4-Iodo-2-nitroanisole
- Product Name
- 4-Iodo-2-nitroanisole
- CAS No.
- 52692-09-8
- Chemical Name
- 4-Iodo-2-nitroanisole
- Synonyms
- 4-IODO-2-NITROANISOLE;4-iodo-1-methoxy-2-nitrobenzene;Benzene, 4-iodo-1-methoxy-2-nitro-
- CBNumber
- CB3213674
- Molecular Formula
- C7H6INO3
- Formula Weight
- 279.03
- MOL File
- 52692-09-8.mol
4-Iodo-2-nitroanisole Property
- Melting point:
- 96-98°C
- Boiling point:
- 330.8±27.0 °C(Predicted)
- Density
- 1.893±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C, protect from light
- Appearance
- Light yellow to yellow Solid
- Sensitive
- Light Sensitive
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H301Toxic if swalloed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- I715735
- Product name
- 4-Iodo-2-nitroanisole
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- I715735
- Product name
- 4-Iodo-2-nitroanisole
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 119934
- Product name
- 4-Iodo-1-methoxy-2-nitrobenzene
- Purity
- 95+%
- Packaging
- 1g
- Price
- $72
- Updated
- 2021/12/16
- Product number
- 4654-H-15
- Product name
- 4-Iodo-2-nitroanisole
- Packaging
- 1g
- Price
- $116
- Updated
- 2021/12/16
- Product number
- X5312
- Product name
- 4-Iodo-2-nitroanisole
- Packaging
- 5g
- Price
- $188
- Updated
- 2021/12/16
4-Iodo-2-nitroanisole Chemical Properties,Usage,Production
Synthesis Reference(s)
Tetrahedron Letters, 10, p. 2427, 1969 DOI: 10.1017/S0009838800024678
Synthesis
91-23-6
52692-09-8
General procedure for the synthesis of 4-iodo-2-nitroanisole from 2-nitroanisole: To a stirred solution of 2-nitroanisole (1 mmol) in dichloromethane (CH2Cl2) or 1,2-dichloroethane ((CH2Cl)2) (0.1 M) was added sequentially Ph3PAuNTf2 (0.025 mmol, 19 mg; if using the 2:1 complex of Ph3PAuNTf2 with toluene) and N-iodosuccinimide (NIS, 1.1 mmol, 248 mg). The reaction mixture was stirred at room temperature or reacted under reflux conditions until complete conversion of the feedstock was confirmed by thin layer chromatography (TLC) monitoring. Upon completion of the reaction, the solvent was evaporated under reduced pressure and the resulting crude product was purified by fast column chromatography using different ratios of hexane and ethyl acetate (EtOAc) as eluents, resulting in pure 4-iodo-2-nitroanisole.
References
[1] Synlett, 2014, vol. 25, # 3, p. 399 - 402
[2] Journal of Organic Chemistry, 1990, vol. 55, # 11, p. 3552 - 3555
[3] Tetrahedron, 2004, vol. 60, # 41, p. 9113 - 9119
[4] Synthetic Communications, 2007, vol. 37, # 8, p. 1259 - 1265
[5] Synthesis, 2006, # 7, p. 1195 - 1199
4-Iodo-2-nitroanisole Preparation Products And Raw materials
Raw materials
Preparation Products
4-Iodo-2-nitroanisole Suppliers
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View Lastest Price from 4-Iodo-2-nitroanisole manufacturers
- Product
- 4-Iodo-2-nitroanisole 52692-09-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- G/KG/T
- Release date
- 2019-12-24