ChemicalBook > CAS DataBase List > 4-Methoxybenzylchloride

4-Methoxybenzylchloride

Product Name
4-Methoxybenzylchloride
CAS No.
824-94-2
Chemical Name
4-Methoxybenzylchloride
Synonyms
PMBCl;4-METHOXYBENZYL CHLORIDE;P-METHOXYBENZYL CHLORIDE;PBMCl;4-(Chloromethyl)-1-methoxybenzene;4-Methoxybenzylchloride, stabilized, 98% 5GR;p-Anisyl chloride;NSC 172955;ANISYL CHLORIDE;AKOS BBS-00003861
CBNumber
CB3330683
Molecular Formula
C8H9ClO
Formula Weight
156.61
MOL File
824-94-2.mol
More
Less

4-Methoxybenzylchloride Property

Melting point:
−1 °C(lit.)
Boiling point:
117-118 °C14 mm Hg(lit.)
Density 
1.155 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.548(lit.)
Flash point:
229 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Liquid
color 
Clear colorless to pale yellow
Water Solubility 
slowly decomposes
Stability:
Moisture Sensitive
InChIKey
MOHYOXXOKFQHDC-UHFFFAOYSA-N
CAS DataBase Reference
824-94-2(CAS DataBase Reference)
NIST Chemistry Reference
«alpha»-Chloro-4-methoxytoluene(824-94-2)
More
Less

Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-27-36/37/39-45
RIDADR 
UN 3265 8/PG 3
WGK Germany 
3
F 
10-19-21
Autoignition Temperature
109℃
Hazard Note 
Corrosive
TSCA 
No
HazardClass 
8
PackingGroup 
III
HS Code 
29093090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P390Absorb spillage to prevent material damage.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
M0676
Product name
4-Methoxybenzyl Chloride (stabilized with Amylene)
Purity
>98.0%(GC)(T)
Packaging
25mL
Price
$93
Updated
2024/03/01
TCI Chemical
Product number
M0676
Product name
4-Methoxybenzyl Chloride (stabilized with Amylene)
Purity
min. 98.0 %
Packaging
100ML
Price
$267
Updated
2024/03/01
TRC
Product number
M261105
Product name
4-MethoxybenzylChloride(Stabilized)
Packaging
5g
Price
$95
Updated
2021/12/16
ChemSupplyAustralia
Product number
300440
Product name
4-Methoxybenzyl chloride, 98% (contains 0.5 wt% of potassium carbonate as stabilizer)
Packaging
5G
Price
$24.2
Updated
2021/12/16
Chem-Impex
Product number
00213
Product name
4-Methoxybenzylchloride,ContainsPotassiumcarbonateasstabilizer.,99%(GC)
Purity
99%(GC)
Packaging
5G
Price
$28
Updated
2021/12/16
More
Less

4-Methoxybenzylchloride Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.

Synthesis Reference(s)

Journal of Medicinal Chemistry, 20, p. 190, 1977 DOI: 10.1021/jm00212a002
The Journal of Organic Chemistry, 53, p. 3634, 1988 DOI: 10.1021/jo00250a048

General Description

4-Methoxybenzyl chloride undergoes mild oxidative claevage with ceric ammonium nitrate.

Purification Methods

Purify 4-anisyl chloride by fractional distillation under vacuum, and the middle fraction is redistilled at 10-6 mm at room temperature by intermittent cooling of the receiver in liquid N2, and the middle fraction is collected. [Mohammed & Kosower J Am Chem Soc 93 2709 1971, Beilstein 6 IV 2137.]

4-Methoxybenzylchloride Preparation Products And Raw materials

Raw materials

Preparation Products

4-Methoxybenzyl cyanide
More
Less

4-Methoxybenzylchloride Suppliers

Americas 1 Belgium 3 Canada 2 China 327 Europe 4 France 2 Germany 8 India 73 Japan 6 Slovakia 1 South Korea 1 Switzerland 4 The Netherlands 1 Ukraine 2 United Kingdom 18 United States 54 Global 507
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10648
Advantage
60
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
AbaChemScene
Tel
732-484-9848
Fax
888-484-5008
Email
sales@chemscene.com
Country
United States
ProdList
3982
Advantage
60
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Alfa Chemistry
Tel
Email
info@alfa-chemistry.com
Country
United States
ProdList
2344
Advantage
58
Aston Chemical
Tel
13000000000
Email
sales@astonchem.com
Country
United States
ProdList
1634
Advantage
58
Alfa Chemistry
Tel
--
Fax
--
Email
info@Alfa-Chemistry.com
Country
United States
ProdList
6814
Advantage
0
Frontier Scientific Services, Inc.
Tel
--
Fax
--
Email
customerservice@frontierssi.com
Country
United States
ProdList
1575
Advantage
0
Fluorochem Ltd.
Tel
--
Fax
--
Email
enquiries@fluorochem.co.uk
Country
United States
ProdList
4583
Advantage
58
eNovation Chemicals LLC
Tel
--
Fax
--
Email
ales@eNovationChem.com
Country
United States
ProdList
1673
Advantage
58
SynQuest Laboratories, Inc.,
Tel
--
Fax
--
Country
United States
ProdList
2301
Advantage
58
VWR International, LLC.
Tel
--
Fax
--
Email
@sargentwelch.com
Country
United States
ProdList
6262
Advantage
58
MilliporeSigma (Sigma-Aldrich Corp.)
Tel
--
Fax
--
Email
@sial.com
Country
United States
ProdList
5414
Advantage
58
Chem-Impex International, Inc. (CII)
Tel
--
Fax
--
Email
Customer@chemimpex.com
Country
United States
ProdList
893
Advantage
58
2A Biotech USA
Tel
--
Fax
--
Email
info@2abiotech.com
Country
United States
ProdList
1785
Advantage
58
Combi-Blocks, Inc.
Tel
--
Fax
--
Email
les@combi-blocks.com
Country
United States
ProdList
2555
Advantage
58
Crescent Chemical Company
Tel
--
Fax
--
Email
fran@creschem.com
Country
United States
ProdList
1441
Advantage
58
Alichem Inc.
Tel
--
Fax
--
Email
sales@alichem.com
Country
United States
ProdList
6167
Advantage
58
Admiral Chemicals LLC
Tel
--
Fax
--
Email
office@admiralchemicals.com
Country
United States
ProdList
49
Advantage
58
SynQuest Laboratories, Inc. (Part of Central Glass Co., Ltd.)
Tel
--
Fax
--
Email
nfo@synquestlabs.com
Country
United States
ProdList
1897
Advantage
58
Leonid Chemicals Private Limited
Tel
--
Fax
--
Email
careers@leonidchemicals.com
Country
United States
ProdList
1700
Advantage
43
OChem Incorporation
Tel
--
Fax
--
Email
sales@ocheminc.com
Country
United States
ProdList
6501
Advantage
60
Spectrum Chemicals & Laboratory Products
Tel
--
Fax
--
Email
sales@spectrumchemical.com
Country
United States
ProdList
6699
Advantage
77
RIA International LLC
Tel
--
Fax
--
Email
marketing@riausa.net
Country
United States
ProdList
1324
Advantage
50
TCI America, Inc. (part of Tokyo Chemical Industry)
Tel
--
Fax
--
Email
Angelina.Crew@tcichemicals.com
Country
United States
ProdList
2053
Advantage
58
Sinova Inc.
Tel
--
Fax
--
Email
sales@sinovainc.com
Country
United States
ProdList
4009
Advantage
58
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
Anvia Chemicals, LLC
Tel
--
Fax
--
Email
sales@anviachem.com
Country
United States
ProdList
3933
Advantage
0
Ivy Fine Chemicals
Tel
--
Fax
--
Email
sales@ivychem.com
Country
United States
ProdList
6493
Advantage
58
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6962
Advantage
56
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
ChemContract Research Inc.
Tel
--
Fax
--
Country
United States
ProdList
1526
Advantage
38
Trans World Chemicals, Inc.
Tel
--
Fax
--
Email
transworldchems@aol.com
Country
United States
ProdList
1591
Advantage
59
Narchem Corporation
Tel
--
Fax
--
Email
sales@narchem.com
Country
United States
ProdList
2813
Advantage
60
Advanced Synthesis Technologies
Tel
--
Fax
--
Email
sales@advancedsynthesis.com
Country
United States
ProdList
4775
Advantage
61
Chem-Impex International, Inc.
Tel
--
Fax
--
Country
United States
ProdList
6730
Advantage
64
2A PharmaChem USA
Tel
--
Fax
--
Email
sales@2apharmachem.com
Country
United States
ProdList
6137
Advantage
39
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
ASDI Incorporated
Tel
--
Fax
--
Email
customerservice@asdi.net
Country
United States
ProdList
6922
Advantage
67
M/S PANAMIT INTERNATIONAL
Tel
--
Fax
--
Email
sales@jyotichem.com
Country
United States
ProdList
312
Advantage
46
Wintersun Chemical
Tel
--
Fax
--
Email
purchasing@wintersunchem.com
Country
United States
ProdList
776
Advantage
68
Benzo Chem Industries/Gitanjali Chemicals
Tel
--
Fax
--
Email
gcpl@bom3.vsnl.net.in
Country
United States
ProdList
108
Advantage
38
Richman Chemical Inc.
Tel
--
Fax
--
Email
kac@richmanchemical.com
Country
United States
ProdList
692
Advantage
67
More
Less

View Lastest Price from 4-Methoxybenzylchloride manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
4-Methoxybenzylchloride 824-94-2
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23
Henan Fengda Chemical Co., Ltd
Product
4-Methoxybenzylchloride 824-94-2
Price
US $10.00-1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08
Henan Bao Enluo International TradeCo.，LTD
Product
4-Methoxybenzylchloride 824-94-2
Price
US $100.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500t/month
Release date
2023-07-25

824-94-2, 4-MethoxybenzylchlorideRelated Search:

4-Methoxybenzoyl chloride 4-Fluorobenzyl chloride Anisole 2-Chlorobenzyl chloride 1,2-Dichloro-4-(chloromethyl)benzene 4-Methoxybenzyl alcohol 4-Methoxybenzylamine 4-Chlorobenzyl cyanide 4-Nitrobenzyl chloroformate 4-Chlorobenzyl chloride Benzyl chloroformate 3-Bromoanisole 4-Methylbenzyl chloride 4'-Methoxyacetophenone 4-Methoxybenzyl cyanide Methoxypropiophenone 4-Formylbenzoic acid 4-Methoxyphenethylamine

  • P-METHOXYBENZYL CHLORIDE
  • alpha-Chloro-4-methoxytoluene
  • Anisole, p-(chloromethyl)-
  • Benzene, 1-(chloromethyl)-4-methoxy-
  • p-(Chloromethyl)anisole
  • p-Anisyl chloride
  • 4-Methoxybenzylchloride, stabilized, 98% 5GR
  • Anisyl Chloride 4-(Chloromethyl)anisole
  • 4-Methoxybenzyl chloride contains potassiuM carbonate as stabilizer, 98%
  • The Methoxy benzyl chloride
  • para-chloromethylanisole
  • 4-Methoxybenzyl chloride, 98%, stabilized with potassium carbonate
  • PMBCl
  • 4-Methoxybenzyl chloride, 98% (Stabilized with Calcium carbote)
  • METHOXYBENZYLCHLORIDE(P-)
  • 1-CHLOROMETHYL-4-METHOXYBENZENE
  • AKOS BBS-00003861
  • ANISYL CHLORIDE
  • 4-METHOXYBENZYL CHLORIDE
  • 4-(CHLOROMETHYL)ANISOL
  • 4-(CHLOROMETHYL)ANISOLE
  • P-methoxyl benzylchloride
  • 4-Methoxybenzylchloride99%
  • 4-Methoxybenzylchloride 99%
  • 4-Methoxybenzene methyl chloride
  • α-Chloro-4-methoxytoluene
  • 4-Methoxybenzylchloride, stabilized, 98%
  • 4-METHOXYBENZYL CHLORIDE (STABILIZED WITH CALCIUM CARBONATE)
  • 4-METHYOXYBENZYL CHLORIDE
  • 4-METHOXYBENZYLCHLORIDE / 4-(CHLOROMETHYL)ANISOLE
  • 4) PARA METHOXY BENZYL CHLORIDE
  • 1-(Chloromethyl)-4-methoxybenzene, 4-(Chloromethyl)anisole
  • 4-Methoxybenzyl Chloride (stabilized with Amylene)
  • 4-Methoxybenzylchloride, 98%, stabilized
  • 4-Chloromethylphenyl methyl ether
  • 4-Methoxy-1-(chloromethyl)benzene
  • 4-Methoxybenzylchloride ,98%
  • 4-Methoxybenzylchlor
  • 4-Methoxybenzylchloride, stabilized, 98% 25GR
  • 4-Methoxybenzyl chloride, 98%, for synthesis
  • 4-MethoxybenzylChloride(stabilizedwithAmylene)&gt
  • 4-methoxychlorobenzyl
  • 1-(Chloromethyl)-4-(methyloxy)benzene
  • 4-(Chloromethyl)-1-methoxybenzene
  • 4-(Chloromethyl)anisole (stabilized with Amylene)
  • 4-Methyloxybenzyl chloride
  • Anisyl Chloride (stabilized with Amylene)
  • NSC 172955
  • p-(Chloromethyl)(methoxy)benzene
  • PBMCl
  • α-Chloro-4-methoxytoluene
  • α-Chloro-p-methoxytoluene
  • p-methoxychlorbenzyl
  • 4-Methoxy Benzyl chloride, contains 1% potassium carbonate as stabilizer, 95%
  • 4-Methoxybenzyl Chloride (stabilized with Potassium carbonate)
  • Monensin Impurity 4
  • 824-94-2
  • C8H9ClO