ChemicalBook > CAS DataBase List > methyl 6-methylpyridine-2-carboxylate

methyl 6-methylpyridine-2-carboxylate

Product Name
methyl 6-methylpyridine-2-carboxylate
CAS No.
13602-11-4
Chemical Name
methyl 6-methylpyridine-2-carboxylate
Synonyms
NSC 109151;Methyl 6-methylpicolinate;6-Methylpicolinic Acid Methyl Ester;Methyl-6-methylpyridin-2-carboxylat;methyl 6-methylpyridine-2-carboxylate;Methyl 6-methyl-2-pyridinecarboxylate;METHYL-6-MENTHYPYRIDINE-2-CARBOXYLATE;Methyl6-Methylpyridine-2-carboxylate>Methyl6-methylpyridine-2-carboxylate,96%;6-methyl-2-pyridinecarboxylic acid ester
CBNumber
CB3908806
Molecular Formula
C8H9NO2
Formula Weight
151.16
MOL File
13602-11-4.mol
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methyl 6-methylpyridine-2-carboxylate Property

Melting point:
18 °C
Boiling point:
242℃
Density 
1.104
refractive index 
1.5160-1.5200
Flash point:
100℃
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to lump to clear liquid
pka
1.93±0.10(Predicted)
color 
White or Colorless to Light yellow
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M2503
Product name
Methyl 6-Methylpyridine-2-carboxylate
Purity
>98.0%(GC)
Packaging
5g
Price
$84
Updated
2025/07/31
TRC
Product number
M264555
Product name
Methyl 6-Methylpyridine-2-carboxylate
Packaging
1g
Price
$50
Updated
2021/12/16
Oakwood
Product number
032619
Product name
6-Methyl-pyridine-2-carboxylicacidmethylester
Purity
98%
Packaging
25g
Price
$60
Updated
2021/12/16
AK Scientific
Product number
J97522
Product name
Methyl6-methylpicolinate
Packaging
25g
Price
$65
Updated
2021/12/16
AK Scientific
Product number
X9935
Product name
Methyl6-methylpicolinate
Packaging
5g
Price
$20
Updated
2021/12/16
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methyl 6-methylpyridine-2-carboxylate Chemical Properties,Usage,Production

Uses

Methyl 6-Methylpyridine-2-carboxylate is a reagent used in the sunthesis of antitumor agents based upon the dihydropyrrolopyrazole compounds. Also used in the synthesis of quinazolinone TGF-β inhibitors.

Synthesis

67-56-1

934-60-1

13602-11-4

Step 2: 26.8 g (0.195 mol) of SOCl2 was slowly added dropwise to 100 mL of methanol at a low temperature of -10 °C while stirring was continued. After the dropwise addition, the reaction mixture was gradually warmed up to room temperature and stirring was continued for 1 hour. Subsequently, 10 g of 6-methyl-2-pyridinecarboxylic acid (Compound 2) was added to the reaction system and the reaction was refluxed at 80 °C for 5 hours. Upon completion of the reaction, 10.2 g of methyl 6-methyl-2-pyridinecarboxylate (Compound 3) was obtained in 93% yield.

References

[1] Patent: CN105294552, 2016, A. Location in patent: Paragraph 0047; 0051
[2] Patent: WO2004/48383, 2004, A1. Location in patent: Page 40
[3] Patent: WO2004/48382, 2004, A1. Location in patent: Page 8
[4] Patent: WO2016/187308, 2016, A1. Location in patent: Paragraph 0349
[5] Patent: WO2012/80221, 2012, A1. Location in patent: Page/Page column 98

methyl 6-methylpyridine-2-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from methyl 6-methylpyridine-2-carboxylate manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
methyl 6-methylpyridine-2-carboxylate 13602-11-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2025-06-04
Dideu Industries Group Limited
Product
methyl 6-methylpyridine-2-carboxylate 13602-11-4
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-10-27
Zhuozhou Wenxi import and Export Co., Ltd
Product
methyl 6-methylpyridine-2-carboxylate 13602-11-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

13602-11-4, methyl 6-methylpyridine-2-carboxylateRelated Search:

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  • 6-Methyl-2-pyridinecarboxylic acid methyl ester
  • Methyl 6-methyl-2-pyridinecarboxylate
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  • Methyl6-methylpyridine-2-carboxylate,96%
  • 6-Methylpicolinic Acid Methyl Ester
  • methyl 6-methylpyridine-2-carboxylate ISO 9001：2015 REACH
  • Methyl 6-methylpyridine-2-carboxylate(13602-11-4)
  • 2-Pyridinecarboxylic acid, 6-methyl-, methyl ester (9CI, ACI)
  • 6-methyl-2-Pyridinecarboxylic acid methyl ester (9CI ACI)
  • 6-methyl-2-pyridinecarboxylic acid ester
  • Methyl-6-methylpyridin-2-carboxylat
  • 13602-11-4
  • Heterocycle-Pyridine series
  • CARBOXYLICESTER
  • GLYCINESCAFFOLD