ChemicalBook > CAS DataBase List > Methyl4-amino-2-methylbenzoate

Methyl4-amino-2-methylbenzoate

Product Name: Methyl4-amino-2-methylbenzoate
CAS No.: 6933-47-7
Chemical Name: Methyl4-amino-2-methylbenzoate
Synonyms: Methyl 4-amino-2-methylbenzoate 98%;4-Amino-2-methylbenzoic acid methyl ester;Benzoic acid, 4-amino-2-methyl-, methyl ester;4-Amino-2-methylbenzoic acid methyl ester (9CI aci);5-Amino-2-(methoxycarbonyl)toluene, 4-(Methoxycarbonyl)-3-methylaniline
CBNumber: CB81074196
Molecular Formula: C9H11NO2
Formula Weight: 165.19
MOL File: 6933-47-7.mol

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Methyl4-amino-2-methylbenzoate Property

Boiling point:: 302.4±22.0 °C(Predicted)
Density: 1.132±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: solid
pka: 2.59±0.10(Predicted)
color: Light brown to brown
InChI: InChI=1S/C9H11NO2/c1-6-5-7(10)3-4-8(6)9(11)12-2/h3-5H,10H2,1-2H3
InChIKey: NRTWXBXJSGGTTE-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(N)C=C1C

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Safety

HS Code: 2921420090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: M331193
Product name: Methyl4-Amino-2-methylbenzoate
Packaging: 5g
Price: $110
Updated: 2021/12/16

AK Scientific

Product number: J51101
Product name: Methyl4-amino-2-methylbenzoate
Packaging: 100g
Price: $135
Updated: 2021/12/16

Matrix Scientific

Product number: 075155
Product name: Methyl 4-amino-2-methylbenzoate
Purity: 95+%
Packaging: 1g
Price: $153
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4758-1-X0
Product name: Methyl 4-amino-2-methylbenzoate
Purity: 98%
Packaging: 5G
Price: $24
Updated: 2021/12/16

Apolloscientific

Product number: OR61046
Product name: Methyl4-amino-2-methylbenzoate
Purity: 98%
Packaging: 5g
Price: $25
Updated: 2021/12/16

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Methyl4-amino-2-methylbenzoate Chemical Properties,Usage,Production

Synthesis

62621-09-4

6933-47-7

Methyl 2-methyl-4-nitrobenzoate (Intermediate 5) (3.25 g, 16.6 mmol) was used as raw material, which was dissolved in ethanol, 10% Pd/C (catalytic amount) and ammonium formate (10.5 g, 0.17 mmol) were added. The reaction mixture was stirred at 40 °C for 2 hours. After completion of the reaction, the mixture was filtered through diatomaceous earth and the diatomaceous earth was washed with ether. The filtrate and washings were combined and the solvent was evaporated under reduced pressure to give the crude product. The crude product was dissolved in ether and washed with water to remove water-soluble impurities. The organic phase was separated, dried with anhydrous Na2SO4, filtered and evaporated the solvent under reduced pressure to give methyl 2-methyl-4-aminobenzoate as a brown oil (2.8 g, quantitative yield). The structure of the product was confirmed by 1H NMR (300 MHz, CDCl3): δ 7.74 (d, 1H, J = 9.20Hz), 6.41 (m, 2H), 3.75 (s, 3H), 2.47 (s, 3H).

References

[1] Patent: WO2009/47240, 2009, A1. Location in patent: Page/Page column 29
[2] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 942 - 945
[3] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 946 - 949
[4] Bulletin de la Societe Scientifique de Bretagne, 1956, vol. 31, p. Sonderheft S.9,41
[5] Patent: WO2006/7542, 2006, A1. Location in patent: Page/Page column 24

Methyl4-amino-2-methylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl4-amino-2-methylbenzoate manufacturers

Career Henan Chemical Co

Product: Methyl4-amino-2-methylbenzoate 6933-47-7
Price: US $2.00/KG
Min. Order: 1KG
Purity: 98%MIN
Supply Ability: ASK
Release date: 2019-12-25

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6933-47-7

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