viscous, orange-brown mass with a woody, rose-like odor reminiscent of tea rose. Sometimes the oil exhibits a smoky note. The main constituent of the oil, also known as champaca wood oil, is guaiol, a sesquiterpene alcohol (85%).
The derivatives are fluid extract, tincture (mainly from G. officinale L.). The tincture is generally a 10% solution in 60% ethanol. The fluid extract is a reddish-brown liquid with a pleasant odor and burning, bitter taste.

Chemical Properties

Bulnesia sarmienti Lor is a wild tree 3 to 4 m high, widespread in the woods of Argentina and in the Gran Chaco area of Paraguay This variety yields the true guaiac G offcinale L , also a tree native to tropical America (Caribbean Islands), grows wild or cultivated in Venezuela, Jamaica, Cuba and Colombia This variety yields a resinous substance from which a tincture is prepared The gum occurs as irregular masses enclosing fragments of vegetable tissues, or in large, nearly homogeneous masses and occasion- ally in more or less rounded or ovoid tears The wood and sawdust from the tree are the parts used Guaiac has a soft, pleasant, rose- like odor reminiscent of tea roses and a slightly acrid taste.

Chemical Properties

Brownish lumps. Mp 85C. Insoluble in water; soluble in alcohol, ether, acetone, chloroform, and caustic soda.

Physical properties

Externally, the gum is brownish-black to dusky-brown, acquiring a greenish color on long expo- sure; the fractured surface has a glassy luster The thin pieces are transparent and vary in color from brown- to yellowish-orange The powder is moderate yel.

Uses

Clinical reagent (blood or hemoglobin).

Uses

The Nobles test can be performed using 67% (w/v) gum guaiac diluted in 96% ethanol to analyze the level of extracellular oxidase production

Definition

A resin from certain Mexican and West Indian trees, especially Guaiacum santum and G. officinale.

GUM GUAIAC(9000-29-7)Related Product Information

• (-)-GUAIOL
• Guaiacol
• GUAIACYLGLYCEROL-BETA-GUAIACYL ETHER
• Tosylmethyl isocyanide
• SALCOMINE
• Ethyl isocyanoacetate
• N-BUTYLISOCYANIDE
• TERT-BUTYL ISOCYANIDE
• DICHLORO(ETHYLENEDIAMINE)PLATINUM(II)
• 2,4-PENTANEDIONE, SILVER DERIVATIVE
• Tris(2,4-pentanedionato)chroMiuM(III)
• Benzyl isocyanide
• PHENYLSELENOL
• Ferric acetylacetonate
• TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III)
• TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III)
• COBALT(II) ACETYLACETONATE
• Cupric acetylacetonate