4-Chloroanisole
- Product Name
- 4-Chloroanisole
- CAS No.
- 623-12-1
- Chemical Name
- 4-Chloroanisole
- Synonyms
- 1-CHLORO-4-METHOXYBENZENE;P-CHLOROANISOLE;para-Chloroanisole;4-Methoxyphenyl chloride;p-chloroanisol;4-Chloroanisol;Chloro anisole;4-CHLOROANISOLE;3 4-Chloroanisole;Anisole, p-chloro-
- CBNumber
- CB1312283
- Molecular Formula
- C7H7ClO
- Formula Weight
- 142.58
- MOL File
- 623-12-1.mol
4-Chloroanisole Property
- Melting point:
- -18 °C (lit.)
- Boiling point:
- 198-202 °C (lit.)
- Density
- 1.164 g/mL at 25 °C (lit.)
- vapor pressure
- 1.08hPa at 25℃
- refractive index
- n20/D 1.535(lit.)
- Flash point:
- 173 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- Liquid
- color
- Clear colorless to yellow
- Water Solubility
- immiscible
- BRN
- 1858901
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- LogP
- 2.78 at 25℃
- CAS DataBase Reference
- 623-12-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, 1-chloro-4-methoxy-(623-12-1)
- EPA Substance Registry System
- Benzene, 1-chloro-4-methoxy- (623-12-1)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 159069
- Product name
- 4-Chloroanisole
- Purity
- 99%
- Packaging
- 25g
- Price
- $102
- Updated
- 2024/03/01
- Product number
- 159069
- Product name
- 4-Chloroanisole
- Purity
- 99%
- Packaging
- 100g
- Price
- $286
- Updated
- 2023/06/20
- Product number
- C0122
- Product name
- 4-Chloroanisole
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $44
- Updated
- 2024/03/01
- Product number
- C0122
- Product name
- 4-Chloroanisole
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $252
- Updated
- 2024/03/01
- Product number
- A11377
- Product name
- 4-Chloroanisole, 99%
- Packaging
- 50g
- Price
- $57.65
- Updated
- 2024/03/01
4-Chloroanisole Chemical Properties,Usage,Production
Chemical Properties
colourless liquid
Uses
4-Chloroanisole was found to react with Cu (II)-smectite forming a blue clay-organic complex. 4-Chloroanisole was chosen as the main test substrate for the optimisation studies as it is electronically deactivated and thus resistant to oxidative addition and consequently very reluctant to enter a catalytic manifold.
Synthesis Reference(s)
Chemistry Letters, 16, p. 1901, 1987
The Journal of Organic Chemistry, 35, p. 528, 1970 DOI: 10.1021/jo00827a060
General Description
4-Chloroanisole is an electron-rich chloroarene. It undergoes Ullmann-type homocoupling catalyzed by in situ generated Pd colloids. Reaction of 4-chloroanisole with Cu(II)-smectite in n-hexane, carbon tetrachloride or dichloromethane has been studied. The nucleophilic photosubstitution reactions, photocyanation and photohydrolysis of 4-chloroanisole has been studied by time resolved spectroscopy.
Purification Methods
Wash the anisole with 10% (by volume) aqueous H2SO4 (three times), 10% aqueous KOH (three times), and then with water until neutral. Dry it (MgSO4), and fractionally distil it from CaH2 through a glass helices-packed column under reduced pressure. [Beilstein 16 IV 822.]
4-Chloroanisole Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Chloroanisole manufacturers
- Product
- 4-Chloroanisole 623-12-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 ton
- Release date
- 2024-08-21
- Product
- 4-Chloroanisole 623-12-1
- Price
- US $1.00/PCS
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2021-02-04
- Product
- 4-Chloroanisole 623-12-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-09-07