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ISOPROPENYLMAGNESIUM BROMIDE

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ISOPROPENYLMAGNESIUM BROMIDE Basic information

Product Name:
ISOPROPENYLMAGNESIUM BROMIDE
Synonyms:
  • Isopropenylmagnesium bromide, 0.5 M solution in THF, HySeal
  • ISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURAN
  • ISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURAN
  • ISOPROPENYLMAGNESIUM BROMIDE 0.5 M THF
  • Isopropenylmagnesium bromide( 1.0 M solution in THF)
  • IsopropenyL
  • Isopropenylmagnesium bromide 1M solution in tetrahydrofuran
  • ISOPROPENYLMAGNESIUM BROMIDE
CAS:
13291-18-4
MF:
C3H5BrMg
MW:
145.28
EINECS:
603-688-6
Product Categories:
  • Grignard Reagent
  • Alkenyl
  • Grignard Reagents
  • Organometallic Reagents
Mol File:
13291-18-4.mol
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ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties

Melting point:
102-104 °C
Boiling point:
67 °C
Density 
0.94 g/mL at 20 °C
Flash point:
−36 °F
storage temp. 
2-8°C
form 
Crystalline Powder
color 
White to yellow to orange
BRN 
3587297
InChIKey
LFTYALBVGVNGLI-UHFFFAOYSA-M
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Safety Information

Hazard Codes 
F,C
Risk Statements 
11-14/15-34-40-37-19-14
Safety Statements 
26-30-36/37/39-43-45-7/8-16
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
1-3-10-34
HS Code 
29319090

MSDS

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ISOPROPENYLMAGNESIUM BROMIDE Usage And Synthesis

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.

General Description

This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

ISOPROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Preparation Products

ISOPROPENYLMAGNESIUM BROMIDESupplier

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