ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties

Melting point:

102-104 °C

Boiling point:

67 °C

Density 

0.94 g/mL at 20 °C

Flash point:

−36 °F

storage temp. 

2-8°C

form 

Crystalline Powder

color 

White to yellow to orange

BRN 

3587297

InChIKey

LFTYALBVGVNGLI-UHFFFAOYSA-M

Safety Information

Hazard Codes 

F,C

Risk Statements 

11-14/15-34-40-37-19-14

Safety Statements 

26-30-36/37/39-43-45-7/8-16

RIDADR 

UN 3399 4.3/PG 1

WGK Germany 

1

F 

1-3-10-34

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich

ISOPROPENYLMAGNESIUM BROMIDE Usage And Synthesis

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.

General Description

This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

ISOPROPENYLMAGNESIUM BROMIDE(13291-18-4)Related Product Information

• ISOBUTYLMAGNESIUM CHLORIDE
• ISOPROPYLMAGNESIUM BROMIDE
• Vinyl isopropyl ether
• Isopropenylboronic acid pinacol ester
• Isopropenyloxytris(triMethylsilyl)silane
• Isofraxidin
• Isopropyl alcohol
• LANTHANUM ISOPROPOXIDE
• BARIUM ISOPROPOXIDE
• (-)-DIOP
• METHYLZINC CHLORIDE
• Benzylmagnesium chloride
• 4-FLUOROPHENYLMAGNESIUM BROMIDE
• Di-n-butylmagnesium
• 3-FLUOROPHENYLMAGNESIUM BROMIDE
• Cyclopropylmagnesium bromide
• CYCLOPENTYLMAGNESIUM BROMIDE
• SEC-BUTYLMAGNESIUM BROMIDE