Methyl4-amino-2-methylbenzoate
- Product Name
- Methyl4-amino-2-methylbenzoate
- CAS No.
- 6933-47-7
- Chemical Name
- Methyl4-amino-2-methylbenzoate
- Synonyms
- Methyl 4-amino-2-methylbenzoate 98%;4-Amino-2-methylbenzoic acid methyl ester;Benzoic acid, 4-amino-2-methyl-, methyl ester;4-Amino-2-methylbenzoic acid methyl ester (9CI aci);5-Amino-2-(methoxycarbonyl)toluene, 4-(Methoxycarbonyl)-3-methylaniline
- CBNumber
- CB81074196
- Molecular Formula
- C9H11NO2
- Formula Weight
- 165.19
- MOL File
- 6933-47-7.mol
Methyl4-amino-2-methylbenzoate Property
- Boiling point:
- 302.4±22.0 °C(Predicted)
- Density
- 1.132±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- solid
- pka
- 2.59±0.10(Predicted)
- color
- Light brown to brown
- InChI
- InChI=1S/C9H11NO2/c1-6-5-7(10)3-4-8(6)9(11)12-2/h3-5H,10H2,1-2H3
- InChIKey
- NRTWXBXJSGGTTE-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C(N)C=C1C
Safety
- HS Code
- 2921420090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- M331193
- Product name
- Methyl4-Amino-2-methylbenzoate
- Packaging
- 5g
- Price
- $110
- Updated
- 2021/12/16
- Product number
- J51101
- Product name
- Methyl4-amino-2-methylbenzoate
- Packaging
- 100g
- Price
- $135
- Updated
- 2021/12/16
- Product number
- 075155
- Product name
- Methyl 4-amino-2-methylbenzoate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $153
- Updated
- 2021/12/16
- Product number
- 4758-1-X0
- Product name
- Methyl 4-amino-2-methylbenzoate
- Purity
- 98%
- Packaging
- 5G
- Price
- $24
- Updated
- 2021/12/16
- Product number
- OR61046
- Product name
- Methyl4-amino-2-methylbenzoate
- Purity
- 98%
- Packaging
- 5g
- Price
- $25
- Updated
- 2021/12/16
Methyl4-amino-2-methylbenzoate Chemical Properties,Usage,Production
Synthesis
62621-09-4
6933-47-7
Methyl 2-methyl-4-nitrobenzoate (Intermediate 5) (3.25 g, 16.6 mmol) was used as raw material, which was dissolved in ethanol, 10% Pd/C (catalytic amount) and ammonium formate (10.5 g, 0.17 mmol) were added. The reaction mixture was stirred at 40 °C for 2 hours. After completion of the reaction, the mixture was filtered through diatomaceous earth and the diatomaceous earth was washed with ether. The filtrate and washings were combined and the solvent was evaporated under reduced pressure to give the crude product. The crude product was dissolved in ether and washed with water to remove water-soluble impurities. The organic phase was separated, dried with anhydrous Na2SO4, filtered and evaporated the solvent under reduced pressure to give methyl 2-methyl-4-aminobenzoate as a brown oil (2.8 g, quantitative yield). The structure of the product was confirmed by 1H NMR (300 MHz, CDCl3): δ 7.74 (d, 1H, J = 9.20Hz), 6.41 (m, 2H), 3.75 (s, 3H), 2.47 (s, 3H).
References
[1] Patent: WO2009/47240, 2009, A1. Location in patent: Page/Page column 29
[2] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 942 - 945
[3] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 946 - 949
[4] Bulletin de la Societe Scientifique de Bretagne, 1956, vol. 31, p. Sonderheft S.9,41
[5] Patent: WO2006/7542, 2006, A1. Location in patent: Page/Page column 24
Methyl4-amino-2-methylbenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl4-amino-2-methylbenzoate Suppliers
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- info@activate-scientific.com
- Country
- Germany
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- Advantage
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View Lastest Price from Methyl4-amino-2-methylbenzoate manufacturers
- Product
- Methyl4-amino-2-methylbenzoate 6933-47-7
- Price
- US $2.00/KG
- Min. Order
- 1KG
- Purity
- 98%MIN
- Supply Ability
- ASK
- Release date
- 2019-12-25