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Hydroxyl-terminated polybutadiene

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Hydroxyl-terminated polybutadiene Basic information

Product Name:
Hydroxyl-terminated polybutadiene
Synonyms:
  • POLYBUTADIENE, DIHYDROXY TERMINATED
  • POLY(BUTADIENE)DIOL
  • POLYBUTADIENE, HYDROXYL FUNCTIONALIZED
  • POLYBUTADIENE HYDROXYL TERMINATED
  • 1,3-Butadiene,homopolymer,hydroxy-terminated
  • Hydroxyl-terminated polybutadiene
  • Hydroxyl-terminated polybutadiene(HTPB)
  • fluid rubber
CAS:
69102-90-5
MW:
0
EINECS:
614-926-3
Product Categories:
  • Polymers
  • Dienes
  • Hydrophobic Polymers
  • Polymer Science
  • Hydrophobic Polymers
  • Materials Science
  • Polymer Science
Mol File:
Mol File
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Hydroxyl-terminated polybutadiene Chemical Properties

Density 
0.913 g/mL at 25 °C
refractive index 
n20/D 1.5126
Flash point:
113 °C
EPA Substance Registry System
1,3-Butadiene, homopolymer, hydroxy-terminated (69102-90-5)
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Safety Information

WGK Germany 
3
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Hydroxyl-terminated polybutadiene Usage And Synthesis

Description

Hydroxyl-terminated polybutadiene (HTPB) is a liquid rubber with a long non-polar carbon chain. Because of its low glass transition temperature, high elasticity, high water resistance, and hydrophobicity, HTPB is widely used in adhesives, foam, rocket propellant, and other fields. HTPB is a commonly used binding polymer in industry to produce polyurethanes. HTPB synthesis via allylic radical propagation leads to varied compositions and conformations that govern this polymer's bulk physical and mechanical properties. The low surface energy and flexibility at low temperatures of HTPB-based polyurethane elastomers have been extensively studied [1-2].

References

[1] R. Buszek. “Structure and energetics of hydroxyl‐terminated polybutadiene via density functional theory.” Propellants, Explosives, Pyrotechnics (2023).
[2] Liu, Jiaran et al. “Synthesis and characterization of hydroxyl-terminated polybutadiene modified low temperature adaptive self-matting waterborne polyurethane.” RSC Advances 10 (2023): 7020–7029.

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