Reaction
ChemicalBook > CAS DataBase List > Bis(benzonitrile)palladium chloride

Bis(benzonitrile)palladium chloride

Reaction
Product Name
Bis(benzonitrile)palladium chloride
CAS No.
14220-64-5
Chemical Name
Bis(benzonitrile)palladium chloride
Synonyms
Pd(PhCN)2Cl2;BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE;Dichlorobis(benzonitrile)palladium;Bis(benzonitrile)palladium dichloride;BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE;Bis(benzonitrile)palladiuM(II);DICHLOROBIS(BENZONITRILE)PALLADIUM(II);Bis(benzonitriL;Bis(benzonitrile;Bis (benzonitrile) palladiuM
CBNumber
CB4339461
Molecular Formula
C14H10Cl2N2Pd
Formula Weight
383.57
MOL File
14220-64-5.mol
More
Less

Bis(benzonitrile)palladium chloride Property

Melting point:
131 °C(lit.)
storage temp. 
Inert atmosphere,2-8°C
solubility 
Soluble in acetone, chloroform
form 
Crystalline Powder
color 
Orange to brown
Water Solubility 
insoluble
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
3981730
Exposure limits
NIOSH: IDLH 25 mg/m3
InChI
InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChIKey
WXNOJTUTEXAZLD-UHFFFAOYSA-L
SMILES
C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference
14220-64-5(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
20/21-23/24/25
Safety Statements 
22-24/25-23-45-36/37-27-20-9-4
RIDADR 
UN3439
WGK Germany 
3
9
TSCA 
No
HazardClass 
6.1
PackingGroup 
III
HS Code 
28439090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P321Specific treatment (see … on this label).

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
223689
Product name
Bis(benzonitrile)palladium(II) chloride
Purity
95%
Packaging
1g
Price
$87.6
Updated
2024/03/01
Sigma-Aldrich
Product number
223689
Product name
Bis(benzonitrile)palladium(II) chloride
Purity
95%
Packaging
10g
Price
$806
Updated
2024/03/01
TCI Chemical
Product number
B1668
Product name
Bis(benzonitrile)palladium(II) Dichloride
Purity
>98.0%(T)
Packaging
1g
Price
$199
Updated
2024/03/01
TCI Chemical
Product number
B1668
Product name
Bis(benzonitrile)palladium(II) Dichloride
Purity
>98.0%(T)
Packaging
5g
Price
$747
Updated
2024/03/01
Alfa Aesar
Product number
010006
Product name
trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.1%
Packaging
1g
Price
$128.65
Updated
2024/03/01
More
Less

Bis(benzonitrile)palladium chloride Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.

Chemical Properties

yellow powder

Uses

suzuki reaction

Uses

Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.

Uses

Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:

  • For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
  • In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins

General Description

This product has been enhanced for catalytic efficiency.

Reactions of 14220-64-5_2
Reactions of 14220-64-5_1

Bis(benzonitrile)palladium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Bis(benzonitrile)palladium chloride Suppliers

Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
NiCHe Materials Ltd.
Tel
--
Fax
--
Email
Mike.Norman@NiCHeMaterials.com
Country
United Kingdom
ProdList
891
Advantage
58
JOHNSON MATTHEY PHARMA SERVICES
Tel
--
Fax
--
Email
group.info@matthey.com
Country
United Kingdom
ProdList
108
Advantage
58
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
MOLEKULA Ltd.
Tel
--
Fax
--
Email
kevinbanks@molekula.com
Country
United Kingdom
ProdList
6140
Advantage
66
CARBONE SCIENTIFIC CO.,LTD
Tel
--
Fax
--
Email
sales@carbonesci.com
Country
United Kingdom
ProdList
6666
Advantage
30
Eurolabs Limited
Tel
--
Fax
--
Country
United Kingdom
ProdList
6309
Advantage
46
Fluorochem Ltd
Tel
--
Fax
--
Email
vernam@fluorochem.co.uk
Country
United Kingdom
ProdList
6375
Advantage
65
VWR International
Tel
--
Fax
--
Email
solutions@vwr.com
Country
United Kingdom
ProdList
6548
Advantage
82
More
Less

View Lastest Price from Bis(benzonitrile)palladium chloride manufacturers

Shanghai Daken Advanced Materials Co.,Ltd
Product
Bis(benzonitrile)palladium(II)chloride 14220-64-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98.00%
Supply Ability
100KG /month
Release date
2021-11-05
henan kanbei chemical co.,ltd
Product
Bis(benzonitrile)palladium chloride 14220-64-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
Bis(benzonitrile)palladium chloride 14220-64-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

14220-64-5, Bis(benzonitrile)palladium chlorideRelated Search:


  • TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE
  • Dichlorobis(benzonitrile)palladiuM(II),98% (C6H5CN)2PdCl2
  • Pd(PhCN)2Cl2
  • trans-Bis(benzonitrile)palladiuM chloride
  • Dichlorobis(benzonitrile)palladium(Ⅱ)
  • Benzonitrile, palladium complex
  • Bis(phenylnitrile)dichloropalladium
  • Dibenzonitrilepalladium dichloride
  • Dichlorobis(benzonitrile)palladium
  • Dichlorobis(phenyl cyanide)palladium
  • Palladium dichloride bis(benzonitrile)
  • Bis(benzonitrile)palladiuM(II)chloridel
  • Bis(benzonitrile)palladiuM(II) chloride 95%
  • Bis (benzonitrile) palladiuM
  • bis(benzonitrile)dichloro-Palladium
  • Bis(benzonitrile)-palladium(II) chloride (27.7% Pd) for synthesis
  • PALLADIUM(II) CHLORIDE BIS(BENZONITRILE) COMPLEX
  • Dichlorodiamminepalladium(II) PdCl2(C6H5CN)2
  • is(benzonitrile)palladium chloride
  • Bis(benzonitrile)palladium(II) chloride 95+%
  • TRANS-DICHLOROBIS-(BENZONITRILO)-PALLADIUM
  • TRANS-BIS(BENZONITRILE)DICHLOROPALLADATE (II)
  • TRANS-BIS(BENZONITRILE)DICHLOROPALLADIUM(II)
  • BIS(BENZONITRILE)DICHLOROPALLADIUM(II)
  • Bis(benzonitrile)palladium chloride
  • BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE
  • BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE
  • DICHLOROBIS(BENZONITRILE)PALLADIUM(II)
  • Dichlorobis(benzonitrile)palladium(II) ,(C6H5CN)2PdCl2
  • Benzonitrile - dichloropalladium (2:1)
  • Bis(benzonitrile)palladium(II) chloride, 99+%
  • trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.7%
  • Trans-Bis(benzonitrile)dichloropalladium(II) Can be used to form catalysts in situ by separate addition of ligand
  • Dichlorobis(benzonitrile)palladium(II),99%
  • Palladium, bis(benzonitrile)dichloro-
  • Palladium(II)chloro-bis(benzonitrile)
  • trans-Bis(benzonitrile)dichloropalladium(II), Pd
  • Dichlorobis(benzonitrile)palladium (II) ,98%
  • Bis(benzonitrile)palladiuM(II)
  • trans-Bis(benzonitrile)dichloropalladiuM(II), Pd 27.1%
  • Bis(benzonitrile)palladiuM(II) chloride, 99+% 1GR
  • Bis(benzonitrile)palladium(II) Dichloride &gt
  • Bis(benzonitrile)dichloropalladium(Ⅱ)
  • Bis(benzonitriL
  • Bis(benzonitrile)palladium dichloride
  • Bis(benzonitrile)palladium chloride ISO 9001:2015 REACH
  • Bis(benzonitrile)palladium(II)chloride 14220-64-5
  • Bis(benzonitrile)palladium(II) Dichloride extrapure, 27.4% Pd
  • BIS (BENZONITRILE) DICHLORO PALLADIUM (II) For synthesis
  • Bis(benzonitrile
  • 14220-64-5
  • PdCl2C6H5CN2
  • C6H5CN2PdCl2
  • C14H10N2PdCl2
  • C14H10Cl2N2Pd
  • 2C7H5NCl2Pd
  • Classes of Metal Compounds
  • Transition Metal Compounds