ChemicalBook > CAS DataBase List > 4-Bromoisoquinoline

4-Bromoisoquinoline

Product Name
4-Bromoisoquinoline
CAS No.
1532-97-4
Chemical Name
4-Bromoisoquinoline
Synonyms
NSC 56333;4-BromoisoquinoL;4-Bromoisoquinoli;4-Bromoisquinoline;4-bromoisoqunoline;4-BROMOISOQUINOLINE;Isoquinoline, 4-broMo-;LABOTEST-BB LT01143353;4-Bromoisoquinoline >4-Isoquinolinyl Bromide
CBNumber
CB7457317
Molecular Formula
C9H6BrN
Formula Weight
208.05
MOL File
1532-97-4.mol
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4-Bromoisoquinoline Property

Melting point:
40-43 °C (lit.)
Boiling point:
280-285 °C (lit.)
Density 
1.5617 (rough estimate)
refractive index 
1.6641 (estimate)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Chloroform, Methanol
pka
3.30±0.10(Predicted)
form 
Crystalline Solid
color 
White to light beige
BRN 
114431
InChI
InChI=1S/C9H6BrN/c10-9-6-11-5-7-3-1-2-4-8(7)9/h1-6H
InChIKey
SCRBSGZBTHKAHU-UHFFFAOYSA-N
SMILES
C1C2=C(C=CC=C2)C(Br)=CN=1
CAS DataBase Reference
1532-97-4(CAS DataBase Reference)
NIST Chemistry Reference
Isoquinoline, 4-bromo-(1532-97-4)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-21/22-20/21/22
Safety Statements 
26-37/39-36/37/39-22-36
WGK Germany 
3
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B70202
Product name
4-Bromoisoquinoline
Purity
98%
Packaging
10g
Price
$67.6
Updated
2024/03/01
Sigma-Aldrich
Product number
B70202
Product name
4-Bromoisoquinoline
Purity
98%
Packaging
25g
Price
$97.2
Updated
2024/03/01
TCI Chemical
Product number
B0930
Product name
4-Bromoisoquinoline
Purity
>98.0%(GC)
Packaging
10g
Price
$69
Updated
2024/03/01
TCI Chemical
Product number
B0930
Product name
4-Bromoisoquinoline
Purity
>98.0%(GC)
Packaging
25g
Price
$138
Updated
2024/03/01
Alfa Aesar
Product number
A15951
Product name
4-Bromoisoquinoline, 98%
Packaging
5g
Price
$46.65
Updated
2024/03/01
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4-Bromoisoquinoline Chemical Properties,Usage,Production

Chemical Properties

Pale Yellow Solid

Uses

Shows selective inhibition of cAMP-dependent protein kinase

Preparation

2-Alkynyl benzyl azides could smoothly undergo an electrocyclic reaction catalyzed by palladium to afford either 4-bromoisoquinoline or 4-bromoisquinolones selectively under different conditions. 4-Bromoisoquinoline was synthesised in the presence of PdBr2/CuBr2/LiBr in MeCN, and 4-bromoisoquinolone was selectively produced with PdBr2/CuBr2/HOAc in CH2ClCH2Cl[1].

Synthesis Reference(s)

Journal of Heterocyclic Chemistry, 10, p. 409, 1973 DOI: 10.1002/jhet.5570100326

References

[1] Hong-ping Zhang, Hongzhan Xiao, Hong‐Yan Li. “A Selective Synthesis of 4-Bromoisoquinoline and 4-Bromoisquinolone.” Journal of Chemical Research-s (2013).

4-Bromoisoquinoline Preparation Products And Raw materials

Raw materials

Preparation Products

4-Isoquinolineboronic acid ISOQUINOLINE-4-BORONIC ACID 2,2-DIMETHYLPROPANEDIOL-1,3 CYCLIC ESTER
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4-Bromoisoquinoline Suppliers

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View Lastest Price from 4-Bromoisoquinoline manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
4-Bromoisoquinoline 1532-97-4
Price
US $30.00-10.00/kg
Min. Order
10kg
Purity
99%
Supply Ability
100000kg
Release date
2024-08-14
Henan Fengda Chemical Co., Ltd
Product
4-Bromoisoquinoline 1532-97-4
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-24
Henan Aochuang Chemical Co.,Ltd.
Product
4-Bromoisoquinoline 1532-97-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-12

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  • 4-BROMOISOQUINOLINE
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  • Building Blocks
  • Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Isoquinolines
  • Building Blocks
  • Chemical Synthesis
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Isoquinoline
  • Organohalides
  • wq
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Isoquinolines
  • IsoquinolinesBuilding Blocks
  • Aromatics Compounds
  • Aromatics
  • Inhibitors
  • Quinolines, Isoquinolines & Quinoxalines
  • Quinolines, Quinazolines and derivatives
  • Quinolines, Isoquinolines & Quinoxalines
  • Quinoline&Isoquinoline
  • Isoquinoline Derivertives
  • Halides
  • Heterocycles