ChemicalBook > CAS DataBase List > Triisopropyl borate

Triisopropyl borate

Product Name
Triisopropyl borate
CAS No.
5419-55-6
Chemical Name
Triisopropyl borate
Synonyms
TIPB;ISOPROPYL BORATE;Triisoproyl borate;BORON ISOPROPOXIDE;Triisopropyl borat;TRIISOPROPOXYBORANE;BORIC ACID TRIISOPROPYL ESTER;Isop;Triisopropylbrate;Triisopropoxyboron
CBNumber
CB7853784
Molecular Formula
C9H21BO3
Formula Weight
188.07
MOL File
5419-55-6.mol
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Triisopropyl borate Property

Melting point:
-59 °C
Boiling point:
139-141 °C (lit.)
Density 
0.815 g/mL at 25 °C (lit.)
vapor pressure 
76 mm Hg ( 75 °C)
refractive index 
n20/D 1.376(lit.)
Flash point:
62.6 °F
storage temp. 
Store below +30°C.
solubility 
Miscible with ether, ethanol, isopropanol and benzene.
form 
Liquid
Specific Gravity
0.815
color 
Clear colorless
Water Solubility 
decomposes
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Sensitive 
Moisture Sensitive
BRN 
1701469
CAS DataBase Reference
5419-55-6(CAS DataBase Reference)
NIST Chemistry Reference
Boric acid (h3bo3), tris(1-methylethyl) ester(5419-55-6)
EPA Substance Registry System
Triisopropyl orthoborate (5419-55-6)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11
Safety Statements 
7-16-23-24/25-33-9
RIDADR 
UN 2616 3/PG 2
WGK Germany 
2
RTECS 
ED5950000
F 
10-21
TSCA 
T
HazardClass 
3
PackingGroup 
II
HS Code 
29209085
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.41264
Product name
Triisopropyl borate
Purity
for synthesis
Packaging
50mL
Price
$54.5
Updated
2024/03/01
Sigma-Aldrich
Product number
8.41264
Product name
Triisopropyl borate
Purity
for synthesis
Packaging
100mL
Price
$83.6
Updated
2024/03/01
Sigma-Aldrich
Product number
8.41264
Product name
Triisopropyl borate
Purity
for synthesis
Packaging
500mL
Price
$230
Updated
2024/03/01
Sigma-Aldrich
Product number
197335
Product name
Triisopropyl borate
Purity
≥98%
Packaging
80g
Price
$53.5
Updated
2024/03/01
Sigma-Aldrich
Product number
197335
Product name
Triisopropyl borate
Purity
≥98%
Packaging
2kg
Price
$559
Updated
2024/03/01
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Triisopropyl borate Chemical Properties,Usage,Production

Chemical Properties

clear colourless liquid

Uses

Triisopropyl borate is used as reagent in Pd-catalyzed coupling reaction with aryl halides such as Suzuki reaction. It is used as a reagent for the preparation of the boronic acids and esters; as a Lewis acid catalyst and involved in the ortho-borylation of 1-substituted naphthalenes. Furthermore, it plays an important role as a catalyst for the production of resins, waxes, paints and varnishes.

General Description

A colorless liquid. Flash point 93°F. Less dense than water and insoluble in water. Vapors heavier than air. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Borates, such as Triisopropyl borate, behave similarly to esters in that they react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters/borates with alkali metals and hydrides.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Triisopropyl borate Preparation Products And Raw materials

Raw materials

Preparation Products

2-Fluoro-4-methylphenylboronic acid 4-CHLORO-2-METHYLPHENYLBORONIC ACID 2-PHENOXYPHENYLBORONIC ACID 5-Fluoro-2-methoxyphenylboronic acid 2-Chloropyridine-5-boronic acid 3-ISOPROPYLPHENYLBORONIC ACID 2-Methoxy-5-pyridineboronic acid 2-Methoxyphenylboronic acid 4-Carboxylphenylboronic acid pinacol ester (6-ETHOXYPYRIDIN-3-YL)BORONIC ACID 5-Methylthiophene-2-boronic acid 3-Thiopheneboronic acid 5-Chloropyridine-2-boronic acid 3-CYANOPYRIDIN-4-YLBORONIC ACID 3-Methoxyphenylboronic acid 5-Methylpyridine-3-boronic acid 2-CYANOPYRIDIN-3-YLBORONIC ACID 2-Bromopyridine-5-boronic acid 2-Cyanophenylboronic acid 2,6-Difluorophenylboronic acid (4-METHOXYPHENYL)-BORANE 4-Hydroxyphenylboronic acid 3-Methoxycarbonylphenylboronic acid 2-(Trifluormethoxy)phenylboronic acid 3-Chloro-5-fluorophenylboronic acid 2-BROMOPYRIDIN-3-YLBORONIC ACID 5-Bromopyridine-3-boronic acid 4-CYANOPYRIDIN-3-YLBORONIC ACID 2-Methoxycarbonylphenylboronic acid 3-Cyanophenylboronic acid 3-Chloro-4-pyridineboronic acid hydrate 5-Methoxypyridine-3-boronic acid ISOQUINOLINE-4-BORONIC ACID 2,2-DIMETHYLPROPANEDIOL-1,3 CYCLIC ESTER 5-Pyrimidinylboronic acid 2,3-Difluorophenylboronic acid 1-Naphthylboronic acid 2-Formylfuran-5-boronic acid 2-Isopropylphenylboronic acid 6-Methylpyridine-3-boronic Acid 5-Methyl-2-pyridineboronic acid
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Triisopropyl borate Suppliers

Americas 1 Belgium 5 Canada 2 China 268 Europe 2 France 1 Germany 11 India 34 Japan 9 Poland 1 Russia 2 Singapore 1 South Korea 1 Spain 1 Switzerland 3 United Kingdom 17 United States 54 Global 413
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View Lastest Price from Triisopropyl borate manufacturers

Hebei Duling International Trade Co. LTD
Product
Triisopropyl borate 5419-55-6
Price
US $35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 Ton
Release date
2023-02-06
Wuhan Boyuan Import & Export Co., LTD
Product
Isop (Triisopropyl borate) CasNo: 5419-55-6 5419-55-6
Price
US $1.00/G
Min. Order
100G
Purity
99.9%
Supply Ability
50000 tons
Release date
2018-11-20
Hebei Mojin Biotechnology Co., Ltd
Product
Triisopropyl borate 5419-55-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-13

5419-55-6, Triisopropyl borateRelated Search:

Methyl acrylate Triisopropyl orthoformate Isopropyl acetate Isopropyl myristate Isopropylboronic acid Potassium chloride Isopropyl salicylate Orthoboric acid Isopropyl palmitate Triisopropyl phosphite BUTYL OLEATE Diisopropyl azodicarboxylate Tris(trimethylsilyl)phosphate Titanium tetraisopropanolate Boric acid TRIMETHYLENE BORATE Mycophenolate mofetil Diphenyl chlorophosphate Isopropyl Borate

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