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N-(tert-Butoxycarbonyl)-L-alanine

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N-(tert-Butoxycarbonyl)-L-alanine Basic information

Product Name:
N-(tert-Butoxycarbonyl)-L-alanine
Synonyms:
  • BOC-L-ALANINE
  • BOC-L-ALANINE-OH
  • BOC-L-ALA-OH
  • BOC-L-ALA
  • BOC-ALA
  • BOC-ALANINE
  • BOC-ALA-OH
  • H-ALPHA-T-BOC-L-ALANINE
CAS:
15761-38-3
MF:
C8H15NO4
MW:
189.21
EINECS:
239-847-8
Product Categories:
  • Boc-Amino Acids
  • Amino Acids (N-Protected)
  • Alanine [Ala, A]
  • Boc-Amino Acids and Derivative
  • Biochemistry
  • Boc-Amino acid series
  • Protected Amino Acids
  • straight chain compounds
  • Amino Acids
  • Amino Acid Derivatives
  • PROTECTED AMINO ACID & PEPTIDES
  • Naphthyridines
Mol File:
15761-38-3.mol
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N-(tert-Butoxycarbonyl)-L-alanine Chemical Properties

Melting point:
79-83 °C(lit.)
alpha 
-26 º (c=2, acetic acid)
Boiling point:
324.46°C (rough estimate)
Density 
1.2321 (rough estimate)
refractive index 
-25.5 ° (C=2, AcOH)
storage temp. 
Sealed in dry,2-8°C
solubility 
DMSO, Methanol
pka
4.02±0.10(Predicted)
form 
Granular Powder
color 
White
optical activity
[α]20/D 25±1°, c = 2% in acetic acid
BRN 
1726365
CAS DataBase Reference
15761-38-3(CAS DataBase Reference)
EPA Substance Registry System
L-Alanine, N-[(1,1-dimethylethoxy)carbonyl]- (15761-38-3)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
24/25-36-26
WGK Germany 
3
TSCA 
Yes
HS Code 
2924 19 00
HazardClass 
IRRITANT

MSDS

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N-(tert-Butoxycarbonyl)-L-alanine Usage And Synthesis

Chemical Properties

White to off-white microcrystalline powder

Uses

Boc-Ala-OH can be used:

  • In the preparation of N-propargylalanine, a key precursor to generate N-(3-aryl)propylated alanine residues.
  • In the resolution of racemic mixture of 3,3′-bis(benzyloxy)-1,1′-binaphthalene-2,2′-diol.
  • In the one-pot synthesis of hybrid tripeptidomimetics containing both amide and imide functionalities.

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