ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Esters > Ethyl compound > Diethyl 1,1-cyclopropanedicarboxylate
Diethyl 1,1-cyclopropanedicarboxylate
Diethyl 1,1-cyclopropanedicarboxylate Basic information
- Product Name:
- Diethyl 1,1-cyclopropanedicarboxylate
- Synonyms:
-
- 1,1-CYCLOPROPANEDICARBOXYLIC ACID DIETHYL ESTER
- RARECHEM AL BO 0836
- CYCLOPROPANE-1,1-DICARBOXYLIC ACID DIETHYL ESTER
- DIETHYL 1,1-CYCLOPROPANEDICARBOXYLATE
- DIETHYL CYCLOPROPANE-1,1-DICARBOXYLATE
- DIETHYL 1,1-CYCLOPROPANEDICARBOXYLATE, 9 7%
- DiethyldifluoroMalonate96%
- 1,1-Bis(ethoxycarbonyl)cyclopropane
- CAS:
- 1559-02-0
- MF:
- C9H14O4
- MW:
- 186.21
- EINECS:
- 216-321-6
- Product Categories:
-
- Building Blocks
- C8 to C9
- Aliphatics
- Carbonyl Compounds
- Chemical Synthesis
- Organic Building Blocks
- Cyclopropanes
- Simple 3-Membered Ring Compounds
- Cycloalkanes
- C8 to C9
- Carbonyl Compounds
- Esters
- bc0001
- Mol File:
- 1559-02-0.mol
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Diethyl 1,1-cyclopropanedicarboxylate Chemical Properties
- Melting point:
- 134-136 °C(lit.)
- Boiling point:
- 94-96 °C/10 mmHg (lit.)
- Density
- 1.055 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.433(lit.)
- Flash point:
- 188 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Acetone (Slightly), Chlorform (Slightly), Methanol (Slightly)
- form
- Liquid
- color
- Clear colorless
- BRN
- 2049509
- CAS DataBase Reference
- 1559-02-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-24/25-23
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- HazardClass
- IRRITANT
- HS Code
- 29172090
MSDS
- Language:English Provider:Diethyl 1,1-cyclopropanedicarboxylate
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Diethyl 1,1-cyclopropanedicarboxylate Usage And Synthesis
Chemical Properties
clear colorless liquid
Uses
Diethyl 1,1-Cyclopropanedicarboxylate (cas# 1559-02-0) is a compound useful in organic synthesis.
Synthesis Reference(s)
Synthesis, p. 690, 1980 DOI: 10.1055/s-1980-29171
General Description
Diethyl cyclopropane-1,1-dicarboxylate participates in ring-opening addition reactions with various nucleophilic reagents.
Purification Methods
If it is free from OH bands in the IR, then fractionally distil the ester and redistil the middle fraction. Otherwise shake it with aqueous NaHCO3, dry it (MgSO4), filter and distil as before or re-esterify it. [As synthon see Danishefsky Acc Chem Res 12 66 1979, Beilstein 9 I 314, 9 II 512, 9 III 3595, 9 IV 2786.]
Diethyl 1,1-cyclopropanedicarboxylate Preparation Products And Raw materials
Preparation Products
Diethyl 1,1-cyclopropanedicarboxylateSupplier
China Langchem Inc. Gold
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- 021-58956006 15800617331
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Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd. Gold
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- 133-96369453 18678026865
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Infinity SCI Gold
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- 400-400-1062016 17800804092
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J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006608290; 18621169109
- market03@meryer.com
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Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)Related Product Information
- Mefenpyr-diethyl
- Diethyl phthalate
- Cyclopropyl methyl ketone
- Diethyl sulfate
- Diethyl phosphite
- Diethyl carbonate
- Diethyl oxalate
- Diethyl 1,3-acetonedicarboxylate
- Diethyl malonate
- 7-Chloro-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxoquinoline-3-carboxylic acid
- Ethylene glycol diethyl ether
- Celiprolol
- n-propyl dioxepene
- Diethyl ether
- 1,1-Cyclopropanedicarboxylic acid
- Cyclopropane
- DIETHYL 2-PHENYL-1,1-CYCLOPROPANEDICARBOXYLATE
- 2-VINYLCYCLOPROPANE-1,1-DICARBOXYLIC ACID DIETHYL ESTER