4-Chloroanisole

Product Name: 4-Chloroanisole
CAS No.: 623-12-1
Chemical Name: 4-Chloroanisole
Synonyms: 1-CHLORO-4-METHOXYBENZENE;P-CHLOROANISOLE;para-Chloroanisole;4-Methoxyphenyl chloride;p-chloroanisol;4-Chloroanisol;Chloro anisole;4-CHLOROANISOLE;3 4-Chloroanisole;Anisole, p-chloro-
CBNumber: CB1312283
Molecular Formula: C7H7ClO
Formula Weight: 142.58
MOL File: 623-12-1.mol

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4-Chloroanisole Property

Melting point:: -18 °C (lit.)
Boiling point:: 198-202 °C (lit.)
Density: 1.164 g/mL at 25 °C (lit.)
vapor pressure: 1.08hPa at 25℃
refractive index: n20/D 1.535(lit.)
Flash point:: 173 °F
storage temp.: Sealed in dry,Room Temperature
form: Liquid
color: Clear colorless to yellow
Water Solubility: immiscible
BRN: 1858901
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
LogP: 2.78 at 25℃
CAS DataBase Reference: 623-12-1(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-chloro-4-methoxy-(623-12-1)
EPA Substance Registry System: Benzene, 1-chloro-4-methoxy- (623-12-1)

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Safety

Hazard Codes: Xn
Safety Statements: 23-24/25
RIDADR: UN 2810
WGK Germany: 3
TSCA: Yes
HS Code: 29093090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 159069
Product name: 4-Chloroanisole
Purity: 99%
Packaging: 25g
Price: $102
Updated: 2024/03/01

Sigma-Aldrich

Product number: 159069
Product name: 4-Chloroanisole
Purity: 99%
Packaging: 100g
Price: $286
Updated: 2023/06/20

TCI Chemical

Product number: C0122
Product name: 4-Chloroanisole
Purity: >98.0%(GC)
Packaging: 25g
Price: $44
Updated: 2024/03/01

TCI Chemical

Product number: C0122
Product name: 4-Chloroanisole
Purity: >98.0%(GC)
Packaging: 500g
Price: $252
Updated: 2024/03/01

Alfa Aesar

Product number: A11377
Product name: 4-Chloroanisole, 99%
Packaging: 50g
Price: $57.65
Updated: 2024/03/01

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4-Chloroanisole Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

4-Chloroanisole was found to react with Cu (II)-smectite forming a blue clay-organic complex. 4-Chloroanisole was chosen as the main test substrate for the optimisation studies as it is electronically deactivated and thus resistant to oxidative addition and consequently very reluctant to enter a catalytic manifold.

Synthesis Reference(s)

Chemistry Letters, 16, p. 1901, 1987
The Journal of Organic Chemistry, 35, p. 528, 1970 DOI: 10.1021/jo00827a060

General Description

4-Chloroanisole is an electron-rich chloroarene. It undergoes Ullmann-type homocoupling catalyzed by in situ generated Pd colloids. Reaction of 4-chloroanisole with Cu(II)-smectite in n-hexane, carbon tetrachloride or dichloromethane has been studied. The nucleophilic photosubstitution reactions, photocyanation and photohydrolysis of 4-chloroanisole has been studied by time resolved spectroscopy.

Purification Methods

Wash the anisole with 10% (by volume) aqueous H2SO4 (three times), 10% aqueous KOH (three times), and then with water until neutral. Dry it (MgSO4), and fractionally distil it from CaH2 through a glass helices-packed column under reduced pressure. [Beilstein 16 IV 822.]

4-Chloroanisole Preparation Products And Raw materials

Raw materials

Disulfur dichloride o-Cresol

Preparation Products

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4-Chloroanisole Suppliers

Americas 1 Belgium 2 Canada 1 China 243 Europe 3 Germany 8 India 24 Japan 4 Slovakia 1 South Korea 1 Switzerland 3 United Kingdom 16 United States 31 Global 338

Matrix Fine Chemicals GmbH

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Email: nfo@matrix-fine-chemicals.com
Country: Switzerland
ProdList: 6968
Advantage: 58

Le Chem Organics SA

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Email: info@lechem.com
Country: Switzerland
ProdList: 196
Advantage: 43

SIGMA-RBI

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Country: Switzerland
ProdList: 6896
Advantage: 91

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View Lastest Price from 4-Chloroanisole manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: 4-Chloroanisole 623-12-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 ton
Release date: 2024-08-21

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Chloroanisole 623-12-1
Price: US $1.00/PCS
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-02-04

Hebei Mojin Biotechnology Co., Ltd

Product: 4-Chloroanisole 623-12-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-09-07

623-12-1, 4-ChloroanisoleRelated Search:

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Ethers

Building Blocks

Oxygen Compounds

Organic Building Blocks

Aromatic Ethers

Anisoles, Alkyloxy Compounds & Phenylacetates

Chlorine Compounds

Ethers

Organic Building Blocks

Oxygen Compounds

623-12-1