2-Nitrochlorobenzene Chemical Properties

Melting point:

31-33 °C(lit.)

Boiling point:

246 °C(lit.)

Density 

1.348 g/mL at 25 °C(lit.)

vapor density 

5.4 (vs air)

vapor pressure 

0.04 mm Hg ( 25 °C)

refractive index 

1.5520 (estimate)

Flash point:

>230 °F

storage temp. 

Store below +30°C.

solubility 

alcohol: soluble

form 

Fused Crystalline Mass

color 

Yellow

PH

6 (0.4g/l, H2O, 20℃)

explosive limit

1.15-13.1%(V)

Water Solubility 

0.43 g/L (20 ºC)

Merck 

14,2151

BRN 

509273

Stability:

Stable. Combustible. Incompatible with strong oxidizing agents, reducing agents, strong bases, alkali metals.

InChIKey

BFCFYVKQTRLZHA-UHFFFAOYSA-N

CAS DataBase Reference

88-73-3(CAS DataBase Reference)

IARC

2B (Vol. 65, 123) 2020

NIST Chemistry Reference

Benzene, 1-chloro-2-nitro-(88-73-3)

EPA Substance Registry System

o-Chloronitrobenzene (88-73-3)

Safety Information

Hazard Codes 

T

Risk Statements 

22-24-52-53-52/53

Safety Statements 

36/37/39-45-60-38-28A

RIDADR 

UN 1578 6.1/PG 2

WGK Germany 

2

RTECS 

CZ0875000

Autoignition Temperature

500 °F

Hazard Note 

Toxic

TSCA 

Yes

HazardClass 

6.1

PackingGroup 

II

HS Code 

29049085

Hazardous Substances Data

88-73-3(Hazardous Substances Data)

MSDS

• Language:English Provider:2-Nitrochlorobenzene
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

2-Nitrochlorobenzene Usage And Synthesis

Chemical Properties

yellow solid with a characteristic odour

Uses

Intermediate, especially for dyes.

Uses

Chemical intermediate in manufacture of dyes, picric acid, lumber preservatives, and diaminophenol hydrochloride (a photographic developer)

General Description

Yellow crystals with an aromatic odor. Sinks in water.

Air & Water Reactions

2-Nitrochlorobenzene may be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

O-NITROCHLOROBENZENE is incompatible with strong bases and strong oxidizing agents. 2-Nitrochlorobenzene will react with ammonia.

Hazard

Toxic by inhalation and ingestion. Combustible. Questionable carcinogen.

Health Hazard

INHALATION: Headache, languour, anemia. Irritation of nose and throat, cyanosis, shallow respiration, convulsions, and coma. EYES: Irritation. SKIN: Irritation. INGESTION: Forms methemoglobin giving rise to cyanosis and blood changes.

Safety Profile

Suspected carcinogen with experimental carcinogenic and neoplastigenic data. Poison by ingestion, skin contact, and probably inhalation. Combustible when exposed to heat or flame. To fight fire, use water, foam. Potentially explosive reaction with ammonia at 160℃/30 bar. When heated to decomposition it emits toxic fumes of Cl-, NOx, and phosgene. See also other chloronitrobenzene entries and NITRO COMPOUNDS of AROMATIC HYDROCARBONS.

Purification Methods

Crystallise it from EtOH, MeOH or pentane (charcoal). [Beilstein 5 IV 721.]

2-Nitrochlorobenzene(88-73-3)Related Product Information

• Nitrobenzene
• 2,3-Dichloronitrobenzene
• Nitrochlorobenzene, p-,Nitrochlorobenzene, para,P-NITROCHLOROBENZENE,4-NITROCHLOROBENZENE,PARA NITROCHLOROBENZENE
• 2-Chlorobenzyl chloride
• 2,3,4-TRICHLORONITROBENZENE
• 2,6-Dichloronitrobenzene
• Nitrochlorobenzene, meta-,m-nitrochlorobenzene(1-chloro-3-nitrobenzene
• TECNAZENE
• 2-Chloro-3-nitrobenzoic acid
• 4-CHLORO-3,5-DINITROBENZONITRILE
• Quintozine
• Chlorodimethylpentafluorophenylsilane
• 2,3,4,5-Tetrachloronitrobenzene
• NITROCHLOROBENZENE
• 2,5-Dichloronitrobenzene
• 1,2,3-Trichlorobenzene
• 2-Chlorotoluene
• Difluorochloromethane