methyl 6-methylpyridine-2-carboxylate
- Product Name
- methyl 6-methylpyridine-2-carboxylate
- CAS No.
- 13602-11-4
- Chemical Name
- methyl 6-methylpyridine-2-carboxylate
- Synonyms
- NSC 109151;Methyl 6-methylpicolinate;6-Methylpicolinic Acid Methyl Ester;Methyl-6-methylpyridin-2-carboxylat;methyl 6-methylpyridine-2-carboxylate;Methyl 6-methyl-2-pyridinecarboxylate;METHYL-6-MENTHYPYRIDINE-2-CARBOXYLATE;Methyl6-Methylpyridine-2-carboxylate>Methyl6-methylpyridine-2-carboxylate,96%;6-methyl-2-pyridinecarboxylic acid ester
- CBNumber
- CB3908806
- Molecular Formula
- C8H9NO2
- Formula Weight
- 151.16
- MOL File
- 13602-11-4.mol
methyl 6-methylpyridine-2-carboxylate Property
- Melting point:
- 18 °C
- Boiling point:
- 242℃
- Density
- 1.104
- refractive index
- 1.5160-1.5200
- Flash point:
- 100℃
- storage temp.
- Inert atmosphere,Room Temperature
- form
- powder to lump to clear liquid
- pka
- 1.93±0.10(Predicted)
- color
- White or Colorless to Light yellow
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- M2503
- Product name
- Methyl 6-Methylpyridine-2-carboxylate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $84
- Updated
- 2025/07/31
- Product number
- M264555
- Product name
- Methyl 6-Methylpyridine-2-carboxylate
- Packaging
- 1g
- Price
- $50
- Updated
- 2021/12/16
- Product number
- 032619
- Product name
- 6-Methyl-pyridine-2-carboxylicacidmethylester
- Purity
- 98%
- Packaging
- 25g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- J97522
- Product name
- Methyl6-methylpicolinate
- Packaging
- 25g
- Price
- $65
- Updated
- 2021/12/16
- Product number
- X9935
- Product name
- Methyl6-methylpicolinate
- Packaging
- 5g
- Price
- $20
- Updated
- 2021/12/16
methyl 6-methylpyridine-2-carboxylate Chemical Properties,Usage,Production
Uses
Methyl 6-Methylpyridine-2-carboxylate is a reagent used in the sunthesis of antitumor agents based upon the dihydropyrrolopyrazole compounds. Also used in the synthesis of quinazolinone TGF-β inhibitors.
Synthesis
67-56-1
934-60-1
13602-11-4
Step 2: 26.8 g (0.195 mol) of SOCl2 was slowly added dropwise to 100 mL of methanol at a low temperature of -10 °C while stirring was continued. After the dropwise addition, the reaction mixture was gradually warmed up to room temperature and stirring was continued for 1 hour. Subsequently, 10 g of 6-methyl-2-pyridinecarboxylic acid (Compound 2) was added to the reaction system and the reaction was refluxed at 80 °C for 5 hours. Upon completion of the reaction, 10.2 g of methyl 6-methyl-2-pyridinecarboxylate (Compound 3) was obtained in 93% yield.
References
[1] Patent: CN105294552, 2016, A. Location in patent: Paragraph 0047; 0051
[2] Patent: WO2004/48383, 2004, A1. Location in patent: Page 40
[3] Patent: WO2004/48382, 2004, A1. Location in patent: Page 8
[4] Patent: WO2016/187308, 2016, A1. Location in patent: Paragraph 0349
[5] Patent: WO2012/80221, 2012, A1. Location in patent: Page/Page column 98
methyl 6-methylpyridine-2-carboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
methyl 6-methylpyridine-2-carboxylate Suppliers
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 400-021-7337 2355568890
- Fax
- 0086-21-50182339
- sales@demochem.com
- Country
- China
- ProdList
- 2572
- Advantage
- 57
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9310
- Advantage
- 66
- Tel
- 001-857-928-2050 or 1-888-588-9418
- Fax
- 001-617-206-9595
- sales@chemreagents.com
- Country
- United States
- ProdList
- 10186
- Advantage
- 62
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11035
- Advantage
- 64
- Tel
- 021-58099652-8005 13585536065
- Fax
- 021-58099609
- bin.wu@shlschem.com
- Country
- China
- ProdList
- 9883
- Advantage
- 59
- Tel
- 021-31038972,31038973 17321035817
- Fax
- +86-21-51385350
- sales@harvest-chem.com
- Country
- China
- ProdList
- 2816
- Advantage
- 64
View Lastest Price from methyl 6-methylpyridine-2-carboxylate manufacturers
- Product
- methyl 6-methylpyridine-2-carboxylate 13602-11-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-06-04
- Product
- methyl 6-methylpyridine-2-carboxylate 13602-11-4
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons Min
- Release date
- 2021-10-27
- Product
- methyl 6-methylpyridine-2-carboxylate 13602-11-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11