4-Fluorobenzaldehyde

ChemicalBook > CAS DataBase List > 4-Fluorobenzaldehyde

4-Fluorobenzaldehyde

Product Name: 4-Fluorobenzaldehyde
CAS No.: 459-57-4
Chemical Name: 4-Fluorobenzaldehyde
Synonyms: PFBA;P-FLUOROBENZALDEHYDE;PFAD;Benzaldehyde, 4-fluoro-;NSC 68095;JACS-459-57-4;AKOS BBS-00003166;4-Fluorbenzaldehyd;P-FLUORBENZALDEHYDE;p-Fluoro benzaldehy
CBNumber: CB6299747
Molecular Formula: C7H5FO
Formula Weight: 124.11
MOL File: 459-57-4.mol

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4-Fluorobenzaldehyde Property

Melting point:: -10 °C (lit.)
Boiling point:: 181 °C/758 mmHg (lit.)
Density: 1.157 g/mL at 25 °C (lit.)
vapor pressure: 19 hPa (70 °C)
refractive index: n20/D 1.521(lit.)
Flash point:: 134 °F
storage temp.: Store below +30°C.
solubility: Chloroform, Methanol
form: Liquid
color: Clear colorless to yellow
Specific Gravity: 1.157
Water Solubility: IMMISCIBLE
Sensitive: Air Sensitive
BRN: 385857
Stability:: Air Sensitive
InChIKey: UOQXIWFBQSVDPP-UHFFFAOYSA-N
CAS DataBase Reference: 459-57-4(CAS DataBase Reference)
NIST Chemistry Reference: Benzaldehyde, 4-fluoro-(459-57-4)
EPA Substance Registry System: Benzaldehyde, 4-fluoro- (459-57-4)

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Safety

Hazard Codes: Xi,F
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39-36/37/39-27
RIDADR: UN 1989 3/PG 3
WGK Germany: 2
F: 9-23
Hazard Note: Flammable
TSCA: T
HazardClass: 3.2
PackingGroup: III
HS Code: 29130000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 128376
Product name: 4-Fluorobenzaldehyde
Purity: 98%
Packaging: 10g
Price: $29.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 128376
Product name: 4-Fluorobenzaldehyde
Purity: 98%
Packaging: 50g
Price: $76.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.18537
Product name: 4-Fluorobenzaldehyde
Purity: for synthesis
Packaging: 25mL
Price: $51.5
Updated: 2023/01/07

TCI Chemical

Product number: F0191
Product name: 4-Fluorobenzaldehyde
Purity: >98.0%(GC)
Packaging: 25mL
Price: $32
Updated: 2024/03/01

TCI Chemical

Product number: F0191
Product name: 4-Fluorobenzaldehyde
Purity: >98.0%(GC)
Packaging: 250mL
Price: $183
Updated: 2024/03/01

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4-Fluorobenzaldehyde Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to yellow liquid

Uses

Usually used in the preparation of pyrazolopyridine UR-13756.

Uses

4-Fluorobenzaldehyde is used in the preparation of pyrazolopyridine derivative, which finds application as mitogen-activated protein kinase (MAPK) inhibitor. It also serves as a synthetic intermediate in the preparation of pharmaceutical compounds.

Uses

4-Fluorobenzaldehyde is a fluorinated benzaldehyde with inhibitory activity of mushroom tyrosinase. 4-Fluorobenzaldehyde is commonly used as a synthetic intermediate in the preparation of pharmaceutic al compounds.

Synthesis

4-Fluorobenzaldehyde is produced by a commercially feasible process. The process comprises heating a mixture of fluorobenzene and a strong Lewis acid with dissolved hydrogen halide in an atmosphere of carbon monoxide at about 45 to about 100° C. and at a total pressure of about 150 psig up to the maximum pressure rating of the reactor. Formed is a reaction mass containing a Lewis acid complex of 4-fluorobenzaldehyde and at least a halobis(fluorophenyl)methane by-product. The complex is broken by quenching the reaction mass with a Lewis acid-solvating liquid to liberate 4-fluorobenzaldehyde. By-product halobis(fluorophenyl)methane is converted to di(fluorophenyl)methanol to avoid potential corrosion problems and formation of light-sensitive color bodies in the recovered 4-fluorobenzaldehyde.

4-Fluorobenzaldehyde Preparation Products And Raw materials

Raw materials

4-Chlorobenzaldehyde p-Fluorotoluene Benzyl dichloride 4-Chlorotoluene

Preparation Products

4-N-PROPOXYBENZALDEHYDE 4-Pyrazol-1-yl-benzaldehyde 3-Bromo-4-fluorobenzaldehyde 2-[2-(4-Fluorophenyl)-2-oxo-1-phenylethyl]-4-methyl-3-oxo-N-phenylpentanamide 4-Fluorobenzoic acid (5-Fluoro-2-methyl-1H-inden-3-yl)acetic acid Rosiglitazone 4-Fluorocinnamic acid DL-3-(4-Fluorophenyl)alanine 4-(1H-Imidazol-1-yl)benzaldehyde 4-Fluoro-3-phenoxybenzaldehyde

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View Lastest Price from 4-Fluorobenzaldehyde manufacturers

Wuhan Circle Star Chem-medical Technology Co.,Ltd

Product: 4-Fluorobenzaldehyde 459-57-4
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98
Supply Ability: 1000
Release date: 2025-01-02

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: 4-Fluorobenzaldehyde 459-57-4
Price: US $70.00-25.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-06-05

Hebei Chuanghai Biotechnology Co., Ltd

Product: 4-Fluorobenzaldehyde 459-57-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-28

459-57-4, 4-FluorobenzaldehydeRelated Search:

4-Fluorobenzoic acid Florfenicol 3-Fluorobenzaldehyde Pentafluorobenzaldehyde 4-Bromofluorobenzene 2,6-Difluorobenzaldehyde Ethyl 4-fluorobenzoate Transfluthrin 1,2-Difluorobenzene 4-Fluoroanisole 4-Fluorobenzoyl chloride 4-Fluorothiophenol 4-Fluoronitrobenzene 4-Fluorobenzyl alcohol 4-Methylbenzyl chloride 4-Chlorobenzaldehyde p-Fluorotoluene 4-Fluoromandelic acid

JACS-459-57-4

4-Fluorobenzaldehyde, p-Fluorobenzaldehyde, Benzaldehyde 4-fluoro-, 4-fluoro-benzaldehyde

Paroxetine Impurity 58

4-fluoro-benzaldehyd

Benzaldehyde, p-fluoro-

PFAD

PFBA

P-FLUOROBENZALDEHYDE

PARA FLUOROBENZALDEHYDE

FLUOROBENZALDEHYDE(4-)

LABOTEST-BB LT00930357

AKOS BBS-00003166

p-Fluorobenzaldehyde 4-Fluorobenzaldehyde

4-Fluorobenzaldehyde,98%

Benzaldehyde, 4-fluoro-

4-Fluorobenzaldehyde99%

4-Fluorbenzaldehyd

4-FLUORO-BENZALDEHYDE 99.5%

19) PARA FLUORO BENZALDEHYDE

P-FLUORBENZALDEHYDE

4-FLUOROBENZALDEHYDE

4-Fluorobenzaldehyde≥ 99% (GC)

p-Fluoro benzaldehyd

4-Fluorobenzaldehyde, AcroSeal, 98+%

4-Fluorobenzaldehyde for synthesis

4-Fluorobenzaldehyde, 98+%, AcroSeal

4-Fluorobenzaldehyde, 98+% 250ML

4-Fluorobenzaldehyde, 98+% 50ML

p-Fluorobenzenecarboxaldehyde

NSC 68095

Benzaldehyde, p-fluoro- (6CI,7CI,8CI)

p-Fluoro benzaldehy

The fluoro benzaldehyde

Retigabine Genotoxic Impurity 3: 4-Fluorobenzaldehyde

4-Fluorobenzaldehyde&gt

Atorvastatin Impurity 195

p-Fluorobenzenecarboxaldehyde (Atorvastatin calcium)

4-Fluorobenzaldehyde pure, 98%

4-Fluorobenzaldehyde, 98+%, AcroSeal&trade

Atorvastatin Impurity 112

4-Fluorobenzaldehyde CAS.459-57-4

4-Fluoro-4-methylacetophenone

4-Fluorobenzaldehyde， ≥ 97.0%

Atorvastatin calcium impurity 69

459-57-4

459-57-0

2615-30-4

Organic Building Blocks

Carbonyl Compounds

Aldehydes

Building Blocks

Aldehydes

Carbonyl Compounds

Fluoro-Aromatics

Benzaldehyde

Fluorobenzene