ChemicalBook > CAS DataBase List > 4-(Bromomethyl)tetrahydropyran

4-(Bromomethyl)tetrahydropyran

Product Name
4-(Bromomethyl)tetrahydropyran
CAS No.
125552-89-8
Chemical Name
4-(Bromomethyl)tetrahydropyran
Synonyms
4-(broMoMethyl)oxane;4-bromomethytetrahydropyran;4-(BroMoMethyl)tetrahydro...;4-BROMOMETHYLTETRAHYDROPYRAN;4-(Bromomethyl)tetrahydropyrane;4-(Bromomethyl)tetrahydropyran ,97%;4-(BROMOMETHYL)-TETRAHYDRO-2H-PYRAN;2H-Pyran, 4-(broMoMethyl)tetrahydro-;Tetrahydro-2H-pyran-4-yl-MethylbroMide;4-(Bromomethyl)tetrahydro-2H-pyran 97%
CBNumber
CB0436966
Molecular Formula
C6H11BrO
Formula Weight
179.05
MOL File
125552-89-8.mol
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4-(Bromomethyl)tetrahydropyran Property

Boiling point:
88 °C
Density 
1.359±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
form 
liquid
color 
Light beige/brown
InChI
InChI=1S/C6H11BrO/c7-5-6-1-3-8-4-2-6/h6H,1-5H2
InChIKey
LMOOYAKLEOGKJR-UHFFFAOYSA-N
SMILES
C1OCCC(CBr)C1
CAS DataBase Reference
125552-89-8(CAS DataBase Reference)
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Safety

Hazard Codes 
C,Xn
Risk Statements 
36/37/38-34-22
Safety Statements 
26-36/37/39-45-23
RIDADR 
3265
Hazard Note 
Irritant
HazardClass 
8
PackingGroup 
Ⅲ
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC
Product number
B697768
Product name
4-Bromomethyltetrahydropyran
Packaging
500mg
Price
$65
Updated
2021/12/16
Oakwood
Product number
037029
Product name
4-(Bromomethyl)tetrahydropyran
Purity
95%
Packaging
5g
Price
$70
Updated
2021/12/16
Matrix Scientific
Product number
069250
Product name
4-(Bromomethyl)tetrahydropyran
Purity
97%
Packaging
5g
Price
$71
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB59639
Product name
4-(Bromomethyl)tetrahydropyran
Packaging
2g
Price
$100
Updated
2021/12/16
Ark Pharm
Product number
P000132139
Product name
4-(Bromomethyl)tetrahydropyran
Purity
95%
Packaging
10g
Price
$105
Updated
2021/12/16
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4-(Bromomethyl)tetrahydropyran Chemical Properties,Usage,Production

Chemical Properties

Viscous liquid

Uses

4-(Bromomethyl)tetrahydropyran is an important organic synthesis intermediate, widely used in the fields of medicine, pesticides and dyes. It can be used to synthesize a variety of biologically active compounds, such as antibacterial agents, anti-tumor drugs, nervous system drugs and fluorescent dyes. In addition, 4-(Bromomethyl)tetrahydropyran can also be used to synthesize organic pigments and functional materials.

Synthesis

To a solution of Tetrahydropyran-4-methanol and N-bromobutanimide (NBS) in DCM was added PPh3 at 0°C. The reaction mixture was stirred at room temperature for 1–2h. The resulting mixture was washed with water (20mL) and brine (3×20mL). The organic layer was concentrated and the residue was purified by silica gel flash chromatography (eluting with ethyl acetate in petroleum ether 2–5%) to give 4-(Bromomethyl)tetrahydropyran as a colorless oil.

4-(Bromomethyl)tetrahydropyran Preparation Products And Raw materials

Raw materials

Hexane Benzyltriethylammonium chloride Ethanol Potassium bromide Potassium hydroxide Acetone Sodium Tetrahydro-2H-pyran-4-carboxylic acid Tosyl chloride 2,2'-Dichlorodiethyl ether Tetrahydrofuran Diethyl ether Ethyl acetate Lithium Aluminum Hydride Hydrochloric acid Phosphorus tribromide Diethyl malonate Pyridine

Preparation Products

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4-(Bromomethyl)tetrahydropyran Suppliers

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View Lastest Price from 4-(Bromomethyl)tetrahydropyran manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
4-BroMoMethyltetrahydropyran 125552-89-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-22
Shanghai Yongzeng Technology Co.,Ltd
Product
4-(Bromomethyl) tetrahydropyran 125552-89-8
Price
US $1500.00/kg
Min. Order
1kg
Purity
99%min
Supply Ability
100kgs
Release date
2024-09-02
Dideu Industries Group Limited
Product
4-BROMOMETHYLTETRAHYDROPYRAN 125552-89-8
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-10-29

125552-89-8, 4-(Bromomethyl)tetrahydropyranRelated Search:

4-IODOTETRAHYDRO-2H-PYRAN (TETRAHYDRO-2H-PYRAN-4-YL)METHANOL 3,4-Dihydro-2H-pyran TETRAHYDRO-2H-PYRAN-4-CARBOXAMIDE Tetrahydro-2H-pyran-4-carboxylic acid 4-Aminotetrahydropyran Tetrahydro-4H-pyran-4-one 3,6-dihydro-2H-pyran Methyl tetrahydropyran-4-carboxylate 2-methyloxan-4-one Tetrahydro-4-pyranol 4-BROMO-TETRAHYDROPYRAN 4-BROMOMETHYLTETRAHYDROPYRAN 2-(BROMOMETHYL)TETRAHYDRO-2 H-PYRAN AKOS BBS-00003110 AKOS BBS-00003110 8-(BROMOMETHYL)-1,8-DIMETHYL-3-OXABICYCLO[3.2.1]OCTANE-2,4-DIONE 8-(BROMOMETHYL)-1,8-DIMETHYL-3-OXABICYCLO[3.2.1]OCTANE

  • 4-(BROMOMETHYL)-TETRAHYDRO-2H-PYRAN
  • 4-BROMOMETHYLTETRAHYDROPYRAN
  • 4-(Bromomethyl)tetrahydropyrane
  • 4-(Bromomethyl)tetrahydropyran ,97%
  • 4-(Bromomethyl)tetrahydro-2H-pyran 97%
  • 4-bromomethytetrahydropyran
  • Tetrahydro-2H-pyran-4-yl-MethylbroMide
  • 4-(BroMoMethyl)tetrahydro...
  • (Tetrahydro-2H-pyran-4-yl)methyl bromide, 4-(Bromomethyl)oxane
  • 4-(broMoMethyl)oxane
  • 2H-Pyran, 4-(broMoMethyl)tetrahydro-
  • 1-(Tetrahydro-2H-pyran-4-yl)methylbromide
  • 4-BROMOMETHYLTETRAHYDROPYRAN ISO 9001：2015 REACH
  • 125552-89-8
  • C6H11BrO
  • Heterocyclic Compounds
  • blocks
  • Bromides
  • Heterocycles
  • Halides