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2,4-Dihydroxy-3-nitropyridine

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2,4-Dihydroxy-3-nitropyridine Basic information

Product Name:
2,4-Dihydroxy-3-nitropyridine
Synonyms:
  • 2,4-DIHYDROXY-3-NITROPYRIDINE
  • 4,6-DIHYDROXY-5-NITRO PYRIDINE
  • 3-NITRO-2,4-PYRIDINEDIOL
  • 4-Hydroxy-3-nitro-2-pyridone
  • 2,4-Hydroxy-3-nitropyridine.
  • 2(1H)-Pyridinone, 4-hydroxy-3-nitro-
  • 2,4-Dihydroxy-3-nitropyridine ,99%
  • 4-Dihydroxy-3-nitropyridine
CAS:
89282-12-2
MF:
C5H4N2O4
MW:
156.1
Product Categories:
  • Pyridine Series
  • Heterocycle-Pyridine series
  • Heterocycles
  • Pyridine
Mol File:
89282-12-2.mol
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2,4-Dihydroxy-3-nitropyridine Chemical Properties

Melting point:
265°C (dec.)
Boiling point:
305.6±42.0 °C(Predicted)
Density 
1.65±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
pka
4.50±1.00(Predicted)
color 
Light yellow to Yellow to Green
BRN 
149558
InChI
InChI=1S/C5H4N2O4/c8-3-1-2-6-5(9)4(3)7(10)11/h1-2H,(H2,6,8,9)
InChIKey
BKYGVGWYPFVKTK-UHFFFAOYSA-N
SMILES
C1(=O)NC=CC(O)=C1[N+]([O-])=O
CAS DataBase Reference
89282-12-2(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-37
RIDADR 
3335
HS Code 
29333990

MSDS

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2,4-Dihydroxy-3-nitropyridine Usage And Synthesis

Chemical Properties

Yellow powder

Reactions

2,4-Dihydroxy-3-nitropyridine could be quickly transformed into 5-bromo-2,4-dihydroxy-3-nitropyridine by the action of a solution of bromine. 3.5 g of 2,4-Dihydroxy-3-nitropyridine were heated with a mixture of 1.15 ml of bromine and 30 ml of acetic acid at 70℃ for 15 minutes. When the reaction mixture was cooled with ice, 3.7 g of 5-bromo-2,4-dihydroxy-3-nitropyridine separated out[1]. Yield: 70 %

References

[1] Kolder, C. R. , and H. J. D. Hertog . Migration of halogen atoms in halogeno-derivatives of 2,4-dihydroxypyridine (II). Recueil des Travaux Chimiques des Pays-Bas 72.10(2010):853-858.

2,4-Dihydroxy-3-nitropyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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