6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE

Application

Product Name: 6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
CAS No.: 337463-88-4
Chemical Name: 6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
Synonyms: 6-Bromo-4H-pyrido[3,2-b][1,4]oxazin-3-one;6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE;2H-Pyrido[3,2-b]-1,4-oxazin-3(4H)-one, 6-bromo-;6-broMo-2H,3H,4H-pyrido[3,2-b][1,4]oxazin-3-one
CBNumber: CB22455909
Molecular Formula: C7H5BrN2O2
Formula Weight: 229.03
MOL File: 337463-88-4.mol

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6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE Property

Boiling point:: 423.1±45.0 °C(Predicted)
Density: 1.772±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 10.18±0.20(Predicted)
Appearance: White to yellow Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC

Product number: B293340
Product name: 6-Bromo-2H-pyrido[3,2-b][1,4]oxazin-3(4H)-one
Packaging: 10mg
Price: $45
Updated: 2021/12/16

ChemScene

Product number: CS-0039106
Product name: 6-Bromo-2H-pyrido[3,2-b][1,4]oxazin-3(4H)-one
Purity: 97.33%
Packaging: 100mg
Price: $62
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB144104
Product name: 6-Bromo-2H-pyrido[3,2-b][1,4]oxazin-3(4H)-one
Packaging: 250mg
Price: $85
Updated: 2021/12/16

ChemScene

Product number: CS-0039106
Product name: 6-Bromo-2H-pyrido[3,2-b][1,4]oxazin-3(4H)-one
Purity: 97.33%
Packaging: 250mg
Price: $100
Updated: 2021/12/16

AK Scientific

Product number: Y3278
Product name: 6-Bromo-2H-pyridooxazin-3(4H)-one
Packaging: 100mg
Price: $142
Updated: 2021/12/16

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6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE Chemical Properties,Usage,Production

Application

6-Bromo-3-hydroxy-2-nitropyridine is a pyridine derivative and an important organic chemical intermediate that can be widely used in pesticides, pharmaceuticals, dyes, fragrances, and other fields.

Synthesis

443956-09-0

337463-88-4

Compound 3.1 (2.7 g, 8.85 mmol) was used as raw material and mixed with iron powder (2.48 g, 44.3 mmol) in acetic acid (40 mL). The reaction mixture was stirred at 100 °C for 2 hours. After the reaction was completed, it was cooled to room temperature and the reaction solution was filtered through diatomaceous earth. Water (100 mL) was added to the filtrate and extracted with dichloromethane (20 mL x 3). The organic phases were combined, dried over anhydrous sodium sulfate and concentrated. The residue was purified by silica gel column chromatography (petroleum ether/ethyl acetate= 3/1) to afford the target product, 6-bromo-2H-pyrido[3,2-b][1,4]oxazin-3(4H)-one (Compound 3.2, 1.9 g, Yield: 95%) as a pale yellow liquid.

References

[1] Patent: CN108623615, 2018, A. Location in patent: Paragraph 0362; 0363; 0366
[2] Tetrahedron Letters, 2010, vol. 51, # 38, p. 5035 - 5037
[3] Synthetic Communications, 2013, vol. 43, # 24, p. 3315 - 3321
[4] Patent: EP2341052, 2011, A1. Location in patent: Page/Page column 35-36
[5] Patent: WO2017/199265, 2017, A1. Location in patent: Paragraph 000134

6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE Suppliers

China 83 India 2 United Kingdom 1 United States 5 Global 91

Accela ChemBio Inc.

Tel: +1-858-6993322
Fax: (+1)-858-876-1948
Email: info@accelachem.com
Country: United States
ProdList: 21193
Advantage: 58

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63687
Advantage: 58

Aladdin Scientific

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Email: tp@aladdinsci.com
Country: United States
ProdList: 52923
Advantage: 58

Synthonix Inc

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Fax: --
Email: info@synthonix.com
Country: United States
ProdList: 6872
Advantage: 58

Matrix Scientific

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Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

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View Lastest Price from 6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE manufacturers

Shanghai Rlavie Technology Co ltd

Product: 6-broMo-2H-pyrido[3,2-b][1,4]oxazin-3(4H)-one 337463-88-4
Price: US $0.00-0.00/kg
Min. Order: 0.0001kg
Purity: 98%min
Supply Ability: 100kgs/month
Release date: 2022-05-09

Career Henan Chemical Co

Product: 6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE 337463-88-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-08

337463-88-4, 6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONERelated Search:

6-Bromo-3-cyanoindole 6-BROMO-3-CHLOROISOQUINOLINE 6-BROMO-3-METHYL INDAZOLE Methyl 6-broMo-3-hydroxypicolinate 6-Bromo-3-hydroxy-2-methylpyridine 6-BROMO-3-METHYLBENZODISOXAZOLE 6-bromo-3-iodopyridin-2-amine 6-Bromo-3-hydroxypicolinicacid 6-Bromo-3,4-dihydro-1H-[1,8]naphthyridin-2-one 6-BroMo-3-Methyl-2-pyridinaMine 6-BroMo-3-Methoxy-2-Methylpyridine 6-BROMO-1H-INDAZOLE-3-CARBALDEHYDE Methyl 6-broMo-3-Methoxypicolinate 2-BROMO-5-ETHOXYPYRIDINE N-(6-Bromopyridin-2-yl)acetamide 2-BROMO-5-METHOXYPYRIDINE 6-BROMO-3,4-DIHYDRO-2H-PYRIDO[3,2-B][1,4]OXAZINE 6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE

6-BROMO-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE

6-broMo-2H,3H,4H-pyrido[3,2-b][1,4]oxazin-3-one

6-Bromo-4H-pyrido[3,2-b][1,4]oxazin-3-one

2H-Pyrido[3,2-b]-1,4-oxazin-3(4H)-one, 6-bromo-

337463-88-4