[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I),98% Chemical Properties

storage temp. 

Keep in dark place,Inert atmosphere,Room temperature

solubility 

Dichloromethane

form 

Powder

color 

white to off-white

Sensitive 

air sensitive, light sensitive, store cold

Stability:

Hygroscopic, Light-sensitive, Air-sensitive

InChI

InChI=1S/C18H15P.C2F6NO4S2.Au/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h1-15H;;/q;-1;/p+1

InChIKey

ZNCATZOEXBYINU-UHFFFAOYSA-O

SMILES

P(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)[Au+][N-](S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

Safety Information

HS Code 

71159010

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I),98% Usage And Synthesis

Reaction

1. Catalyst promoting the addition of nucleophiles to alleneamides.
2. Gold- and Bronsted acid-catalyzed cycloisomerization of 1,8-diynyl vinyl acetates to bicycle[2.2.1]hept-2-en-7-ones.
3. Catalyst used for the synthesis of spiro[piperidine-3,3’-oxindoles].
4. Catalyst used in the gold(I)-catalyzed Rautenstrauch rearrangement.
5. Gold-catalyzed π-directed regioselective cyclization of bis(o-alkynyl benzyl alcohols): rapid excess to dihydroisobenzofuran derivatives.
6. Gold compound used in acid-catalyzed cycloisomerization – synthesis of diverse nitrogen-containing spiro heterocycles.
7. Gold catalyst used in the domino synthesis of functionalized benzofurans and tetracyclic isochromans via formal carboalkoxylation.

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I),98%(866395-16-6)Related Product Information

• GRUBBS CATALYST 2ND GENERATION
• Benzeneruthenium(II) chloride dimer
• [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
• Tris(triphenylphosphine)ruthenium(II) chloride
• [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
• Dichloro(p-cymene)ruthenium(II) dimer
• Rhodium(II) acetate dimer
• Ruthenium(II) chloride mesitylene dimer
• Rhodium(III) 2,4-pentanedionate
• Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
• PROPARGYLTRIPHENYLPHOSPHONIUM BROMIDE
• N-BOC-IMINO-(TRIPHENYL)PHOSPHORANE
• TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE
• (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
• Dichloro(cycloocta-1,5-diene)ruthenium(II)
• 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
• Ruthenium acetylacetonate
• Tris(triphenylphosphine)chlororhodium