ISOPROPENYLMAGNESIUM BROMIDE
ISOPROPENYLMAGNESIUM BROMIDE Basic information
- Product Name:
- ISOPROPENYLMAGNESIUM BROMIDE
- Synonyms:
-
- Isopropenylmagnesium bromide, 0.5 M solution in THF, HySeal
- ISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURAN
- ISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURAN
- ISOPROPENYLMAGNESIUM BROMIDE 0.5 M THF
- Isopropenylmagnesium bromide( 1.0 M solution in THF)
- IsopropenyL
- Isopropenylmagnesium bromide 1M solution in tetrahydrofuran
- ISOPROPENYLMAGNESIUM BROMIDE
- CAS:
- 13291-18-4
- MF:
- C3H5BrMg
- MW:
- 145.28
- EINECS:
- 603-688-6
- Product Categories:
-
- Grignard Reagent
- Alkenyl
- Grignard Reagents
- Organometallic Reagents
- Mol File:
- 13291-18-4.mol
ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties
- Melting point:
- 102-104 °C
- Boiling point:
- 67 °C
- Density
- 0.94 g/mL at 20 °C
- Flash point:
- −36 °F
- storage temp.
- 2-8°C
- form
- Crystalline Powder
- color
- White to yellow to orange
- BRN
- 3587297
- InChIKey
- LFTYALBVGVNGLI-UHFFFAOYSA-M
Safety Information
- Hazard Codes
- F,C
- Risk Statements
- 11-14/15-34-40-37-19-14
- Safety Statements
- 26-30-36/37/39-43-45-7/8-16
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 1
- F
- 1-3-10-34
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
ISOPROPENYLMAGNESIUM BROMIDE Usage And Synthesis
Uses
Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Uses
Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.
General Description
This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.
reaction suitability
reaction type: Grignard Reaction
Synthesis
The Preparative Method of 2-Propenylmagnesium Bromide-Copper(I) Iodide: prepared in situ under anhydrous conditions by reacting 2-propenylmagnesium bromide (1) with Copper(I) Iodide (2) in varying molar ratios.
ISOPROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation Products
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ISOPROPENYLMAGNESIUM BROMIDE(13291-18-4)Related Product Information
- ISOBUTYLMAGNESIUM CHLORIDE
- ISOPROPYLMAGNESIUM BROMIDE
- Vinyl isopropyl ether
- Isopropenylboronic acid pinacol ester
- Isopropenyloxytris(triMethylsilyl)silane
- Isofraxidin
- Isopropyl alcohol
- LANTHANUM ISOPROPOXIDE
- BARIUM ISOPROPOXIDE
- (-)-DIOP
- METHYLZINC CHLORIDE
- Benzylmagnesium chloride
- 4-FLUOROPHENYLMAGNESIUM BROMIDE
- Di-n-butylmagnesium
- 3-FLUOROPHENYLMAGNESIUM BROMIDE
- Cyclopropylmagnesium bromide
- CYCLOPENTYLMAGNESIUM BROMIDE
- SEC-BUTYLMAGNESIUM BROMIDE