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4-Bromobenzaldehyde

Product Name
4-Bromobenzaldehyde
CAS No.
1122-91-4
Chemical Name
4-Bromobenzaldehyde
Synonyms
Bromobenzaldehyde;4-BBA;4-Brombenzaldehyd;4-bromo-benzaldehyd;P-BROMOBENZALDEHYDE;4-BROMOBENZYLALDEHYDE;4-Bromobenzaldehyde99%;BRBA1;DK484;4-BromobenzaL
CBNumber
CB9214370
Molecular Formula
C7H5BrO
Formula Weight
185.02
MOL File
1122-91-4.mol
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4-Bromobenzaldehyde Property

Melting point:
55-58 °C(lit.)
Boiling point:
66-68°C 2mm
Density 
1.85 g/cm3
refractive index 
1.5727 (estimate)
Flash point:
228 °F
storage temp. 
Store below +30°C.
solubility 
Chloroform, Ethyl Acetate
form 
Crystalline Solid
color 
White
Water Solubility 
INSOLUBLE
Sensitive 
Air Sensitive
BRN 
507100
InChIKey
ZRYZBQLXDKPBDU-UHFFFAOYSA-N
LogP
2.75 at 25℃
CAS DataBase Reference
1122-91-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzaldehyde, 4-bromo-(1122-91-4)
EPA Substance Registry System
Benzaldehyde, 4-bromo- (1122-91-4)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38-43
Safety Statements 
26-36/37-36/37/39-22
RIDADR 
2811
WGK Germany 
2
RTECS 
CU4810000
Hazard Note 
Irritant/Harmful/Air Sensitive
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29130000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B57400
Product name
4-Bromobenzaldehyde
Purity
99%
Packaging
10g
Price
$68.3
Updated
2024/03/01
Sigma-Aldrich
Product number
B57400
Product name
4-Bromobenzaldehyde
Purity
99%
Packaging
25g
Price
$110
Updated
2024/03/01
Sigma-Aldrich
Product number
8.04146
Product name
4-Bromobenzaldehyde
Purity
for synthesis
Packaging
10g
Price
$64.5
Updated
2024/03/01
Sigma-Aldrich
Product number
8.04146
Product name
4-Bromobenzaldehyde
Purity
for synthesis
Packaging
100g
Price
$290
Updated
2024/03/01
TCI Chemical
Product number
B0549
Product name
4-Bromobenzaldehyde
Purity
>97.0%(GC)
Packaging
25g
Price
$58
Updated
2024/03/01
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4-Bromobenzaldehyde Chemical Properties,Usage,Production

Chemical Properties

white crystalline solid

Uses

4-Bromobenzaldehyde is widely utilized as an intermediate for the preparation of agrochemicals, pharmaceuticals and other organic compounds. It is used as a precursor and reacts with sulfamethoxazole to prepare Schiff?s base, 4-[(4-Bromo-benzylidene)-amino]-N-(5-methyl-isoxazol-3-yl)-benzene sulfonamide, which can be used for the photo stability of polyvinyl chloride (PVC). It plays an important role in palladium-catalyzed mono- and bis-arylation of 3,4-(ethylenedioxy)thiophenes. It is employed in a cross-coupling study with potassium vinyltrifluoroborate.

Uses

Employed in palladium-catalyzed mono- and bis-arylation of 3,4-(ethylenedioxy)thiophenes. Also used in a cross-coupling study with potassium vinyltrifluoroborate.

Reactions

4-Bromobenzaldehyde is widely utilized as an intermediate for preparing agrochemicals, pharmaceuticals, and other organic compounds. It is used as a precursor and reacts with sulfamethoxazole to prepare Schiff?s base, 4-[(4-Bromo-benzylidene)-amino]-N-(5-methyl-isoxazol-3-yl)-benzene sulfonamide, which can be used for the photostability of polyvinyl chloride (PVC). It plays a vital role in palladium-catalyzed mono- and bis-arylation of 3,4-(ethylenedioxy)thiophenes. It is employed in a cross-coupling study with potassium vinyltrifluoroborate.

Synthesis Reference(s)

Journal of the American Chemical Society, 81, p. 4113, 1959 DOI: 10.1021/ja01524a080
Tetrahedron Letters, 21, p. 813, 1980 DOI: 10.1016/S0040-4039(00)71512-7

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4-Bromobenzaldehyde Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
K. Sakai & Co., Ltd.
Tel
--
Fax
--
Email
em@ksakai.co.jp
Country
Japan
ProdList
957
Advantage
58
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
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View Lastest Price from 4-Bromobenzaldehyde manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
4-Bromobenzaldehyde 1122-91-4
Price
US $79.00-38.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-11-21
Hubei Lidu New Material Technology Co., Ltd
Product
4-BROMOBENZALDEHYDE 1122-91-4
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2024-10-30
WUHAN FORTUNA CHEMICAL CO., LTD
Product
4-Bromobenzaldehyde 1122-91-4
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-09

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