Uses
ChemicalBook > CAS DataBase List > Ethyl acrylate

Ethyl acrylate

Uses
Product Name
Ethyl acrylate
CAS No.
140-88-5
Chemical Name
Ethyl acrylate
Synonyms
Ethy Acrylate;FEMA 2418;Ethyl propenoate;ETHYL 2-PROPENOATE;ACRYLIC ACID ETHYL ESTER;Ethyl acrylate, stabilized;2-988;NCI-C50384;carboset511;Carboset 511
CBNumber
CB8382425
Molecular Formula
C5H8O2
Formula Weight
100.12
MOL File
140-88-5.mol
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Ethyl acrylate Property

Melting point:
−71 °C(lit.)
Boiling point:
99 °C(lit.)
Density 
0.921 g/mL at 20 °C
vapor density 
3.5 (vs air)
vapor pressure 
31 mm Hg ( 20 °C)
refractive index 
n20/D 1.406(lit.)
FEMA 
2418 | ETHYL ACRYLATE
Flash point:
60 °F
storage temp. 
2-8°C
solubility 
20g/l
form 
Liquid
color 
Clear
Odor
Characteristic acrylic odor; sharp, fragrant; acrid; slightly nauseating; sharp, ester type.
Odor Threshold
0.00026ppm
explosive limit
1.8-14%(V)
Odor Type
plastic
Water Solubility 
1.5 g/100 mL (25 ºC)
FreezingPoint 
99.8℃
Merck 
14,3759
JECFA Number
1351
BRN 
773866
Henry's Law Constant
2.25(x 10-3 atm?m3/mol) at 20 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits
TLV-TWA 5 ppm (～20 mg/m3) (ACGIH), 25 ppm (～100 mg/m3 (MSHA, NIOSH), TWA skin 25 ppm (100 mg/m3) (OSHA); IDLH 2000 ppm (NIOSH).
Stability:
Stable, but may polymerize upon exposure to light. Highly flammable. Keep cool. Incompatible with oxidizing agents, peroxides and other polymerization initiators.
LogP
1.18 at 25℃
CAS DataBase Reference
140-88-5(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenoic acid, ethyl ester(140-88-5)
IARC
2B (Vol. 39, Sup 7, 71, 122) 2019
EPA Substance Registry System
Ethyl acrylate (140-88-5)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
11-20/21/22-36/37/38-43
Safety Statements 
9-16-33-36/37
RIDADR 
UN 1917 3/PG 2
WGK Germany 
2
RTECS 
AT0700000
F 
8
Autoignition Temperature
721 °F
TSCA 
Yes
HS Code 
2916 12 00
HazardClass 
3
PackingGroup 
II
Hazardous Substances Data
140-88-5(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 550 mg/kg LD50 dermal Rabbit 1800 mg/kg
IDLA
300 ppm
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
E9706
Product name
Ethyl acrylate
Purity
contains 10-20 ppm MEHQ as inhibitor, 99%
Packaging
1l
Price
$47.34
Updated
2024/03/01
Sigma-Aldrich
Product number
8.00836
Product name
Ethyl acrylate
Purity
(stabilised with hydroquinone monomethyl ether) for synthesis
Packaging
100mL
Price
$34.5
Updated
2024/03/01
Sigma-Aldrich
Product number
8.00836
Product name
Ethyl acrylate
Purity
(stabilised with hydroquinone monomethyl ether) for synthesis
Packaging
1L
Price
$53.7
Updated
2024/03/01
Sigma-Aldrich
Product number
76130
Product name
Ethyl acrylate
Purity
analytical standard
Packaging
5ml
Price
$82
Updated
2024/03/01
TCI Chemical
Product number
A0143
Product name
Ethyl Acrylate (stabilized with MEHQ)
Purity
>99.0%(GC)
Packaging
25mL
Price
$18
Updated
2024/03/01
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Ethyl acrylate Chemical Properties,Usage,Production

Uses

A monomer widely used in the production of polymers and copolymers for manufacturing textiles, latex paints, paper coatings, dirt release agents, and specialty plastics

Description

Ethyl acrylate is an organic compound with the formula CH2CHCO2CH2CH3. It is the ethyl ester of acrylic acid. It is a colourless liquid with a characteristic acrid odor. It is mainly produced for paints, textiles, and non-woven fibers . It is also a reagent in the synthesis of various pharmaceutical intermediates.

Chemical Properties

Ethyl acrylate has a characteristic penetrating and persistent odor. Ethyl acrylate is possibly carcinogenic to humans (IARC, California Proposition 65)

Chemical Properties

Ethyl acrylate is a colorless liquid. Sharp, acrid odor. The Odor Threshold is 0.00024~0.0009 ppm. 1.5 % soluble in water, miscible with alcohol and oils. Ethyl acrylate absorbs 1.5% water in aqueous media. It polymerizes easily under influence of air, heat or daylight. Fairly stable below 10℃. The polymer form is a transparent, resilient, odorless mass.

Physical properties

Clear, colorless liquid with a penetrating and pungent odor. Leonardos et al. (1969) and Nagata and Takeuchi (1990) reported odor threshold concentrations of 0.47 and 0.26 ppbv, respectively. Experimentally determined detection and recognition odor threshold concentrations were 1.0 μg/m3 (0.24 ppbv) and 1.5 μg/m3 (0.37 ppbv), respectively (Hellman and Small, 1974).

Occurrence

Reported found in pineapple, yellow passion fruit and durian (Durio zibethinus).

Uses

Ethyl acrylate is used in the manufacture ofacrylic resins, acrylic fibers, textile and papercoatings, adhesives, and leather finish resins;and as a flavoring agent.

Uses

Monomer for acrylic resins.

Uses

Ethyl Acrylate is a flavoring agent that is a clear, colorless liquid. its odor is fruity, harsh, penetrating, and lachrymatous (causes tears). it is sparingly soluble in water and miscible in alcohol and ether, and is obtained by chemical synthesis.

Preparation

By esterification of acrylic acid; by heating acetylene with HCl in alcoholic solution in the presence of Ni(CO)4; also from ethyl-3-chloropropionate passed over activated carbon at high temperature.

Production Methods

Ethyl acrylate is manufactured via oxidation of propylene to acrolein and then to acrylic acid. The acid is treated with ethanol to yield the ethyl ester .
Vinyl chloride reacts at 270 °C at >6895 kPa (68 atm) with ethanol in the presence of a cobalt and palladium catalyst to give ethyl acrylate in a yield of 17% .

Definition

ChEBI: Ethyl acrylate is an enoate ester.

Aroma threshold values

Detection: 0.2 ppb

General Description

A clear colorless liquid with an acrid odor. Flash point 60°F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Auto ignition temperature 721°F (383°C) (NTP). Less dense than water. Vapors heavier than air. Used to make paints and plastics.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

A flammable liquid, confirmed carcinogen. Ethyl acrylate can react vigorously with oxidizing reagents, peroxides,strong alkalis and polymerization initiators. [NTP] Ethyl acrylate reacts violently with chlorosulfonic acid [Sax, 9th ed., 1996, p. 1515]. When an inhibited monomer was placed in a clear glass bottle exposed to sunlight, exothermic polymerization set in and caused the bottle to burst. The use of brown glass or metal containers and increase in inhibitor concentration (to 200 ppm; tenfold) was recommended [MCA Case History No. 1759]. Ethyl acrylate may polymerize when exposed to light and Ethyl acrylate is subject to slow hydrolysis. Inhibitors do not function in the absence of air. Solutions in DMSO are stable for 24 hours under normal lab conditions. [NTP].

Hazard

Toxic by ingestion, inhalation, skin absorption; irritant to skin and eyes. Flammable, dangerous fire and explosion hazard. Possible carcinogen.

Health Hazard

Ethyl acrylate is a strong irritant to the eyes,skin, and mucous membranes. The liquid orits concentrated solutions can produce skinsensitization upon contact. It is toxic by allroutes of exposure. The toxicity is low inrats and mice and moderate in rabbits. Thetoxic effects from inhalation noted in animalswere congestion of lungs and degenerativechanges in the heart, liver, and kidney. Mon key exposed to 272 ppm for 28 days showedlethargy and weight loss; while exposure to1024 ppm caused death to the animals after2.2 days (Treon et al. 1949). By compari son, guinea pigs died of exposure to about1200 ppm for 7 hours. Ingestion of the liq uid may result in irritation of gastrointestinaltracts, nausea, lethargy, and convulsions
The LD50 values varied significantly indifferent species of animals. The oral LD50values in rabbits, rats, and mice are in therange 400, 800, and 1800 mg/kg, respectively. Animals administered ethyl acrylateshowed increased incidence of tumors inforestomach. However, there is no evidenceof carcinogenicity caused by this compoundin humans.

Flammability and Explosibility

Flammable

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: May occur; exclude moisture, light; avoid exposure to high temperatures; store in presence of air; Inhibitor of Polymerization: 13-17 ppm monomethyl ether of hydroquinone.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion and inhalation. Moderately toxic by skin contact and intraperitoneal routes. Human systemic effects by inhalation: eye, olfactory, and pulmonary changes. A skin and eye irritant. Characterized in its terminal stages by dyspnea, cyanosis, and convulsive movements. It caused severe local irritation of the gastroenteric tract; and toxic degenerative changes of cardiac, hepatic, renal, and splenic tissues were observed. It gave no evidence of cumulative effects. When applied to the intact skin of rabbits, the ethyl ester caused marked local irritation, erythema, edema, thickening, and vascular damage. Animals subjected to a fairly high concentration of these esters suffered irritation of the mucous membranes of the eyes, nose, and mouth as well as lethargy, dpspnea, and convulsive movements. A substance that migrates to food from packagmg materials. Flammable liquid. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. Violent reaction with chlorosulfonic acid. To fight fire, use CO2, dry chemical, or alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Safety

It is an acute toxin with an LD50 (rats, oral) of 1020 mg / kg and a TLV of 5 ppm. The International Agency for Research on Cancer stated, "Overall evaluation, Ethyl acrylate is possibly carcinogenic to humans (Group 2B)." The United States Environmental Protection Agency (EPA) states, "Human studies on occupational exposure to ethyl acrylate... have suggested a relationship between exposure to the chemical(s) and colorectal cancer, but the evidence is conflicting and inconclusive. In a study by the National Toxicology Program (NTP), increased incidences of squamous cell papillomas and carcinomas of the fore stomach were observed in rats and mice exposed via gavage (experimentally placing the chemical in the stomach). However, the NTP recently determined that these data were not relevant to human carcinogenicity since humans do not have a fore stomach, and removed ethyl acrylate from its list of carcinogens." (Occupational exposure generally involves exposure that occurs regularly, over an extended period of time.)
One favorable safety aspect is that ethyl acrylate has good warning properties; the odor threshold is much lower than any level of health concern. In other words, the bad odor warns people of ethyl acrylate's presence long before the concentration reaches a level capable of creating a serious health risk.

Potential Exposure

This material is used in emulsion polymers for paints, textiles, adhesives, coatings and binders; as a monomer in the manufacture of homopolymer and copolymer resins for the production of paints and plastic films

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 24- 48 h afterbreathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor orauthorized paramedic may consider administering a corticosteroid spray

Carcinogenicity

A retrospective study found an excess of colorectal cancers in one exposed population of workers; however, the data were confounded by other exposures and lack of association of causality and risk in similarly exposed populations from other locations. Therefore, there was inadequate evidence based on the study that ethyl acrylate is a human carcinogen . Ethyl acrylate is listed as USEPA group B2, “Probable human carcinogen”; IARC group B2, “Possibly carcinogenic in humans”; NIOSH, “Carcinogen with no further categorization”; NTP group 2, “Reasonably anticipated to be a carcinogen” and listed as a carcinogen by California Proposition 65 .
Dermal studies of acrylic acid, ethyl acrylate, and n-butyl acrylate using mice did not result in local carcinogenesis, but several mice in the ethyl acrylate-treated group did exhibit dermatitis, dermal fibrosis, epidermal necrosis, and hyperkeratosis .

Environmental Fate

Chemical/Physical. Polymerizes on standing and is catalyzed by heat, light, and peroxides (Windholz et al., 1983). Slowly hydrolyzes in water forming ethanol and acrylic acid. The reported rate constant for the reaction of ethyl acrylate with ozone in the gas phase was determined to be 5.70 x 10-18 cm3 mol/sec (Munshi et al., 1989).
At an influent concentration of 1,015 mg/L, treatment with GAC resulted in an effluent concentration of 226 mg/L. The adsorbability of the carbon used was 157 mg/g carbon (Guisti et al., 1974).

storage

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Ethyl acrylate must be stored to avoid contact with oxidizers (such as peroxides, perchlorates, chlorates, nitrates, andpermanganates), strong alkalis (such as sodium hydroxideand potassium hydroxide) and moisture since violent reactions occur. Store in tightly closed containers in a cool,well-ventilated area away from heat. Heat can cause ethylacrylate to react by itself. If this takes place in a closed container, an explosion could occur. Ethyl acrylate usually contains an inhibitor, such as hydroquinone or its methyl ether,to prevent a self-reaction. If it does not contain an inhibitor,the reaction may occur without the application of heat.Sources of ignition, such as smoking and open flames, areprohibited where ethyl acrylate is handled, used, or stored.Metal containers involving the transfer of 5 gallons or moreof ethyl acrylate should be grounded and bonded. Drumsmust be equipped with self-closing valves, pressure vacuumbungs, and flame arresters. Use only nonsparking tools andequipment, especially when opening and closing containersof ethyl acrylate. Wherever ethyl acrylate is used, handled,manufactured, or stored, use explosion-proof electricalequipment and fittings

Shipping

UN1917 Ethyl acrylate, Hazard Class: 3; Labels: 3-Flammable liquid

Purification Methods

Wash the ester repeatedly with aqueous NaOH until free from inhibitors such as hydroquinone, then wash it with saturated aqueous CaCl2 and distil it under reduced pressure. Hydroquinone should be added if the ethyl acrylate is to be stored for extended periods. [Beilstein 2 IV 1460.] LACHRYMATORY.

Toxicity evaluation

The toxic mode of action for ethyl acrylate is unknown. However, the parent compound may play a significant role since pretreatment of rats with a carboxylesterase inhibitor enhances the respiratory irritation and lethality produced by the inhalation of ethyl acrylate. The enhanced toxicity could be a direct effect of methyl acrylate on surrounding tissues and/or a secondary effect due to the increased conjugation of methyl acrylate with glutathione that occurs under these conditions which in turn can result in toxicity due to the depletion of local glutathione stores.

Incompatibilities

May form explosive mixture with air. Atmospheric moisture and strong alkalies may cause fire and explosions unless properly inhibited (Note: Inert gas blanket not recommended). Heat, light or peroxides can cause polymerization. Incompatible with oxidizers (may be violent), peroxides, polymerizers, strong alkalis; moisture, chlorosulfonic acid, strong acids; amines. May accumulate static electrical charges, and may cause ignition of its vapors. Polymerizes readily unless an inhibitor, such as hydroquinone is added. Uninhibited vapors may plug vents by the formation of polymers.

Waste Disposal

Incineration or by absorption and landfill disposal

Ethyl acrylate Preparation Products And Raw materials

Raw materials

Resin catalyst 2-Oxetanone FUMING SULFURIC ACID 3-Hydroxypropionitrile CARBON MONOXIDE Ethylene Acrolein Ethanol Acrylamide Ethyl 3-chloropropionate NICKEL CARBONYL Acrylic acid Ammonium bisulfate Self-interlinkage adhesive T Poly(acrylic acid) Acrylonitrile

Preparation Products

Ethyl 5-[3-(4,6-dimethoxy pyrimidyl-2-yl)ureido]methylpyrazolyl-4-carboxylic ester ETHYL 2-(BROMOMETHYL)ACRYLATE Enalapril Ethyl 3-(benzylamino)propanoate Ciprofloxacin hydrochloride Vinyl acetate-acrylate copolymer,emulsion Ethyl 3-(isopropylamino)propanoate Adhesive for electrostatic flocking carfentrazone-ethyl 2,4-Piperadinedione Ethyl 3-methylthiopropionate acrylic resin coating finish Thickening agent Leather coating agent of filling acrylic resin impregnanting agent for leather 3-AMINO-PROPIONIC ACID ETHYL ESTER 2,3,4,5-Tetrahydro-5-methyl-1H-pyrido[4,3-b]indol-1-one 1-BENZYL-3-METHYL-4-PIPERIDONE 5,6-DIHYDRO-4-(2-METHYL-2-PHENYLHYDRAZINO)-2-1H-PYRIDINONE Styrene-acrylic latex 4-Piperidinone ETHYL 4-PIPERIDONE-3-CARBOXYLATE HYDROCHLORIDE Poly(acrylic acid)
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Ethyl acrylate Suppliers

Americas 1 Argentina 1 Australia 3 Belgium 4 Canada 5 Chile 1 China 301 Europe 4 France 2 Germany 15 India 103 Indonesia 1 Italy 1 Japan 13 Malaysia 1 Russia 1 Singapore 2 Slovakia 1 South Africa 1 South Korea 5 Spain 3 Switzerland 2 The Netherlands 4 Turkey 1 United Arab Emirates 4 United Kingdom 10 United States 80 Global 570
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View Lastest Price from Ethyl acrylate manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Ethyl acrylate 140-88-5
Price
US $100.00/KG
Min. Order
1KG
Purity
99%min
Supply Ability
50tons
Release date
2024-10-31
Qingdao RENAS Polymer Material Co., Ltd.
Product
Ethyl Acrylate 140-88-5
Price
US $0.00/kg
Min. Order
20kg
Purity
99.5%
Supply Ability
20 tons
Release date
2024-05-30
Hebei Chuanghai Biotechnology Co,.LTD
Product
Ethyl acrylate 140-88-5
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20

140-88-5, Ethyl acrylateRelated Search:

2-Hydroxypropyl methacrylate 2-Ethylhexyl acrylate Methyl methacrylate Ethyl methacrylate Ethyl 2-(hydroxymethyl)acrylate Methyl acrylate Ethyl 3-ethoxyacrylate Acrylic acid Ethanol Butyl acrylate ISOXADIFEN-ETHYL 2-Ethoxyethanol ETHYL 2-CYANOACRYLATE Ethyl 3-benzoylacrylate 2-Hydroxyethyl acrylate Trinexapac-ethyl Ethylparaben Ethyl acetate

  • Acrylate d'ethyle
  • acrylated’ethyle
  • acrylated’ethyle(french)
  • Acrylic acid, ethyl ester (inhibited)
  • Akrylanem etylu
  • akrylanemetylu
  • Carboset 511
  • carboset511
  • CH2=CHCOOC2H5
  • Ethoxycarbonylethylene
  • Ethyl acrylate, inhibited
  • Ethyl ester of 2-propenoic acid
  • Ethyl propenoate
  • Ethylacrylaat
  • ethylacrylate,inhibited
  • ethylacrylate--2-propenoicacid,ethylester
  • Ethylacrylatemonomer
  • Ethylakrylat
  • ethylakrylat(czech)
  • Ethylester kyseliny akrylove
  • ethylesterkyselinyakrylove
  • ethylpropenoate
  • Etil acrilato
  • 2-PROPENOIC ACID ETHYL ESTER
  • ACRYLIC ACID ETHYL ESTER
  • FEMA 2418
  • ETHYL ACRYLATE
  • ETHYL 2-PROPENOATE
  • Acryl acid ethylester
  • ETHYL ACRYLATE, STAB.
  • ETHYL ACRYLATE 99.5+% FCC
  • ETHYL ACRYLATE, STAB., STANDARD FOR GC
  • ETHYL ACRYLATE GC STANDARD
  • EthylAcrylateForSynthesis
  • Ethyl acrylate, stabilized, 99.50%
  • Acrylsureethylester
  • ETHYLACRYLAT
  • Propenoic acid ethyl ester
  • 2-Propenoic acid, ethyl ester (I)
  • Ethyl acrylate, 99%, stab. with ca 20ppm 4-methoxyphenol
  • Ethyl Acrylate (stabilized with MEHQ)
  • Ethyl acrylate, 99.50%, stabilized
  • Ethyl acrylate, stabilized
  • 2-988
  • 2-Propenoic acid ethyl
  • Acrylic acid ethyl
  • RARECHEM AL BI 0670
  • Ethyl acrylate, 98+%
  • Ethyl acrylate 10g [140-88-5]
  • Ethyl acrylate, stabilized, 99.5%
  • Ethyl acrylate, 99.5%, stabilized
  • Ethyl acrylate, stabilized, 99.5% 1LT
  • Ethyl acrylate, stabilized, 99.5% 2.5LT
  • Ethyl acrylate, stabilized, 99.5% 25ML
  • etilacrilato
  • Etilacrilatului
  • etilacrilatului(roumanian)
  • femanumber2418