Boc-Glycine hydrazide
- Product Name
- Boc-Glycine hydrazide
- CAS No.
- 6926-09-6
- Chemical Name
- Boc-Glycine hydrazide
- Synonyms
- BUTTPARK 77\04-08;BOC-GLYCINE HYDRAZIDE;Boc-Glycinehydrazide8%;Boc-Glycinehydrazide，98%;Butoxycarbonylglycine hydrazide;Boc-Glycine hydrazide USP/EP/BP;N-TERT-BUTOXYCARBONYLGLYCYLHYDRAZIDE;tert-Butyl (2-hydrazinyl-2-oxoethyl);2-Aminoacetohydrazide, 2-BOC protected;tert-butyl (2-hydrazino-2-oxoethyl)carbamate
- CBNumber
- CB9323340
- Molecular Formula
- C7H15N3O3
- Formula Weight
- 189.21
- MOL File
- 6926-09-6.mol
Boc-Glycine hydrazide Property
- Melting point:
- 111-115
- Boiling point:
- 386.5±25.0 °C(Predicted)
- Density
- 1.139±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- solid
- pka
- 11.40±0.46(Predicted)
- color
- Beige
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B809885
- Product name
- tert-ButylN-(2-Hydrazinyl-2-oxoethyl)carbamate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- E007
- Product name
- Boc-Glycinehydrazide
- Packaging
- 1g
- Price
- $47
- Updated
- 2021/12/16
- Product number
- FB38781
- Product name
- Boc-glycine hydrazide
- Packaging
- 2g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- OR2444
- Product name
- 2-Aminoacetohydrazide,2-BOCprotected
- Packaging
- 1g
- Price
- $83
- Updated
- 2021/12/16
- Product number
- 4158-1-X1
- Product name
- N-tert-butoxycarbonylglycylhydrazide
- Packaging
- 1g
- Price
- $92
- Updated
- 2021/12/16
Boc-Glycine hydrazide Chemical Properties,Usage,Production
Uses
Boc-Glycine hydrazide is used as organic synthesis intermediate and pharmaceutical intermediate, mainly used in laboratory research and development process and chemical production process.
Synthesis
N-Protected Hydrazides 2a-l; General Procedure The protected amino acid 1 (2 equiv) and EDAC (2 equiv) were dissolved in the minimum amount of CH2Cl2 at 0 ??C. The mixture was stirred at 0 ??C for 2 h. PhthNNH2 (1 equiv) was added and the mixture was stirred at 0 ??C for 1 h and then at r.t. overnight. Distillation of the solvent under reduced pressure gave a product which was dissolved in EtOAc and washed successively with 1 M KHSO4, sat. aq NaHCO3, and brine. The organic layer was then dried (Na2SO4), filtered, and concentrated in vacuo. The residue was precipitated with Et2O to yield compound 2. If necessary, the residue was purified by column chromatography (silica gel, hexane- EtOAc, 3:7 to 7:3). Compounds 4a-l; General Procedure Aminomethylated polystyrene resin (3 equiv; 1.1 mmol/g, 100-200 mesh) was conditioned for 10 min at r.t. in CH2Cl2. Then 2 (1 equiv) was added, and the mixture was slowly stirred for 24 h at r.t. The mixture was filtered and the solvent was evaporated in vacuo to give product 4. Compound 4h, yield 89%.
Boc-Glycine hydrazide Preparation Products And Raw materials
Raw materials
Preparation Products
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