ChemicalBook > CAS DataBase List > Palladium (II) Acetate

Palladium (II) Acetate

Product Name
Palladium (II) Acetate
CAS No.
3375-31-3
Chemical Name
Palladium (II) Acetate
Synonyms
pd(oac)2;PALLADIUM DIACETATE;PALLADIUM ACETATE;PALLADIUM(II) ACETATE;diacetoxypalladium;diacetatopalladium;alladium diacetate;Palladium(Ⅱ)Acetate;bis(acetato)palladium;PD(OAC)2 (TRIMER) SALT
CBNumber
CB1187458
Molecular Formula
Pd(OCOCH3)2
Formula Weight
226.52
MOL File
3375-31-3.mol
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Palladium (II) Acetate Property

Melting point:
205 °C
vapor pressure 
0.002Pa at 25℃
storage temp. 
Store below +30°C.
solubility 
Soluble as monomer in glacial acetic acid or as trimer in benzene.
form 
Various Forms In Red-(Powder/Flake/Crystalline/Beads)
color 
Red-brown
PH
2-3 (H2O, 20℃)(aqueous suspension)
PH Range
2.0 - 3.0 at 20 °C
Water Solubility 
insoluble
Sensitive 
Hygroscopic
λmax
400nm(EtOH)(lit.)
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Merck 
14,6991
BRN 
6086766
InChIKey
PCUVQHHZCJMCHO-UHFFFAOYSA-M
LogP
-0.17 at 20℃
CAS DataBase Reference
3375-31-3(CAS DataBase Reference)
EPA Substance Registry System
Acetic acid, palladium(2+) salt (3375-31-3)
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Safety

Hazard Codes 
Xi,Xn,C
Risk Statements 
41-36/37/38-40-35
Safety Statements 
26-39-36/37/39-45-36
RIDADR 
3261
WGK Germany 
2
RTECS 
AJ1900000
F 
10-23
TSCA 
Yes
HS Code 
28439090
Toxicity
LD50 orally in Rabbit: >= 5110 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H318Causes serious eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.18056
Product name
Palladium(II) acetate (47% Pd)
Purity
for synthesis
Packaging
500mg
Price
$206
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18056
Product name
Palladium(II) acetate (47% Pd)
Purity
for synthesis
Packaging
1g
Price
$340
Updated
2024/03/01
Sigma-Aldrich
Product number
8.18056
Product name
Palladium(II) acetate (47% Pd)
Purity
for synthesis
Packaging
5G
Price
$1480
Updated
2024/03/01
Sigma-Aldrich
Product number
205869
Product name
Palladium(II) acetate
Purity
reagent grade, 98%
Packaging
1g
Price
$108
Updated
2024/03/01
Sigma-Aldrich
Product number
205869
Product name
Palladium(II) acetate
Purity
reagent grade, 98%
Packaging
2g
Price
$203
Updated
2024/03/01
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Palladium (II) Acetate Chemical Properties,Usage,Production

Chemical Properties

Brown needles, soluble in benzene and toluene, insoluble in ether and alcohol, keep in dark and refrigerated.

Uses

Palladium (II) Acetate Trimer is used in Suzuki-Miyaura cross-coupling reactions and a catalyst for intramolecular coupling. It also serves to catalyze the chemoselective reduction of nitroarenes.

Definition

Palladium acetate is a chemical compound of palladium. It is used as a catalyst for many organic reactions and as a precursor to other palladium(II) compounds. Palladium is a chemical element with the chemical symbol Pd and an atomic number of 46. It is found as a free metal alloyed with gold and other platinum group metals and in the rare minerals cooperite and polarite. (Toxin and Toxin Target Database (T3DB))

Preparation

The synthesis of palladium acetate was first reported by Wilkinson et al.,where glacial acetic acid containing palladium powder is heated at reflux with a minimal amount of nitric acid until the generation of brown NOx fumes ceases. Although this is a relatively old method, it is still the most commercially employed route for the synthesis of palladium acetate, considering the process economics. Palladium (II) Acetate can be synthesized in two steps from palladium sponge via the intermediate dinitrate by first combining it with hot glacial acetic acid and nitric acid:
Pd + 2 HNO3 → Pd(NO3)2 + H2
Pd(NO3)2 + 2 CH3COOH → Pd(O2CCH3)2 + 2 HNO3

Reactions

  1. Efficient catalyst for the arylation of olefins (Heck reaction).
  2. Catalyst for cross-coupling reactions.
  3. Catalyst for C-H activation.
  4. Precatalyst for enantioselective decarboxylative protonation of allyl β-ketoesters. 

General Description

Palladium(II) acetate is a homogenous oxidation catalyst. It participates in the activation of alkenic and aromatic compounds towards oxidative inter- and intramolecular nucleophilic reactions. Crystals of palladium(II) acetate have a trimeric structure, having symmetry D3h. Each of the palladium atoms in the crystals are joined to the other two by double acetate bridges. Microencapsulation of palladium(II) acetate in polyurea affords polyurea-encapsulated palladium(II) acetate. It is a versatile heterogeneous catalyst for various phosphine-free cross-coupling reactions. It participates as catalyst in the Heck coupling reaction of pthalides with different alkenes.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of palladium.

Purification Methods

It recrystallises from CHCl3 as purple crystals. It can be washed with AcOH and H2O and dried in air. Large crystals are obtained by dissolving it in *C6H6, adding half its volume of AcOH and allowing it to evaporate slowly at room temperature. It forms green adducts with nitrogen donors, it dissolves in KI solution to form solid PdI2 and a red solution of PdI42-, but is insoluble in aqueous saturated NaCl, and NaOAc. It dissolves in HCl to form PdCl42-. It is soluble in CHCl3, CH2Cl2, Me2CO, MeCN, Et2O, but it is insoluble in H2O, and decomposes when warmed in alcohols in which it is also insoluble. [Morehouse et al. Chem Ind (London) 544 1964, Stephenson et al. J Chem Soc 3632 1965, Skapski & Smart J Chem Soc (D) 658 1970, Heck Acc Chem Res 12 146 1979.]

Palladium (II) Acetate Preparation Products And Raw materials

Raw materials

Hydrazine hydrate Palladium chloride Sodium formate Acetic acid

Preparation Products

3-AMINOBIPHENYL 2,3-DIHYDRO-1H-INDOLE-5-CARBOXYLIC ACID 3-PHENYLBENZYLAMINE N,N'-Bis- (1-naphthalenyl)-N,N'-bis-phenyl-(1,1'-biphenyl)-4,4'-diamine 5-CYANO-2,3-DIHYDRO-1H-INDOLE Ethyl (R)-2-hydroxy-4-phenylbutyrate (E)-METHYL 3-(4-BROMOPHENYL)ACRYLATE (S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE 5-PHENYL-2-THIOPHENECARBALDEHYDE C-(3,4-DIHYDRO-2H-BENZO[1,4]OXAZIN-3-YL)-METHYLAMINE (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% 4-(2-KETO-1-BENZIMIDAZOLINYL)PIPERIDINE 1-ACETYL-5-AMINO-2,3-DIHYDRO-(1H)-INDOLE ethyl 1H-indole-6-carboxylate (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE 2-MORPHOLINO-5-(TRIFLUOROMETHYL)BENZALDEHYDE 4-Aminophenylboronic acid pinacol ester (R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Diphenylacetylene ethyl indoline-6-carboxylate 5-Phenylthiophene-2-carboxylic acid Bergapten 4-Aminobiphenyl INDOLINE-6-CARBOXYLIC ACID 3-Phenyl-1H-pyrazole 1-(4-Pyridyl)piperazine Allyl acetate 5-Methylindole 4,6-Diamino-2-pyrimidinol (R)-7,7'-BIS(DIPHENYLPHOSPHINO)-1,1'-SPIROBIINDANE
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View Lastest Price from Palladium (II) Acetate manufacturers

Hebei Kangcang new material Technology Co., LTD
Product
Palladium diacetate 3375-31-3
Price
US $9.00-70.00/g
Min. Order
10g
Purity
99%
Supply Ability
10 tons
Release date
2024-03-27
R&D Scientific Inc.
Product
Palladium (II) acetate 3375-31-3
Price
US $1390.00/g
Min. Order
1g
Purity
98
Supply Ability
500 Kg
Release date
2024-04-22
Hebei Saisier Technology Co., LTD
Product
Palladium (II) Acetate 3375-31-3
Price
US $6.00/KG
Min. Order
1KG
Purity
More than 99%
Supply Ability
2000KG/MONTH
Release date
2024-04-18

3375-31-3, Palladium (II) AcetateRelated Search:

Ethyl acetate Tocopheryl acetate Glatiramer acetate Vinyl acetate Palladium Calcium acetate Butyl acetate POLY(VINYL ACETATE) Pancuronium bromide Sodium acetate trihydrate Sodium acetate Acetic acid Palladium chloride Palladium hydroxide Bis(2,4-pentanedionato-O,O')palladium(II) Bis(tricyclohexylphosphine)palladium(II) Dichloride Bis(benzonitrile)palladium chloride hexakis[mu-(acetato-O:O')]-mu3-oxo-triangulo-triruthenium acetate

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